CAS: 149104-90-5; 4-Acetylphenylboronic Acid

上下游产品

4-Iodoacetophenone 1-bromo-4-(1,1-diethoxyethyl)benzene para-bromoacetophenone (4-(1-hydroxyethyl)phenyl)boronic acid 1-(4'-methoxy-biphenyl-4-yl)-ethanone 4-acetyl-2'-methylbiphenyl 4,4'-diacetylbiphenyl (4-acetylphenyl)(phenyl)methanol

4-(1-羟基乙基)苯硼酸置于c25H43Mono6*h2O体系中,用 水 用作溶剂,以81 %的收率获得4-乙酰基苯硼酸
参考文献:A Metallomicellar Catalyst For Controlled Oxidation Of Alcohols And Lignin Mimics In Water Using Open Air As Oxidant
标题:A Metallomicellar Catalyst For Controlled Oxidation Of Alcohols And Lignin Mimics In Water Using Open Air As Oxidant
摘要:摘要 醇基和 β-O-4 (C-C) 链广泛存在于生物质原料中,它们是丰富的可再生增值化学品资源.利用露天空气作为氧化剂,以可控方式开发原料材料的直接氧化或氧化裂解的可持续方案,是生产具有重要工业价值的羰基化合物的一项具有启发性的任务.此外,将木质素氧化解聚成精细化学品近来也引起了人们的兴趣.在此,我们报告了首个催化剂系统实例,该催化剂系统可激活大气中的分子氧,在露天条件下对醇类,β-O-4(c-C)连接和水中真正的木质素等原料进行受控氧化和氧化裂解/解聚.羰基产物的选择性可通过在 ~7.0 和 ~12.0 之间改变 Ph 值来控制.目前的策略突出了不使用任何外部助催化剂,氧化剂,自由基添加剂和/或破坏性有机溶剂的特点.该催化剂具有广泛的底物范围和出色的官能团耐受性.使用廉价的催化剂和易于获得的氧化剂进行多克级合成,证明了所开发方案的实用性.在一些对照实验,动力学和计算研究的帮助下,我们提出了一种合理的机制.
Doi:10.1002/cssc.202301754

专利信息

专利号:US-2022411860-A1
优先权日:2015-09-28
标题:Design and synthesis of novel disulfide linker based nucleotides as reversible terminators for dna sequencing by synthesis

专利号:US-2023160000-A1
优先权日:2015-09-28
标 题:Synthesis of novel disulfide linker based nucleotides as reversible terminators for dna sequencing by synthesis

专利号:WO-2023179723-A1
优先权日:2022-03-25
标题:Cleavable fragment directed by affinity fragment, design and synthesis thereof, and use thereof in preparation of site-directed drug conjugate
发明人：HUANG WEI; TANG FENG; ZENG YUE
权利人:SHANGHAI INST MATERIA MEDICA CAS
摘要:Provided in the present invention are a cleavable fragment directed by an affinity fragment, the design and the synthesis thereof, and the use thereof in the preparation of a site-directed drug conjugate. Specifically, provided in the present invention is a conjugate with a ligand affinity directing group. The conjugate is as represented by formula I: AT-CL-R (I), wherein AT is an affinity moiety for a target protein (TP); CL is a cleavable fragment which has a self-cleaving reactivity; and R is a group to be modified to the target protein.

专利号:US-2023028388-A1
优先权日:2015-09-28
标 题 :Design and synthesis of novel disulfide linker based nucleotides as reversible terminators for dna sequencing by synthesis

专利号:US-11085076-B2
优先权日:2015-09-28
标 题 :Synthesis of novel disulfide linker based nucleotides as reversible terminators for DNA sequencing by synthesis

专利号:CN-114634407-A
优先权日:2020-12-16
标题 :A kind of method for stereospecific synthesis of 2-alkenal, 2-enone compound and deuterated compound thereof