CAS: 4519-28-2; Tetramethylphosphonium Bromide

该化合物是一种四甲基铵盐,其特点是磷化,由磷原子质结合到四甲基组和一种溴阴离子组成;该化合物通常是在水和酒精等极地溶剂中溶解的白晶状固体,在各种化学应用中有用;TMPB因其作为分阶段转移催化剂的作用而著称,它促进在非强迫阶段之间转移离子或分子,这在有机合成中特别宝贵;此外,它可以作为各种反应中四甲基磷-磷-磷离子的来源,包括核循环生物替代物;在标准条件下,该化合物相对稳定,但应谨慎处理,因为其潜在的毒性和刺激性能;其应用范围包括有机化学,材料科学和生物化学等领域,它有助于提高反应效率和产量.

结构式图片

相似化合物

1941-19-1 993-11-3

欧盟法规

ECHA物质C&L通报

上下游产品

methyl bromide methylmagnesium bromidetrimethyl(methylene)phosphorane N,N-diphenyl-N-(4-vinylphenyl)amine 4-[N,N-bis-(3,4-dimethylphenyl)-amino] styrene (3S)-3-allyl-1-methyl-3-phenyl-1,3-dihydroindol-2-one

合成工艺路线路线简述

    甲基溴化镁置于三氯化磷体系中,用 乙醚 作为反应溶剂,化学反应生成 四甲基溴化磷
    参考文献:Alkaline Cleavage Reactions Of Tetraalkylphosphonium Salts
    标题:Alkaline Cleavage Reactions Of Tetraalkylphosphonium Salts
    摘要:
    DOI:10.1021/ja00782A035

    专利信息


    专利号:US-2008103312-A1
    优先权日:2006-08-29
    标 题:Processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole
    发明人:KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D
    权利人:KANSAL VINOD K; MISTRY DHIRENKUMAR N; VASOYA SANJAY L; LUNAGARIYA VIJAYKUMAR D
    摘要:Provided are processes for the synthesis of 5-phenyl-1-trityl-1H-tetrazole, an intermediate useful in the synthesis of irbesartan.

    专利号:US-5853555-A
    优先权日:1997-04-03
    标 题:Synthesis of onium hydroxides from onium salts
    发明人:SHARIFIAN HOSSEIN; HULME DAVID R
    权利人:SACHEM INC
    摘要:The present invention provides a process for preparing onium hydroxide from a corresponding onium salt and for purifying onium hydroxide including providing an electrochemical cell containing a cathode, an anode, a divider and a bipolar membrane, the bipolar membrane having an anion selective side facing the anode and a cation selective side facing the cathode, wherein the divider is positioned between the cathode and the bipolar membrane, and the bipolar membrane is positioned between the divider and the anode, thereby defining a feed compartment between the divider and the bipolar membrane, a recovery compartment between the divider and the cathode, and a water compartment between the bipolar membrane and the anode; charging a solution containing at least one of the onium salt and the onium hydroxide to be purified to the feed compartment; charging a liquid electrolyte to the other compartments; passing a current through the electrochemical cell to produce the onium hydroxide in the recovery compartment; and recovering the onium hydroxide from the recovery compartment.

    专利号:US-4270015-A
    优先权日:1979-02-05
    标题:Manufacture of ethylene from synthesis gas (D#75,673-C1)
    发明人:KNIFTON JOHN F
    权利人:TEXACO INC
    摘要:This invention concerns a two-step process for the preparation of ethylene from mixture of carbon monoxide and hydrogen (commonly known as synthesis gas) by reaction of said carbon monoxide/hydrogen mixtures with a carboxylic acid in the presence of one or more ruthenium catalyst complexes to form an ethyl ester of said carboxylic acid coreactant, followed by pyrolysis of said ethyl ester intermediate to ethylene.

    专利号:US-2008214386-A1
    优先权日:2004-03-01
    标题:Catalyst for Cyclic Carbonate Synthesis
    发明人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
    权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU
    摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.

    专利号:WO-9844169-A1
    优先权日:1997-04-03
    标 题:Synthesis of onium hydroxides from onium salts

    专利号:EP-1931648-A2
    优先权日:2006-08-29
    标 题 :Processes for the synthesis of 5-phenyl -1 trityl-1h-tetrazole
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    合成参考文献

    合成方法参考DOI号:10.1021/ja00782a035
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