CAS: 34375-28-5; 2-(Hydroxy(Methyl)Amino)Ethan-1-Ol

相似化合物

109-83-1 3710-84-7 62640-03-3

📜N-(2-Hydroxyethylidene)Methanamine N-Oxide置于钾硼氢体系中,用 甲醇,水 用作溶剂,化学反应 24.0H,反应生成2-(羟甲基氨基)乙醇
参考文献:Structural Studies Of Organoboron Compounds Lxii. Synthesis And Structure Of Various N-Alkylated 1,3-Dioxa-4-Aza-2-Boracyclohexanes
标题:Structural Studies Of Organoboron Compounds Lxii. Synthesis And Structure Of Various N-Alkylated 1,3-Dioxa-4-Aza-2-Boracyclohexanes
摘要:本文详细介绍了多种不同取代的n-烷基2-羟基氨基烷醇3的合成及其与苯硼酸的反应.在一些情况下,晶体产物被证明是1:2缩聚物4,而在所有其他研究案例中均为1:1缩聚物5.2-三甲基-6,6-戊二亚-1,3-二氧杂-4-氮杂-2-硼杂环己烷晶体5L为三斜晶系,A = 11.540(2) å,B = 10.402(3) å,C = 8.440(2) å,α = 108.86(2)°,β = 97.62(2)°,γ = 89.36(2)°,Z = 2,空间群[formula: See Text].4,4'-亚甲基双(6,6-戊二亚-2-苯基-1,3-二氧杂-4-氮杂-2-硼杂环己烷)苯溶剂15A•c6H6的晶体为单斜晶系,A = 22.690(1) å,B = 16.867(1) å,C = 8.4783(9) å,β = 104.912(8)°,Z = 4,空间群c2/c.这些结构通过直接方法解决,并通过全矩阵最小二乘程序精化至r = 0.037和0.035(rw = 0.035和0.044),分别对应3190和2084个反射,其中i >= 3σ(F2)•.
Doi:10.1139/v94-269