CAS: 84494-81-5; Tert-Butyldimethyl(4-Vinylphenoxy)Silane

该化合物是硅氧烷经改造的苯乙烯化合物,其特征是,在苯乙烯环的副位置上有一个与苯乙烯环的副位置相连的t-丁基二甲基硅氧基化合物组,这种改变增强了化合物的热稳定性,疏水性,以及与各种聚合物的兼容性,使其在粘合剂,涂层和密封剂等应用中有用.硅氧组有助于增强灵活性和对环境因素的抗药性,而苯乙烯的粘性则提供了僵硬性和强度.该化合物通常具有较低的挥发性性和良好的化学抗药性,在工业配方中具有优势.此外,其独特的结构允许在需要提高性能特性的地方,在特殊聚合物和合成物和合成物中的潜在用途.

结构式图片

物理性质

MSDS等安全信息

上下游产品

4-hydroxy-benzaldehyde tert-butyldimethylsilyl chloride p-[(tert-butyldimethylsilyl)oxy]benzaldehyde methyl iodide1-(4-((tert-butyldimethylsilyl)oxy)phenyl)-3,3,3-trifluoropropyl 2-iodobenzoate 21H28O3SSiC21H28O3SSi 21H28O3SSiC21H28O3SSi

合成工艺路线路线简述

  • 18162-48-6 + 2628-17-3 = 84494-81-5
    反应条件:1.1 Reagents: Imidazole Solvents: Dimethylformamide; 0 °C; 0 °C -> Rt; Overnight,Rt
    标题:Controlled Delivery Of Paclitaxel From Stent Coatings Using Poly(Hydroxystyrene-B-Isobutylene-B-Hydroxystyrene) And Its Acetylated Derivative
    作者:Sipos,Laszlo; Et Al
    参考文献:Biomacromolecules 日期:2005 卷标:6(5) 页码:2570-2582]

    18162-48-6 + 2628-17-3 = 84494-81-5
    反应条件:1.1 Reagents: Imidazole Solvents: Dichloromethane; 16 H,Rt
    标题:Selective And Orthogonal Post-Polymerization Modification Using Sulfur(Vi) Fluoride Exchange (Sufex) And Copper-Catalyzed Azide-Alkyne Cycloaddition (Cuaac) Reactions
    作者:Oakdale,James S.; Et Al
    参考文献:Macromolecules (Washington 日期:2016 卷标:49(12) 页码:4473-4479]

    1779-49-3 + 120743-99-9 = 84494-81-5
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 0 °C; 15 Min,0 °C1.2 Solvents: Tetrahydrofuran; 0 °C; 4 H,0 °C1.3 Reagents: Ammonium Chloride
    标题:Synthesis Of Amphiphilic Diblock Copolymers Of Isotactic Polystyrene-Block-Isotactic Poly(P-Hydroxystyrene) Using A Titanium Complex With An [osso]-Type Bis(Phenolate) Ligand And Sequential Monomer Addition
    作者:Zhou,Qi Hua; Et Al
    参考文献:Rsc Advances 日期:2017 卷标:7(32) 页码:19885-19893]

    1779-49-3 + 18162-48-6 + 123-08-0 = 84494-81-5
    反应条件:1.1 Reagents: Imidazole Solvents: Tetrahydrofuran; 4 H,Rt1.2 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; Overnight,Rt
    标题:Metallocene-Mediated Synthesis Of Chain-End Functionalized Polypropylene And Application In Pp/clay Nanocomposites
    作者:Chung,T. C.
    参考文献:Journal Of Organometallic Chemistry 日期:2005 卷标:690(26) 页码:6292-6299]

    488814-77-3 = 84494-81-5
    反应条件:1.1 Reagents: Dimethylglyoxime Catalysts: Cobalt Diacetate,2-Chloroanthraquinone Solvents: 1,2-Dichloroethane; 30 Min,Rt; 36 H,Rt
    标题:Site-Selective Acceptorless Dehydrogenation Of Aliphatics Enabled By Organophotoredox/cobalt Dual Catalysis
    作者:Zhou,Min-Jie; Et Al
    参考文献:Journal Of The American Chemical Society 日期:2021 卷标:143(40) 页码:16470-16485]

    120743-99-9 + 74-95-3 = 84494-81-5
    反应条件:1.1 Reagents: Acetyl Chloride,Zinc Solvents: Dimethylformamide
    标题:Method For Producing Hydroxystyrene Derivatives From Hydroxybenzaldehyde Derivatives And Dibromomethane
    参考文献:Japan]

    2628-16-2 + 18162-48-6 = 84494-81-5 [标题:Reaction Conditions
    标题:Synthesis Of Amphiphilic Block Copolymers Of 4-Substituted Styrene And Cyclohexene Oxide Utilizing Radical/cation Transformation Polymerization
    作者:Hashidzume,Akihito; Et Al
    参考文献:Macromolecules 日期:2002 卷标:35(13) 页码:5326-5330]

