专利号:US-2009318592-A1 优先权日:2005-10-11 标 题 :Process for the Synthesis of Amine Ethers 发明人:FREY MARKUS; BROENNIMANN VALERIE 权利人:CIBA GEIGY CORP 摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.
专利号:US-2007191516-A1 优先权日:2004-03-15 标题 :Process for the synthesis of amine ethers 发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS 摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.
专利号:US-6417363-B1 优先权日:1997-12-04 标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts 发明人:VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN 权利人:CIBA SC HOLDING AG 摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.
专利号:US-6077805-A 优先权日:1997-03-06 标题:Hexacoordinated ruthenium or osmium carbene catalysts 发明人:VAN DER SCHAAF PAUL ADRIAAN; HAFNER ANDREAS; MUEHLEBACH ANDREAS 权利人:CIBA SC HOLDING AG 摘要:Hexacoordinated ruthenium and osmium catalysts of the formulae in which M and M' independently of one another are ruthenium or osmium; X, X', Y and Y' independently of one another are anionic ligands, or X and Y and X' and Y' in each case together are bis-anionic ligands L1 and L1' independently of one another are tertiary phosphine; L2 and L3 independently of one another are a monodentate ligand, or L2 and L3 together are bidentate, neutral electron donor ligands; L4 is tetradentate, neutral electron donor ligand; L5 is a bidentate, neutral electron donor ligand; and T and T' indepedently of one another are H or organic substituents, are useful for the synthesis of custom-tailored polymers and for the ring-closing metathesis of olefins.
专利号:US-2003171461-A1 优先权日:2000-05-26 标 题 :Process for the synthesis of amine ethers from secondary amino oxides
专利号:US-2009069470-A1 优先权日:2004-11-02 标 题 :Process for the synthesis of n-alkoxyamines
[参考文献]: A Iwado, Et Al. Catalytic Activity Of Anion-Exchange Resins Modified With Metal-Porphine In Oxidative Reactions Of Phenols. Chem Pharm Bull (Tokyo). 2000 Nov;48(11):1831-2. [参考文献]: H Verhagen, Et Al. Sensitive High-Performance Liquid Chromatographic Method For The Routine Determination Of Butylated Hydroxyanisole In Plasma. J Chromatogr. 1987 Jan 23:413:282-6. [参考文献]: T Mizutani, Et Al. Protective Effects Of Butylated Hydroxyanisole And Its Analogs On The Lung Toxicity Of Butylated Hydroxytoluene In Mice. Res Commun Chem Pathol Pharmacol. 1985 Oct;50(1):125-33.
合成参考文献
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198