专利号:US-5877337-A 优先权日:1997-03-20 标 题 :Process for preparing alkylchlorosilanes from the residues of direct synthesis of alkylchlorosilanes 发明人:MAUTNER KONRAD; SCHINABECK ANTON; STRAUSSBERGER HERBERT 权利人:WACKER CHEMIE GMBH 摘要:Alkylchlorosilanes are prepared continuously from the residue of direct synthesis of alkylchlorosilanes containing liquid constituents with a boiling point of at least 70 DEG C. at 1013 hPa and solid constituents, by heating the residue with hydrogen chloride at temperatures of from 300 DEG C. to 800 DEG C. in a tubular reactor with internals which can be rotated.
专利号:US-8637695-B2 优先权日:2011-12-30 标 题:Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue 发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID 权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC 摘要:Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.
专利号:US-8207366-B2 优先权日:2008-02-26 标题:Method for producing alkyl chlorosilanes from the residues of the direct synthesis of alkyl chlorosilanes 发明人:BOECK MANFRED; FUCHS PAUL; MAUTNER KONRAD 权利人:BOECK MANFRED; FUCHS PAUL; MAUTNER KONRAD; WACKER CHEMIE AG 摘要:High boiling residue from the direct synthesis of alkylchlorosilanes are converted in large part to monosilanes by heating the residue by passage of alternating current in a pressurized reactor.
专利号:US-6344578-B1 优先权日:2000-08-10 标题 :Process for working up residues from the direct synthesis of organochlorosilanes 发明人:MAUTNER KONRAD; KOEHLER BERND; TAMME GUDRUN 权利人:WACKER CHEMIE GMBH 摘要:The invention relates to a process for preparing alkylchlorosilanes from the liquid constituents of the residues from the direct synthesis of alkylchlorosilanes which have a boiling point of above 70° C. at 1013 hPa and comprise disilanes, in which the residues are heated with hydrogen chloride and silicon at temperatures of at least 300° C., with at least 10% by weight of trichlorosilane and/or tetrachlorosilane, based on the weight of the alkylchlorosilanes formed, being formed at the same time.
专利号:US-4289890-A 优先权日:1979-02-12 标 题:Synthesis of chloromethyldisilanes 发明人:GORDON ROY G 权利人:GORDON ROY G 摘要:1,2 Dichloro-1,1,2,2-tetramethyldisilane is synthesized in high yield and good purity starting from a crude mixture of chloromethyldisilanes formed as by-products in the manufacture of silicones. The new method uses less than half as much Grignard reagent as previous methods required. The synthesis can also be used to produce other haloalkyldisilanes such as chloropentamethyldisilane or 1,1,2 trichloro-1,2,2-trimethyldisilane.
专利号:US-11691883-B2 优先权日:2018-09-10 标题:Synthesis of trichlorosilane from tetrachlorosilane and hydridosilanes 发明人:AUNER NORBERT; STURM ALEXANDER G 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The invention relates to a process for the preparation of trichlorosilane (HSiCl3) which comprises the reaction of tetrachlorosilane (SiCU) with hydridosilanes in the presence of a catalyst.