CAS: 85026-55-7; (2R,3R,4S,5S,6R)-2-(Cinnamyloxy)-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-3,4,5-Triol

该化合物是天然玫瑰物质,产自松树,主要由各种树脂酸组成,包括乙酸及其衍生物;Rosin X的特点是室温呈固体,细质形式,呈现黄色和黄黄色;它以粘合性能著称,通常用于生产粘合剂,油墨和涂层,因为其细腻和胶片成型能力很强.此外,Rosin X因其与各种聚合物和树脂的兼容性而受到重视,提高了其加入的配方的性能;该物质一般被认为毒性较低,但应该像所有化学物质一样,观察适当的处理和安全措施.它的应用范围扩大到食品工业,在那里可用于食品级粘合剂,尽管遵守规章是必要的.总的来说,Rosin X是一种配方材料,具有重要的工业用途,特别是在粘合和涂层部门.

结构式图片

上下游产品

cinnamylalcohol 9-O-(6'-O-α-L-arabinofuranosyl)-β-D-glucopyranoside cinnamyl 6-O-(α-L-arabinopyranosyl)-β-D-glucopyranoside 3-Phenylpropenol 4-nitrophenyl-β-D-glucosideD-Glucose (Z)-cinnamyl alcohol (2E)-3-phenyl-2-propen-1-ol (2R,3S,4S,5R,6R)-2-Hydroxymethyl-6-((Z)-3-phenyl-allyloxy)-tetrahydro-pyran-3,4,5-triol

合成工艺路线路线简述

    Acetic Acid (2R,3R,4S,5R,6R)-3,5-Diacetoxy-2-Acetoxymethyl-6-Allyloxy-Tetrahydro-Pyran-4-Yl Ester置于lithium Acetate,Sodium Methylate,Copper Diacetate,Palladium Diacetate体系中,用 甲醇,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 2.0H,反应生成 (2E)-3-苯基-2-丙烯-1-基 Beta-D-吡喃葡萄糖苷
    参考文献:Simple Preparation Of Phenylpropenoid β-D-Glucopyranoside Congeners By Mizoroki-heck Type Reaction Using Organoboron Reagents
    标题:Simple Preparation Of Phenylpropenoid β-D-Glucopyranoside Congeners By Mizoroki-heck Type Reaction Using Organoboron Reagents
    摘要:Palladium(II)-Catalyzed Carbon-Carbon Bond Formation Between Allyl 2,3,4,6-Tetra-O-Acetyl-Beta-(D)-Glucopyranoside (3) And Arylboronic Acid Congeners Gave The Corresponding Cinnamyl 2,3,4,6-Tetra-O-Acetyl-Beta-(D)-Glucopyranosides (4A-M) In Good Yield. Among Them,Coupling Products 4A-M Were Converted To Not Only The Naturally occurring Phenylpropenoid Beta-(D)-Glucopyranoside Analogues (La-E) But Also The Unnaturally Ones (If-M). (C) 2005 Elsevier Ltd. All Rights Reserved.
    DOI:10.1016/j.Tet.2005.08.043

    海关参考信息

    专利信息


    专利号:US-11891497-B2
    优先权日:2019-12-17
    标题 :Mechanochemical synthesis of polymer-compatible organoclays
    发明人:Rounaghi Seyyed Amin; ESMAEILI ELAHEH
    权利人:Rounaghi Seyyed Amin; ESMAEILI ELAHEH
    摘要:A method for producing a clay/polymer composite may include choosing an intercalating agent from among organic constituents of a polymer matrix, forming a polymer-compatible organoclay by mixing and milling an intercalating agent with a clay, and adding a polymer-compatible organoclay to a polymer matrix.

