Acetic Acid (2R,3R,4S,5R,6R)-3,5-Diacetoxy-2-Acetoxymethyl-6-Allyloxy-Tetrahydro-Pyran-4-Yl Ester置于lithium Acetate,Sodium Methylate,Copper Diacetate,Palladium Diacetate体系中,用 甲醇,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 2.0H,反应生成 (2E)-3-苯基-2-丙烯-1-基 Beta-D-吡喃葡萄糖苷
参考文献:Simple Preparation Of Phenylpropenoid β-D-Glucopyranoside Congeners By Mizoroki-heck Type Reaction Using Organoboron Reagents
标题:Simple Preparation Of Phenylpropenoid β-D-Glucopyranoside Congeners By Mizoroki-heck Type Reaction Using Organoboron Reagents
摘要:Palladium(II)-Catalyzed Carbon-Carbon Bond Formation Between Allyl 2,3,4,6-Tetra-O-Acetyl-Beta-(D)-Glucopyranoside (3) And Arylboronic Acid Congeners Gave The Corresponding Cinnamyl 2,3,4,6-Tetra-O-Acetyl-Beta-(D)-Glucopyranosides (4A-M) In Good Yield. Among Them,Coupling Products 4A-M Were Converted To Not Only The Naturally occurring Phenylpropenoid Beta-(D)-Glucopyranoside Analogues (La-E) But Also The Unnaturally Ones (If-M). (C) 2005 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tet.2005.08.043