CAS: 85107-55-7; 4-Methoxycarbonyl-2-Nitrophenylboronic Acid

该化合物是有机化合物,其特点是存在一种碳酸性功能组,硝基化合物和酯酸酯,该化合物一般是固体,在极有机溶剂中可溶解.boron酸组中的原子可形成可逆的共价结合,与二醇形成可逆的共价结合,使其在各种应用中有用,特别是在有机合成和药用化学中.硝基化合物有助于化合物的电子下拖附特性,影响其再活性和稳定性.此外,与芳香环相连的甲基组可影响化合物的...

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4-羧基-2-硝基苯硼酸 (4-Carboxy-2-Nitro Phenyl)Dihydroxy Borane 85107-54-6
4-碘-3-硝基苯甲酸甲酯 4-Iodo-3-Nitrobenzoic Acid Methyl Ester 89976-27-2

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  • 85107-54-6 = 85107-55-7
    反应条件:1.1 Reagents: Thionyl Chloride; Rt; 3 H,Reflux1.2 Reagents: Water; 0.5 H,Cooled
    标题:Synthesis Of 2-Amino-4-(Methoxycarbonyl)Phenylboronic Acid Hydrochloride,A Key Intermediate For The Synthesis Of Quinolines Derivatives
    作者:Xue,Feng; Li,Chang-Gong; Zhu,Yong; Lou,Tian-Jun
    参考文献:Journal Of Chemical Research 日期:2014 卷标:38(12) 页码:719-721]

    89976-27-2 = 85107-55-7
    反应条件:1.1 Reagents: Phenylmagnesium Chloride Solvents: Tetrahydrofuran; -78 °C; 5 Min,-78 °C1.2 Reagents: Trimethyl Borate; -78 °C; 30 Min,-78 °C; -78 °C -> -20 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; -20 °C
    标题:Promoting Reductive Tandem Reactions Of Nitrostyrenes With Mo(Co)6 And A Palladium Catalyst To Produce 3H-Indoles
    作者:Jana,Navendu; Zhou,Fei; Driver,Tom G.
    参考文献:Journal Of The American Chemical Society 日期:2015 卷标:137(21) 页码:6738-6741
📜4-碘-3-硝基苯甲酸甲酯置于盐酸,苯基氯化镁体系中,用 四氢呋喃,水 作为反应溶剂,化学反应 0.58H,反应生成 4-羧酸甲酯-2-硝基苯硼酸
参考文献:Promoting Reductive Tandem Reactions Of Nitrostyrenes With Mo(Co)6 And A Palladium Catalyst To Produce 3H-Indoles
标题:Promoting Reductive Tandem Reactions Of Nitrostyrenes With Mo(Co)6 And A Palladium Catalyst To Produce 3H-Indoles
摘要:The Combination Of Mo(Co)(6) And 10 Mol % Of Palladium Acetate Catalyzes The Transformation Of 2-Nitroarenes To 3H-Indoles Through A Tandem Cyclization-[1,2] Shift Reaction Of In Situ Generated Nitrosoarenes. Mo(Co)(6) Appears To Have Dual Roles In This Transformation Generate Generate Co And Promote C-N Bond Formation To Increase The Yield Of The N-Heterocycle Product.
DOI:10.1021/jacs.5B02946

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参考标题:The Suzuki-Miyaura Cross‐coupling As The Key Step In The Synthesis Of 2‐aminobiphenyls And 2,2'‐diaminobiphenyls: Application In The Synthesis Of Schiff Base Complexes Of Zn
作者:Knut Tormodssønn Hylland,Sigurd øien‐ødegaard,Mats Tilset |发布日期:2020.7.23
摘要:The Suzuki-Miyaura Reaction Is Used As A Key Step For The Synthesis Of 2‐aminobiphenyls And 2,2'‐diaminobiphenyls, Which In Turn Can Be Utilized To Make Schiff Base Complexes Of Zn. Special Emphasis Is On The Cross‐coupling Reaction Between 2‐bromoanilines And A 2‐nitro‐substituted Arylboronic Acid, For Which There Is Little Existing Precedence.

合成参考文献


参考文献:10.1007/s11244-025-02218-5
摘要:Cortez Sgroi Pupo R, Garetto B, Rasheed MA, Cao N, Arstad B, Pourpoint F, Aunan E, Bordiga S, Olsbye U, Nova A, Borfecchia E, Szilágyi PÁ. C-H Activation with Cu(I) MOFs: The Pertinence of Natural-Like Active Centres and Their Facile Modification. Top Catal. 2025 Nov 17;68(20):2375–92. doi: 10.1007/s11244-025-02218-5.
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