CAS: 34767-44-7; Cyclopentadienylzirconium Trichloride

该化合物是一个协调化合物,以为中央金属原子,其独特结构特征是,该化合物包括环开普丁二烯离心机,以5(eta 5)方式协调,这意味着环开普丁环环的所有五个碳原子都涉及与中心的联系;三种氯原子作为离心机的存在有助于其再活动性和溶解性.这种化合物通常用于有机金属化学和催化,特别是在聚合过程中.由于对水分和空气的敏感性,该化合物往往在惰性大气中处理,这可能导致水解或氧化.其应用可能扩大到先进材料的合成和各种化学反应催化剂的开发.

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    专利信息


    专利号:US-2008086013-A1
    优先权日:2006-06-15
    标 题:Carbometallation of alkynes and improved synthesis of uniquinones
    发明人:LIPSHUTZ BRUCE H
    权利人:UNIV CALIFORNIA
    摘要:Methods for the carbometallation of alkynes are presented. Those are useful for the synthesis of CoQ 10 and other ubiquinones as well as for the synthesis of ubiquinol analogs.

    专利号:US-2006167289-A1
    优先权日:2003-12-05
    标题 :Practical, cost-effective synthesis of ubiquinones
    发明人:LIPSHUTZ BRUCE H; BERL VOLKER; SCHEIN KARIN; WETTERICH FRANK
    权利人:ZYMES LLC
    摘要:The present invention provides a convergent method for the synthesis of ubiquinones and ubiquinone analogues. Also provided are precursors of ubiquinones and their analogues that are useful in the methods of the invention. The invention further provides an improved method for the carboalumination of alkyne substrates.

    专利号:US-2009131705-A1
    优先权日:2005-12-15
    标 题 :Practical, Cost-Effective Synthesis of Ubiquinones

    专利号:US-6114555-A
    优先权日:1998-04-29
    标 题:Functionalized metallocene compounds, synthesis process and use thereof
    发明人:LLINAS GERARDO HIDALGO; LAFUENTE ANTONIO MUNOZ-ESCALON
    权利人:REPSOL QUIMICA SA
    摘要:The present invention relates to nietallocene compounds characterized by the following formulas: n n (LR.sub.k).sub.z [LR.sub.k-f (R.sup.I OH).sub.f ].sub.x MX.sub.yI n n ##STR1## wherein: L, equal to or different from each other, is selected from the group comprising: cyclopentadienyl, indenyl, tetrahydroindenyl, fluorenyl, octahydrofluorenyl or benzoindenyl; each R is independently selected from hydrogen, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 3 -C 20 alkenyl C 7 -C 20 arylalkyl, C 7 -C 20 alkylaryl, C 8 -C 20 arylalkenyl, linear or branched, optionally substituted by 1 to 10 halogen atoms, or a group SiR II 3 ; each R I equal to or different from each other, is a group SiR II 2 , or a divalent aliphatic or aromatic hydrocarbon group containing from 1 to 20 carbon atoms, optionally containing from 1 to 5 heteroatoms of groups 14 to 16 of the periodic table of the elements and boron; each Q is independently selected from B, C, Si, Ge, Sn; M is a metal of group 3, 4 or 10 of the Periodic Table, Laitlanide or Actinide; each X is independently selected from: hydrogen, chlorine, bromine, OR II , NR II 2 , C 1 -C 20 alkyl or C 6 -C 20 aryl; each R II is independently selected from C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 3 -C 20 alkenyl, C 7 -C 20 arylalkyl, C 7 -C 20 arylalkenyl or alkylaryl, linear or branched; R II is methyl, ethyl, isopropyl; L' is N or O.

    专利号:WO-2007078679-A2
    优先权日:2005-12-15
    标 题:Practical, cost-effective synthesis of ubiquinones

    专利号:JP-4120709-B2
    优先权日:1995-11-07
    标 题:Synthesis of organic diurethanes and / or polyurethanes and their use for the production of diisocyanates and / or polyisocyanates

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