专利号:US-4303593-A 优先权日:1979-06-16 标 题 :Process for the dimerization of hexafluoropropene oxide 发明人:KUEHNE GERHARD 权利人:HOECHST AG 摘要:In the dimerization of hexafluoropropene oxide to give oligomeric acid fluorides of the formula the ratio of the oligomeric constituents formed is directed, in an improved manner, towards the formation of the dimer (n=0) if the reaction is carried out in the presence of a catalyst system which consists of a mixture of a copper (I) compound and a copper (II) compound mixed with a complex-forming agent from the group of the nitriles, isocyanides, tertiary phosphines and cyclic hydrocarbons with 6 to 12 ring atoms and 2 to 3 double bonds in the ring, and an aprotic organic solvent. The dimer is an intermediate product in the synthesis of perfluoropropyl perfluorovinyl ether, the latter being employed as a comonomer in fluorine-containing copolymers.
专利号:CA-2912893-C 优先权日:2008-06-11 标题 :Bromine-facilitated synthesis of fluoro-sulfur compounds
专利号:CA-2958407-C 优先权日:2008-06-11 标题:Bromine-facilitated synthesis of fluoro-sulfur compounds
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013. 摘要:ACGIH - Documentation of the TLVs and BEIs, 7th Ed. Cincinnati: ACGIH Worldwide, 2020. 摘要:National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review., 5(28), 1953