    专利号:WO-2024063732-A1
    优先权日:2022-11-01
    标 题 :Isoamylester rosin and its synthesis method
    发明人:YILMAZ BILGE; DENİZ İLHAN; FAZLI HİLAL
    权利人:KARADENIZ TEKNIK UNIV; YESILPOLIMER KIMYA SANAYI VE TICARET LTD STI
    摘要:The invention relates to the compound of isoamyl ester rosin represented by Formula I and the synthesis method of this compound from pine resin colophony. The isoamyl ester rosin compound according to the invention is used as a biobased hardener in various fields such as the paper industry, adhesives, paint industry, and printing inks. It finds applications in the furniture sector for varnish and adhesive production, in the wood panel industry for water-repellent adhesive production, and in the aerospace industry for producing different types of paint formulations or adhesives with varying characteristics. Additionally, the disclosed isoamyl ester rosin compound is suitable as a biobased hardener, serving as an alternative to paraffin, in MDF (medium-density fiberboard) production.

    专利号:US-2025144039-A1
    优先权日:2022-07-13
    标题:Compositions comprising surface modified globular nano-particles
    发明人:ABRAMOVICH SAGI; AVIDOR GAL; LANDA BENZION
    权利人:LANDA LABS 2012 LTD
    摘要:There are disclosed compositions comprising core-shell nano-elements composed in their core of a water-insoluble thermoplastic compound having a molecular weight of more than 0.6 kDa and in their shell of at least one fatty amine, or a part thereof, the core-shell nano-elements having a viscosity of 107 mPa·s or less and being dispersed in a polar carrier as nano-elements having an average diameter of 200 nm or less. The water-insoluble thermoplastic compound can be capable of stimulating the synthesis of skin proteins and/or enabling the delivery of active agents upon application of the core-shell nano-elements to a surface to be treated therewith. Methods for preparing the composition and uses thereof are also provided.

    专利号:EP-3497144-B1
    优先权日:2016-08-08
    标 题:Process for the synthesis of silylated polyurethanes and silylated polyurethane composition

    专利号:US-9700589-B2
    优先权日:2015-02-03
    标题:Compositions and methods for improved muscle metabolism
    发明人:BILY ANTOINE CHARLES; MEYER MARJOLAINE; CHEVALIER KARL; Laurençon Lise; FEUILLERE NICOLAS; ROLLER MARC; BIRTIC SIMONA
    权利人:NATUREX SA
    摘要:A composition for improving muscle metabolism in a subject and methods for manufacturing and using same. Embodiments include compositions having an extract of Rhaponticum and an extract of Rhodiola . An extract of Rhaponticum may include amounts of ecdysterones including 20-hydroxyecdysone. An extract of Rhodiola my include salidrosides and rosavins, including rosavin. Suitable ingestion dosages of the composition may be operable to increase protein synthesis and reduce protein proteolysis in a subject.

    专利号:CN-115109793-A
    优先权日:2022-06-24
    标题 :A kind of recombinant Escherichia coli for de novo synthesis complex and its construction method and application
    上海高又高化工有限公司
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    主要参考文献

    参考标题:A Sustainable One‐pot, Two‐enzyme Synthesis Of Naturally Occurring Arylalkyl Glucosides
    作者:Ivan Bassanini,Jana Krejzová,Walter Panzeri,Daniela Monti,Vladimir Křen,Sergio Riva |发布日期:2017.5.9
    摘要:A Sustainable, Convenient, Scalable, One-Pot, Two-Enzyme Method For The Glucosylation Of Arylalkyl Alcohols Was Developed. The Reaction Scheme Is Based On A Transrutinosylation Catalyzed By A Rutinosidase From A. Niger Using The Cheap Commercially Available Natural Flavonoid Rutin As Glycosyl Donor, Followed By Selective "Trimming" Of The Rutinoside Unit Catalyzed By A Rhamnosidase From A. Terreus

    合成参考文献


    参考文献:10.3987/com-04-10205
    摘要:Tanaka T, Nakanishi T, Iida N, Inatomi Y, Murata H, Inada A, Murata J, A. Lang F, Iinuma M. New Neolignan and Phenylpropanoid Glycosides in Juniperus communis var. depressa. HETEROCYCLES. 2004;63(11):2573. doi: 10.3987/com-04-10205.
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