专利号:US-2005209355-A1 优先权日:2004-03-22 标 题:[Novel Reactions and the Products of Such Reactions] 发明人:ROITMAN LIPA L 权利人:ROITMAN LIPA L 摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.
专利号:WO-2015131100-A1 优先权日:2014-02-28 标题:Ligand-controlled c(sp3)-h arylation and olefination in synthesis of unnatural chiral alpha amino acids 发明人:YU JIN-QUAN 权利人:SCRIPPS RESEARCH INST 摘要:The use of ligands to tune the reactivity and selectivity of transition metal-catalysts for C(-sp3)-H bond functionalization is a central challenge in synthetic organic chemistry. Herein, we report a rare example of catalyst-controlled C(sp3)-H arylation using pyridine and quinoline derivatives: the former promotes exclusive monoarylation, whereas the latter activates the catalyst further to achieve diarylation. Successive application of these ligands enables the sequential diarylation of a methyl group in an alanine derivative with two different aryl iodides, affording a wide range of β-Ar-p-Ar ' -cc-amino acids with excellent levels of diastereoselectivity (d.r. > 20:1). Both configurations of the β-chiral center can be accessed by choosing the order in which the aryl groups are installed. The use of a quinoline derivative as a ligand also enables C(sp3)-H olefination of a protected alanine.
专利号:US-11862794-B2 优先权日:2020-05-06 标题:Cost effective synthesis of oxide materials for lithium ion batteries
专利号:US-2024351913-A1 优先权日:2020-05-06 标 题 :Cost effective synthesis of oxide materials for lithium ion batteries
专利号:US-12211999-B2 优先权日:2020-05-06 标题:Cost effective synthesis of oxide materials for lithium ion batteries 发明人:XIAO JIE; BI YUJING 权利人:BATTELLE MEMORIAL INSTITUTE 摘要:Methods for synthesizing single crystalline Ni-rich cathode materials are disclosed. The Ni-rich cathode material may have a formula LiNi X Mn y M z Col 1-x-y-z O 2 , where M represents one or more dopant metals, x≥0.6, 0.01≤y<0.2, 0≤z≤0.05, and x+y+z≤1.0. The methods are cost-effective, and include methods for solid-state, molten-salt, and flash-sintering syntheses.
专利号:US-2024088382-A1 优先权日:2020-05-06 标题 :Cost effective synthesis of oxide materials for lithium ion batteries
[参考文献]: M Friedman, Et Al. Reactions Of Proteins With Ethyl Vinyl Sulfone. Int J Pept Protein Res. 1975;7(6):481-6. [参考文献]: M M Millard, Et Al. X-Ray Photoelectron Spectroscopy Of Bsa And Ethyl Vinyl Sulfone Modified Bsa. Biochem Biophys Res Commun. 1976 May 17;70(2):445-51.
合成参考文献
摘要:Kawęcki, R., Science of Synthesis Knowledge Updates, (2018) 4, 314. 摘要:Bronger, R. P. J.; Kamer, P. C. J.; Vogt, D., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 1, 38. 摘要:Zhu, S., Science of Synthesis: Special Topics, (2022) 1, 528.