CAS: 7789-27-7; Thallium(I) Fluoride

该化合物是一种无机化合物,在专门的化学和光学领域有显著应用,在水中表现出高溶性,形成稳定的晶体结构,在某些合成工艺中有用.红外线透明性尤其受到重视,它有助于红外光学应用,如红外光谱和激光技术.它与有机化合物的反射性也使它成为选择性氟化反应的候选物.由于的毒性,处理需要严格的安全规程.然而,该化合物的独特特性证明,在需要精确的氟化或红外传输的受控研究和工业环境中使用该化合物是合理的.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

hydrogen fluoride Dichlorodifluoromethane mercury bis(trifluoromethanethiolate) Bromo-bis-(pentafluorphenyl)-thallium(III)[Tl(μ-F)3Ru(triphenylphosphine)3] 4P)[OsF3Br2(CO)]mer-(Ph4P)[OsF3Br2(CO)]

合成工艺路线路线简述

    专利信息


    专利号:US-4303593-A
    优先权日:1979-06-16
    标 题 :Process for the dimerization of hexafluoropropene oxide
    发明人:KUEHNE GERHARD
    权利人:HOECHST AG
    摘要:In the dimerization of hexafluoropropene oxide to give oligomeric acid fluorides of the formula the ratio of the oligomeric constituents formed is directed, in an improved manner, towards the formation of the dimer (n=0) if the reaction is carried out in the presence of a catalyst system which consists of a mixture of a copper (I) compound and a copper (II) compound mixed with a complex-forming agent from the group of the nitriles, isocyanides, tertiary phosphines and cyclic hydrocarbons with 6 to 12 ring atoms and 2 to 3 double bonds in the ring, and an aprotic organic solvent. The dimer is an intermediate product in the synthesis of perfluoropropyl perfluorovinyl ether, the latter being employed as a comonomer in fluorine-containing copolymers.

    专利号:CA-2912893-C
    优先权日:2008-06-11
    标题 :Bromine-facilitated synthesis of fluoro-sulfur compounds

    专利号:CA-2958407-C
    优先权日:2008-06-11
    标题:Bromine-facilitated synthesis of fluoro-sulfur compounds

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013.
    摘要:ACGIH - Documentation of the TLVs and BEIs, 7th Ed. Cincinnati: ACGIH Worldwide, 2020.
    摘要:National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review., 5(28), 1953
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