CAS: 1314-84-7; Zinc Phosphide

该化合物是一种无机化合物,其特点是深灰色至黑色外观,主要以其用作杀灭鼠剂和杀虫剂而闻名,是一种由锌和磷组成的二元化合物,具有晶状结构.锌磷酸在水中是溶解的,但与硫酸反应后释放磷酸气体,这种气体毒性很高.该化合物以其相对于其他杀菌剂对哺乳动物的毒性相对较低而著称,但它对非目标物种和环境构成重大风险.它具有高熔点,在正常条件下保持稳定,尽管在接触水分解时,它能够分解水分,由于其毒性,处理锌磷化物需要谨慎,在许多管辖区受到管制.其应用范围超出虫害控制范围,因为研究还研究了在半导体技术中的潜在用途,以及作为其他含磷化合物合成的前体.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

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    专利信息


    专利号:US-2018076373-A1
    优先权日:2016-09-13
    标题 :SOLUTION PHASE SYNTHESIS OF HIGHLY PROCESSIBLE NANOCRYSTALLINE LiZnP AND SIMILAR TERNARY SEMICONDUCTORS
    发明人:Vela-Becerra Javier; White Miles Arthur Burris; THOMPSON MICHELLE JOANN; MILLER GORDON J
    权利人:VELA BECERRA JAVIER; White Miles Arthur Burris; THOMPSON MICHELLE JOANN; MILLER GORDON J; UNIV IOWA STATE RES FOUND INC
    摘要:Nowotny-Juza phases offer a wide range of potential applications including solar cell and thermoelectric device fabrication. The disclosure presents a solution phase synthesis of the Nowotny-Juza semiconductors LiZnP, LiCdP, and LiZnSb. These samples are phase pure, crystalline, and exhibit particle sizes of around 20 nm.

    专利号:US-2024097109-A1
    优先权日:2021-02-11
    标 题:Bottom-Up, Scalable Synthesis Of Oxide-Based Sub-Nano And Nanofilaments And Nanofilament-Based Two-Dimensional Flakes And Mesoporous Powders
    发明人:BARSOUM MICHEL W; BADR HUSSEIN OSAMA
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert—through a bottom-up approach—binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into lepidocrocitic nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can comprise nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances.

    专利号:WO-2022174264-A1
    优先权日:2021-02-11
    标题:Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders
    发明人:BADR HUSSEIN O; BARSOUM MICHEL W
    权利人:UNIV DREXEL
    摘要:Provided are methods to convert - through a bottom-up approach – binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can be C-containing anatase-based layers that are in turn comprised of nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances. Electrodes made from these materials performed well in energy systems. The materials also reduce the viability of some cancer cells. Also provided are mesoporous materials, devices, and related methods.

    专利号:US-5350540-A
    优先权日:1992-10-22
    标题 :Method of making alkaline earth metal halophosphate phosphor using metal phosphide reducing agent
    发明人:CHAU CHUNG-NIN
    权利人:OSRAM SYLVANIA INC
    摘要:Metal phosphide used as a raw material in the synthesis of alkaline earth metal halophosphate phosphor activated by antimony and manganese acts as a reducing agent to prevent oxidation of the antimony and manganese. The result is maximum availability of trivalent antimony and divalent manganese for incorporation into the phosphor lattice.

    专利号:US-9790093-B2
    优先权日:2016-01-19
    标题:High-yield synthesis of nanostructured boron phosphide by a pyrotechnic method
    发明人:LUAN ZHAOHUA; MORRIS LAUREN A; SHAW ANTHONY P; HAINES CHRISTOPHER D; PORET JAY C
    权利人:US ARMY
    摘要:A simplified method for synthesizing boron phosphide at high yields. The method requires mixing of boron phosphate and magnesium metal without diluents into a homogenous mixture, loosely packing the mixture at less than 20,000 psi and igniting the mixture using an energy input that is not greater than 20% of the reaction energy output to create a self-propagating high-temperature reaction wherein the boron phosphate and magnesium metal is completely burned during the reaction to synthesize boron phosphide at high yields.

    专利号:US-8801979-B2
    优先权日:2010-06-10
    标题:Apparatus and method for continuous production of materials
    发明人:CHANG CHIH-HUNG; JIN HYUNGDAE
    权利人:CHANG CHIH-HUNG; JIN HYUNGDAE; OREGON STATE
    摘要:Embodiments of a continuous-flow injection reactor and a method for continuous material synthesis are disclosed. The reactor includes a mixing zone unit and a residence time unit removably coupled to the mixing zone unit. The mixing zone unit includes at least one top inlet, a side inlet, and a bottom outlet. An injection tube, or plurality of injection tubes, is inserted through the top inlet and extends past the side inlet while terminating above the bottom outlet. A first reactant solution flows in through the side inlet, and a second reactant solution flows in through the injection tube(s). With reference to nanoparticle synthesis, the reactant solutions combine in a mixing zone and form nucleated nanoparticles. The nucleated nanoparticles flow through the residence time unit. The residence time unit may be a single conduit, or it may include an outer housing and a plurality of inner tubes within the outer housing.
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    合成参考文献


    摘要:Malaysian Agricultural Journal., 52(2)(166), 1979
    摘要:Yakkyoku. Pharmacy., 27(189), 1976
    摘要:Yakkyoku. Pharmacy., 31(1247), 1980
    摘要:Agrochemicals Handbook, with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86, A421(1984)
    摘要:Yakkyoku. Pharmacy., 30(397), 1979
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