CAS: 13433-42-6; Dimethyl ((Trimethylsilyl)Methyl)Phosphonate

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上下游产品

methanol (trimethylsilanyl-methyl)-phosphonic acid-dichloride chloro-trimethyl-silane dimethyl methane phosphonate1-tert-butyl-4-methylenecyclohexane dimethyl 2,2-diphenyl-2-(trimethylsiloxy)ethylphosphonate 1,1-Diphenylethylene dimethyl 2,2-diphenylethenylphosphonate

合成工艺路线路线简述

  • 合成目标产物 Dimethyl Trimethylsilylmethylphosphonate 主要起始原料 Chlorotrimethylsilane And Dimethyl Methylphosphonate
  • (文献来源)合成步骤主要原料 Chlorotrimethylsilane 和 Dimethyl Methylphosphonate
📜Dimethyl Lithium(Trimethylsilyl)Methylphosphonate置于盐酸体系中,化学反应生成三甲硅基甲基膦酸二甲酯
参考文献:A One Step Generation Of α-Lithiotrimethylsilylalkanephosphonates. A New Preparative Route To Dialkyl 1-(Trimethylsilyl)Alkanephosphonates And Vinylphosphonates
标题:A One Step Generation Of α-Lithiotrimethylsilylalkanephosphonates. A New Preparative Route To Dialkyl 1-(Trimethylsilyl)Alkanephosphonates And Vinylphosphonates
摘要:
Doi:10.1055/s-1986-31828

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✅ COA系统入驻 | 共享模式

主要参考文献

参考标题:Total Synthesis And Structural Revision Of Chaetoviridins A
作者:Mehdi Makrerougras,Romain Coffinier,Samuel Oger,Arnaud Chevalier,Cyrille Sabot,Xavier Franck |发布日期:2017.8.4
摘要:The First Synthesis Of The Proposed Structures Of Chaetoviridins A 1-4 Has Been Achieved In 10 Steps By Controlling The Syn- Or Anti-Aldol Side Chain. The Angular Lactone Has Been Regioselectively Introduced By Condensation Of A Chiral Dioxin-4-One To Cazisochromene. Comparison Of The Nmr And Circular Dichroism Data Of The Synthesized And Reported Natural Products Led To The Complete Reassignment And

合成参考文献

合成方法参考DOI号:10.1021/acs.j°C.5b00039
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