3,3,3-三氟丙烯置于activated By Hf Zinc/chromia Catalyst 氢氟酸,氯体系中,用45.2%的收率获得三氟氯丙烯 参考文献: Process For The Preparation Of 2,3,3,3-Tetrafluoropropene[fr] Procédé 标题: Process For The Preparation Of 2,3,3,3-Tetrafluoropropene[fr] Procédé
专利号:US-8680346-B2 优先权日:2008-09-11 标 题 :Process for the preparation of trifluorinated and tetrafluorinated compounds 发明人:PIGAMO ANNE; DEVIC MICHEL; WENDLINGER LAURENT 权利人:PIGAMO ANNE; DEVIC MICHEL; WENDLINGER LAURENT; ARKEMA FRANCE 摘要:The subject of the invention is a process for the preparation of 2,3-dichloro-1,1,1-trifluoropropane by chlorination of 3,3,3-trifluoropropene at a pressure greater than 2 bar. Application in the synthesis of 1234yf.
专利号:US-10882802-B2 优先权日:2016-08-31 标题 :Process for catalytic hydrodefluorodimerization of fluoroölefins 发明人:BAKER RALPH THOMAS; SICARD ALEXANDRE JAMES 权利人:UNIV OTTAWA 摘要:The present application provides a hydrodefluorodimerization process, which is useful in the synthesis of, for example, fluoroolefins that can be used as refrigerants, blowers and the like. The process is an “early-stage fluorinationâ€? process, wherein precursors containing fluorine are assembled into the desired product using a zerovalent nickel catalyst. Also provided is a liquid composition comprising one or more fluoroolefin produced by this catalytic process.
专利号:US-8563789-B2 优先权日:2007-06-27 标题 :Process for the manufacture of hydrofluoroolefins 发明人:ELSHEIKH MAHER Y; BONNET PHILIPPE; CHEN BENJAMIN BIN 权利人:ELSHEIKH MAHER Y; BONNET PHILIPPE; CHEN BENJAMIN BIN; ARKEMA INC 摘要:In this invention we are disclosing a process for the synthesis of hydrocchlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the steps of fluorination of hydrochloropropenes or hydrochloropropanes to form hydrochlorofluoropropenes and/or hydrofluoropropenes, followed by gas phase, catalytic fluorination of the hydrochlorofluoropropenes to form hydrofluoropropenes.
专利号:US-8263817-B2 优先权日:2010-07-06 标 题:Synthesis of 1234YF by selective dehydrochlorination of 244BB 发明人:NAPPA MARIO JOSEPH; LOUSENBERG ROBERT D; JACKSON ANDREW 权利人:NAPPA MARIO JOSEPH; LOUSENBERG ROBERT D; JACKSON ANDREW; DU PONT 摘要:Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,tetrafluoro-2-chloropropane with a catalyst comprised of chromium (III) oxide, and at least 1% of an alkali metal, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in step (a) above.
专利号:US-8324436-B2 优先权日:2006-01-03 标 题 :Gas phase synthesis of 2,3,3,3-tetrafluoro-1-propene from 2-chloro-3,3,3-trifluoro-1-propene 发明人:MUKHOPADHYAY SUDIP; LIGHT BARBARA A; FLEMING KIM M; PHILLIPS STEVEN D; DUBEY RAJESH K 权利人:MUKHOPADHYAY SUDIP; LIGHT BARBARA A; FLEMING KIM M; PHILLIPS STEVEN D; DUBEY RAJESH K; HONEYWELL INT INC 摘要:A multi-step process for preparing 2,3,3,3-tetrafluoro-1-propene comprising the steps of (a) contacting a starting material comprising 2-chloro-3,3,3-trifluoro-1-propene with hydrogen fluoride in the presence of activated first catalyst selected from the group consisting of antimony-halides, iron-halides, titanium halides, and tin-halides, to produce an intermediate composition; and (b) contacting said intermediate composition with a second catalyst of activated carbon to produce a final product comprising 2,3,3,3-tetrafluoro-1-propene.
专利号:US-12180132-B2 优先权日:2019-07-03 标题:Compositions and methods for synthesis of 2,3-dichloro-1,1,1,2-tetrafluoropropane and 2,3,3,3-tetrafluoropropene 发明人:SUN XUEHUI 权利人:CHEMOURS CO FC LLC 摘要:A method of synthesizing 2,3,3,3-tetrafluoropropene (1234yf) from 2-chloro-3,3,3-trifluoropropene (1233xf). The 2-chloro-3,3,3-trifluoropropene (1233xf) is reacted in the vapor phase, in the presence of a catalyst, at a temperature and pressure sufficient to selectively convert the 2-chloro-3,3,3-trifluoropropene (1233xf) to 2,3,3,3-tetrafluoropropene (1234yf) without the use of antimony-based catalysts.
参考标题:Gas Phase Synthesis Of 2,3,3,3-Tetrafluoro-1-Propene From 2-Chloro-3,3,3-Trifluoro-1-Propene 摘要:A Multi-Step Process For Preparing 2,3,3,3-Tetrafluoro-1-Propene Comprising The Steps Of (A) Contacting A Starting Material Comprising 2-Chloro-3,3,3-Trifluoro-1-Propene With Hydrogen Fluoride In The Presence Of Activated First Catalyst Selected From The Group Consisting Of Antimony-Halides, Iron-Halides, Titanium Halides, And Tin-Halides, To Produce An Intermediate Composition; And (B) Contacting Said Intermediate Composition With A Second Catalyst Of Activated Carbon To Produce A Final Product Comprising 2,3,3,3-Tetrafluoro-1-Propene.