CAS: 7797-81-1; N-Hydroxynaphthalimide

该化合物是一种多用途有机化合物,在合成化学中广泛用作中间体,特别是在染料,药品和光活材料的配制方面,其结构以一个带有非碘和氢氧功能组的氯化萘核心为特征,在氧化和激进反应中可以有选择性地反应.该化合物在普通有机溶剂中表现出极好的热稳定性和溶性,有助于将其纳入多种反应系统.它作为光化剂或聚合工艺催化剂的能力进一步增强了其在材料科学中的用途.N-Hydroxynthalimide因其在学术和工业应用中一贯的纯度和可靠性而受到重视.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号81-84-5 1,8-萘二甲酸酐 | CAS号81-83-4 1,8-萘二甲酰亚胺 | CAS号111063-75-3 2-(3-nitro-benz... | CAS号1830-56-4 1-ethylbenz[cd]... | CAS号6207-89-2 N,N-(1,8-萘基)羟胺钠盐 | CAS号130-00-7 1,8-萘内酰亚胺

合成工艺路线路线简述

  • 合成目标产物 N-Hydroxy-1,8-Naphthalimide 主要起始原料 1,8-Naphthalic Anhydride
  • (文献来源)合成步骤主要原料 1,8-Naphthalic Anhydride
在 羟胺体系中,用 乙腈 作为反应溶剂,以80%的收率获得产物n-羟基-1,8-萘二甲酰亚胺
参考文献:Mild And Convenient One Pot Synthesis Ofn-Hydroxyimides Fromn-Unsubstituted Imides
标题:Mild And Convenient One Pot Synthesis Ofn-Hydroxyimides Fromn-Unsubstituted Imides
摘要:A New,One Pot Synthesis Of Various N-Hydroxyimides From N-Unsubstituted Imides Is Described. Imides Are First Transformed Into Their N-Boc Derivatives,Which Are Next Reacted With Aqueous Hydroxylamine,Providing Crystalline Hydroxylammonium Salts Of The Corresponding N-Hydroxyimides. Filtration And Acidic Workup Affords Pure N-Hydroxyimides.
DOI:10.1081/scc-100103264

海关参考信息

专利信息


专利号:US-7628979-B1
优先权日:2005-04-20
标题 :Use of calco oil blue V in bait formulations for marking and controlling subterranean termites
发明人:MORALES-RAMOS JUAN A; ROJAS MARIA G
权利人:US AGRICULTURE
摘要:Termite bait matrix containing cellulose, calco oil blue V (solvent blue 58 or 9,10-anthracenedione, 1,4-bis[(2-ethylhexyl)amino]), and optionally a termite toxicant (e.g., chitin synthesis inhibitor). Methods of monitoring termite activity in a region involving placing a termite bait matrix in the region and assessing the presence of termites at the site of the termite matrix, the termite bait matrix contains cellulose and 9,10-anthracenedione, 1,4-bis[(2-ethylhexyl)amino]. Methods of killing termites, involving placing a termite bait matrix in a termite habitat and allowing termites to feed on the bait matrix, the termite bait matrix contains cellulose, 9,10-anthracenedione, 1,4-bis[(2-ethylhexyl)amino], and a termite toxicant (e.g., chitin synthesis inhibitor).

专利号:US-6160128-A
优先权日:1997-12-22
标题:Tritioacetylating reagents and processes for preparation thereof
发明人:SALJOUGHIAN MANOUCHEHR; MORIMOTO HIROMI; WILLIAMS PHILIP G; THAN CHIT
权利人:UNIV CALIFORNIA
摘要:Novel acetylating and tritioacetylating reagents suitable for preparation of nonlabelled and radiolabelled organic compounds. N-acetoxynaphthalimide, N-tritioacetoxyphthalimide, N-tritioacetoxysuccinimide, N-tritioacetoxynaphthalimide and processes of their preparation. The invention also concerns synthesis of nonlabelled acetylated and tritioacetylated organic compounds from precursors containing a free --NH 2 , --SH or --OH group.

专利号:US-6340734-B1
优先权日:1998-09-03
标题:Silsesquioxane polymers, method of synthesis, photoresist composition, and multilayer lithographic method
发明人:LIN QINGHUANG; ANGELOPOULOS MARIE; KATNANI AHMAD D; SOORIYAKUMARAN RATNAM
权利人:IBM
摘要:Novel silsesquioxane polymers are formed by methods which avoid the use of BBr 3 . The novel silsesquioxane polymers are especially useful in negative photoresist compositions and photolithographic processes. Alternatively, improved silsesquioxane polymer-containing negative photoresist compositions are obtained by using a polymer component containing a blend of silsesquioxane polymer and non-silsesquioxane polymer. The photoresist compositions provide improved dissolution characteristics enabling the use of 0.26N TMAH developer. The photoresist compositions also provide improved thermal characteristics enabling use of higher processing temperatures. The photoresist compositions are especially useful in a multilayer photolithographic processes and are capable of producing high resolution.

专利号:US-9499465-B2
优先权日:2013-03-15
标题 :Synthesis of biobased and substituted terephthalic acids and isophthalic acids
发明人:FROST JOHN W
权利人:UNIV MICHIGAN STATE
摘要:Methods for producing bio-terephthalic acid and bio-isophthalic acid are provided. The methods comprise a cycloaddition reaction to produce bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic from bio-isoprene and bio-acrylic acid. An aromatization reaction produces bio-para-toluic acid and bio-meta-toluic acid from the bio-4-methyl-3-cyclohexene-1-carboxylic acid, and bio-3-methyl-3-cyclohexene-1-carboxylic. An oxidation reaction produces the bio-terephthalic acid and iso-phthalic acid from the bio-para-toluic acid and bio-meta-toluic acid.

专利号:US-2016031787-A1
优先权日:2013-03-15
标 题 :Synthesis of biobased and substituted terephthalic acids and isophthalic acids

专利号:WO-2014144843-A1
优先权日:2013-03-15
标 题 :Synthesis of biobased terephthalic acids and isophthalic acids
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合成参考文献


参考文献:10.1016/j.bioelechem.2005.10.001
摘要:Shumakovich GP, Shleev SV, Morozova OV, Khohlov PS, Gazaryan IG, Yaropolov AI. Electrochemistry and kinetics of fungal laccase mediators. Bioelectrochemistry. 2006 Sep;69(1):16–24. doi: 10.1016/j.bioelechem.2005.10.001.
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