CAS: 49678-04-8; (E)-3-(4-Bromophenyl)Acrylaldehyde

该化合物是苯环的副位置上存在溴原子的肉桂丁的溴化衍生物,该化合物是有机合成的多用途中间体,特别是在制药,农用化学品和精细化学物的制作方面.其α,β-不饱和甲醛酸盐混合物使它成为Michael添加,凝聚反应和其他转化的宝贵基质.溴代苯子的分质增强了它的再活动,使复杂的分子构造能够有选择地实现功能化.在定义明确的熔点和纯度的情况下,4-Broomcynnaldhyde适合需要精确化学修改的研究和工业应用.由于它可能对光和湿度具有敏感性,因此建议适当处理.

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上下游产品

CAS号105515-33-1 3-(4-BROMOPHENY... | CAS号75-07-0 乙醛 | CAS号1122-91-4 对溴苯甲醛 | CAS号80793-25-5 3-(4-溴苯基)丙醛 | CAS号3650-78-0 4-溴肉桂酸甲酯 | CAS号13565-09-8 (2E)-3-(4-Bromo... | CAS号1200-07-3 对溴肉桂酸 | CAS号2136-75-6 甲酰甲撑基三苯基膦 | CAS号105515-33-1 3-(4-BROMOPHENY... | CAS号80793-25-5 3-(4-溴苯基)丙醛 | CAS号73387-46-9 3-(4-溴苯基)-1H-吡唑 | CAS号13484-04-3 3-(4-溴苯基)异噁唑 | CAS号1200-07-3 对溴肉桂酸 | CAS号17788-94-2 4,4''-二溴三联苯

合成工艺路线路线简述

    📜3-(4-溴苯基)丙-2-烯-1-醇置于manganese(Iv) Oxide体系中,用 二氯甲烷 作为反应溶剂,化学反应 2.0H,反应生成 4-溴肉桂醛
    参考文献:Synthesis Of 1,3,5-Trisubstituted Pyrazolines Via Zn(II)-Catalyzed Double Hydroamination Of Enynes With Aryl Hydrazines
    标题:Synthesis Of 1,3,5-Trisubstituted Pyrazolines Via Zn(II)-Catalyzed Double Hydroamination Of Enynes With Aryl Hydrazines
    摘要:讨论了一种高效的zn(II)催化的1,3-炔烃与芳香肼的分子间双氢胺化反应,用于合成吡唑啉.
    DOI:10.1039/c1Cc14850H

    海关参考信息

    专利信息


    专利号:US-2022356139-A1
    优先权日:2019-09-03
    标 题:Synthesis of deuterated aldehydes
    发明人:WANG WEI
    权利人:ARIZONA BOARD OF REGENTS ON BEHALF OF ATHE UNIV OF ARIZONA
    摘要:Described are methods for preparing a deuterated aldehyde using N-heterocyclic carbene catalysts in a solvent comprising D 2 O. The methods may be used to convert a wide variety of aldehydes (e.g., aryl, alkyl, or alkenyl aldehydes) to C-1 deuterated aldehydes under mild reaction conditions without functionality manipulation.

    专利号:WO-2021045879-A1
    优先权日:2019-09-03
    标 题 :Synthesis of deuterated aldehydes

    专利号:CN-110003093-A
    优先权日:2019-04-15
    标题 :A method for the synthesis of 1,4-dihydropyridine derivatives catalyzed by zirconocene dichloride in conjunction with benzoic acid ligands

    专利号:US-10829464-B2
    优先权日:2016-11-23
    标题 :Benzoheterocyclic alkylamine compounds and use thereof
    发明人:LI JIAN; LAN LEFU; LI BAOLI; CHEN FEIFEI; NI SHUAISHUAI; LIU YIFU; WEI HANWEN; MAO FEI; ZHU JIN
    权利人:UNIV EAST CHINA SCIENCE & TECH; SHANGHAI INST MATERIA MEDICA CAS
    摘要:Disclosed are benzoheterocyclic alkylamine compounds, or a pharmaceutically acceptable salt thereof, or a stereoisomer thereof, and a preparation method thereof, and use of the same in the manufacture of an antibacterial drug as an inhibitor of staphyloxanthin synthesis in Staphylococcus aureus .

    专利号:CN-114105993-A
    优先权日:2021-06-28
    标 题:Synthesis method of chiral pyrroloimidazole compound

    专利号:UA-79448-C2
    优先权日:2002-02-06
    标题 :Derivatives of 3-aryl-2,5-dihydroxy-1,4-benzoquinone, method for synthesis and pharmaceutical composition

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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Catalytic Enantioselective Synthesis Of Bicyclic Lactam N ,S -Acetals In One Pot By Cascade Transformations
    作者:Kaiheng Zhang,Luca Deiana,Erik Svensson Grape,A. Ken Inge,Armando Córdova |发布日期:2019.8.7
    摘要:A Versatile Strategy For The Enantioselective Synthesis Of Bicyclic Lactam N,S-Acetals By One-Pot Cascade Transformations Is Disclosed. The Transformation Of Readily Available Substrates Is Promote ...

    合成参考文献


    摘要:Delvos, L. B.; Oestreich, M., Science of Synthesis Knowledge Updates, (2017) 1, 122.
    摘要:Joule, J. A., Science of Synthesis Knowledge Updates, (2010) 2, 270.
    摘要:González-Bello, C., Science of Synthesis Knowledge Updates, (2018) 3, 441.
    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2019) 2, 307.
    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2019) 2, 313.
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