    18162-48-6 + 123-08-0 = 84494-81-5
    反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 10 Min,Rt1.2 Solvents: Dichloromethane; Rt; 2 H,Rt1.3 Reagents: Water; Rt2.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; Cooled; 10 Min,Cooled2.2 Solvents: Tetrahydrofuran; Cooled; 4 H,Cooled2.3 Reagents: Ammonium Chloride
    标题:Synthesis And Characterization Of Isotactic Poly(P-Hydroxystyrene)- Block-1,4-Trans-Polybutadiene By Sequential Monomer Addition Using Titanium Complex With An [osso]-Type Bis(Phenolate) Ligand
    作者:Liang,Huaqing; Et Al
    参考文献:Journal Of Polymer Research 日期:2019 卷标:26(1) 页码:1-6]

    2628-16-2 = 84494-81-5
    反应条件:1.1 Reagents: Lithium Hydroxide Solvents: Methanol,Tetrahydrofuran,Water; 4 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water; Neutralized,Rt2.1 Reagents: Imidazole Solvents: Dichloromethane; 16 H,Rt
    标题:Selective And Orthogonal Post-Polymerization Modification Using Sulfur(Vi) Fluoride Exchange (Sufex) And Copper-Catalyzed Azide-Alkyne Cycloaddition (Cuaac) Reactions
    作者:Oakdale,James S.; Et Al
    参考文献:Macromolecules (Washington 日期:2016 卷标:49(12) 页码:4473-4479]

    2628-16-2 = 84494-81-5
    反应条件:1.1 -2.1 Reagents: Imidazole Solvents: Dimethylformamide; 1 H,0 °C; Overnight2.2 Solvents: Dichloromethane
    标题:Synthesis And Cross-Linking Of Copolymers Containing Dithiocarbonate And Phenol Moieties
    作者:Yukiko,Inoue; Et Al
    参考文献:Nettowaku Porima 日期:2016 卷标:37(3) 页码:116-121]

    18162-48-6 + 2628-17-3 = 84494-81-5
    反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 3 H,Rt
    标题:Total Synthesis Of Gombamide A
    作者:Garcia-Barrantes,Pedro M.; Et Al
    参考文献:Organic Letters 日期:2016 卷标:18(15) 页码:3810-3813]

    18162-48-6 + 7400-08-0 = 84494-81-5
    反应条件:1.1 Reagents: Triethylamine Solvents: Dimethylformamide; Rt -> 100 °C; 0 °C1.2 24 H; 20 °C1.3 Solvents: Water; Cooled
    标题:Bio-Based Vinylphenol Family: Synthesis Via Decarboxylation Of Naturally Occurring Cinnamic Acids And Living Radical Polymerization For Functionalized Polystyrenes
    作者:Takeshima,Hisaaki; Et Al
    参考文献:Journal Of Polymer Science (Hoboken 日期:2020 卷标:58(1) 页码:91-100]

    1779-49-3 + 120743-99-9 = 84494-81-5
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; Cooled; 10 Min,Cooled1.2 Solvents: Tetrahydrofuran; Cooled; 4 H,Cooled1.3 Reagents: Ammonium Chloride
    标题:Synthesis And Characterization Of Isotactic Poly(P-Hydroxystyrene)- Block-1,4-Trans-Polybutadiene By Sequential Monomer Addition Using Titanium Complex With An [osso]-Type Bis(Phenolate) Ligand
    作者:Liang,Huaqing; Et Al
    参考文献:Journal Of Polymer Research 日期:2019 卷标:26(1) 页码:1-6]

    1779-49-3 + 120743-99-9 = 84494-81-5
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane; 10 Min,Cooled1.2 Solvents: Tetrahydrofuran; 4 H,Rt1.3 Reagents: Ammonium Chloride
    标题:Titanium Complex With An [osso]-Type Bis(Phenolate) Ligand For Ethylene Copolymerization With Vinyl Polar Monomer Based On Group Protection
    作者:Zhu,Yuqiong; Et Al
    参考文献:Rsc Advances 日期:2019 卷标:9(46) 页码:26582-26587]

    120743-99-9 + 67719-69-1 = 84494-81-5 [标题:Reaction Conditions
    标题:μ-Chlorobis(Cyclopentadienyl) (Dimethylaluminum)-μ-Methylenetitanium
    作者:Straus,Daniel A.; Et Al
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2006 卷标:1 页码:1-12]

    120743-99-9 = 84494-81-5
    反应条件:1.1 Reagents: Diphenylsilane,Carbonic Acid,Mono(1,1-Dimethylethyl) Ester,Sodium Salt (1:1) Catalysts: 9-Phosphabicyclo[4.2.1]Nonane,9-[4-(Trifluoromethyl)Phenyl]-,9-Oxide,(9-Anti)... Solvents: Toluene; 1 H,140 °C; 140 °C -> Rt1.2 Reagents: Carbonic Acid,Mono(1,1-Dimethylethyl) Ester,Sodium Salt (1:1); Rt -> 140 °C; 4 H,140 °C; 24 H,140 °C
    标题:Catalytic Wittig Reactions Of Semi- And Nonstabilized Ylides Enabled By Ylide Tuning
    作者:Coyle,Emma E.; Et Al
    参考文献:Angewandte Chemie 日期:2014 卷标:53(47) 页码:12907-12911]

    120743-99-9 = 84494-81-5 [标题:Reaction Conditions
    标题:Selective Synthesis Of Secondary Alkylboronates: Markovnikov-Selective Hydroboration Of Vinylarenes With Bis(Pinacolato)Diboron Catalyzed By A Nickel Pincer Complex
    作者:Hashimoto,Toru; Et Al
    参考文献:Organic Letters 日期:2020 卷标:22(10) 页码:4033-4037]

    120743-99-9 = 84494-81-5 [标题:Reaction Conditions
    标题:Bottleable Nicl2(Dppe) As A Catalyst For The Markovnikov-Selective Hydroboration Of Styrenes With Bis(Pinacolato)Diboron
    作者:Hashimoto,Toru; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2020 卷标:56(78) 页码:11701-11704]

    1779-49-3 + 123-08-0 = 84494-81-5
    反应条件:1.1 Reagents: Potassium Tert-Butoxide Solvents: Tetrahydrofuran; 10 Min,Rt1.2 Solvents: Tetrahydrofuran; Rt; 16 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water; Rt2.1 Reagents: Triethylamine Solvents: Dichloromethane; 3 H,Rt
    标题:Total Synthesis Of Gombamide A
    作者:Garcia-Barrantes,Pedro M.; Et Al
    参考文献:Organic Letters 日期:2016 卷标:18(15) 页码:3810-3813]

    7400-08-0 = 84494-81-5
    反应条件:1.1 Reagents: Triethylamine Solvents: Dimethylformamide; Rt; 24 H2.1 0 °C; 24 H,20 °C2.2 Solvents: Water; Cooled
    标题:Bio-Based Vinylphenol Family: Synthesis Via Decarboxylation Of Naturally Occurring Cinnamic Acids And Living Radical Polymerization For Functionalized Polystyrenes
    作者:Takeshima,Hisaaki; Et Al
    参考文献:Journal Of Polymer Science (Hoboken 日期:2020 卷标:58(1) 页码:91-100
📜4-香豆酸置于三乙胺体系中,用 N,N-二甲基甲酰胺 作为反应溶剂,化学反应 48.0H,反应生成 (对乙烯基苯氧基)叔丁基二甲基硅烷
参考文献:生物基乙烯基苯酚家族:通过天然肉桂酸的脱羧反应和官能化聚苯乙烯的活性自由基聚合合成
标题:生物基乙烯基苯酚家族:通过天然肉桂酸的脱羧反应和官能化聚苯乙烯的活性自由基聚合合成
摘要:通过将各种天然存在的肉桂酸(例如o,M和p)简单地脱羧,可以制备一系列生物基乙烯基苯酚或羟基苯乙烯.-香豆; 咖啡的 阿魏的 和芥子酸,其在芳环的不同位置具有羟基和其他取代基.用三烷基甲硅烷基保护酚基部分后,用二硫代苯甲酸枯基酯完成可逆的加成-断裂链转移聚合反应,从而得到分子量可控且分子量分布窄的各种生物基羟基保护的聚苯乙烯.随后在温和条件下对甲硅烷基基团进行脱保护,得到一系列定义明确的官能化聚苯乙烯,它们在不同位置(o,M,P处具有不同数量(单,二,三)羟基).所获得的官能化聚苯乙烯根据取代基显示出独特的热性能,并且具有苯酚和邻苯二酚基团的那些充当银离子的还原剂.©2019 Wiley Periodicals,Inc.J.Polym.科学 2020,58,91-100
DOI:10.1002/pola.29453

海关参考信息

专利信息


专利号:US-2013196019-A1
优先权日:2010-03-18
标 题:Silicon-containing block co-polymers, methods for synthesis and use
发明人：WILLSON C GRANT; BATES CHRISTOPHER M; STRAHAN JEFFREY; ELLISON CHRISTOPHER JOHN; MUELLER BRENNEN
权利人:WILLSON C GRANT; BATES CHRISTOPHER M; STRAHAN JEFFREY; ELLISON CHRISTOPHER JOHN; MUELLER BRENNEN; NAT UNIVERSITY OF SINAPORE
摘要:The present invention describes the synthesis of silicon-containing monomers and copolymers. The synthesis of a monomer, trimethyl-(2-methylenebut-3-enyl)silane (TMSI) and subsequent synthesis of diblock copolymer with styrene, forming polystyrene-block-polytrimethylsilyl isoprene, and synthesis of diblock copolymer Polystyrene-block-polymethacryloxymethyltrimethylsilane or PS-b-P(MTMSMA). These silicon containing diblock copolymers have a variety of uses. One preferred application is as novel imprint template material with sub-100 nm features for lithography.

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合成参考文献


摘要:de Figueiredo, R. M., Science of Synthesis: Knowledge Updates, (2024) 2, 308.
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