CAS: 3395-03-7; 1,2-Dimethoxy-4,5-Dinitrobenzene

上下游产品

CAS号91-16-7 1,2-二甲氧基苯 | CAS号709-09-1 3,4-二甲氧基硝基苯 | CAS号577-68-4 4,5-二甲氧基邻苯二甲酸 | CAS号74-88-4 碘甲烷 | CAS号1131-62-0 3,4-二甲氧基苯乙酮 | CAS号93-07-2 藜芦酸 | CAS号4101-32-0 1-(4,5-二甲氧基-2-硝... | CAS号110190-08-4 1,2-二碘-4,5-二甲氧基苯 | CAS号77400-30-7 4,5-dinitrobenz... | CAS号111611-40-6 5,6-dimethoxy-2... | CAS号19365-52-7 2-amino-4,5-dim... | CAS号7595-31-5 2-硝基-4,5-二甲氧基苯胺 | CAS号77400-30-7 4,5-dinitrobenz... | CAS号105780-30-1 2-methoxy-4,5-d... | CAS号33561-34-1 2,3-bis(bromome... | CAS号146535-11-7 Tyrphostin AG 1296 | CAS号25808-66-6 2H-Benzimidazol... | CAS号14227-14-6 2,4,5-Trimethox... | CAS号216699-86-4 2-氯-6,7-二甲氧基喹噁啉

1-(4,5-二甲氧基-2-硝基苯基)乙酮置于硝酸体系中,化学反应生成1,2-二甲氧基-4-二硝基苯
参考文献:Lawson; Perkin; Robinson,Journal Of The Chemical Society,1924,Vol. 125,P. 653
标题:Lawson; Perkin; Robinson,Journal Of The Chemical Society,1924,Vol. 125,P. 653

专利信息

专利号:US-6051704-A
优先权日:1996-07-22
标题:Synthesis of macrocyclic tetraamido-N ligands
发明人：GORDON-WYLIE SCOTT W; COLLINS TERRENCE J
权利人:UNIV CARNEGIE MELLON
摘要:New synthetic methods for the preparation of macrocyclic amido-N donor ligands are provided. The primary method of the present invention involves in general only two synthetic steps. In the first step, an α or β amino carboxylic acid is allowed to react with an optimal (approximately stoichiometric) amount of an activated malonate or oxalate derivative with mild heating. Upon completion of the double coupling reaction, hydrolysis of the reaction mixture yields a diamide containing intermediate (a macro linker). In the second step, stoichiometric amounts of a diamine, preferably an orthophenylene diamine, are added to the macro linker intermediate in the presence of a coupling agent and heat. This second double coupling reaction, is allowed to proceed for a period of time sufficient to produce a macrocyclic tetraamido compound. The substituent groups on the α or β amino carboxylic acid, the malonate, and the aryl diamine may all be selectively varied so that the resulting tetraamido macrocycle can be tailored to specific desired end uses. The macrocyclic tetraamide ligand may then be complexed with a metal, such as a transition metal, and preferably the middle and later transition metals, to form a robust chelate complex suitable for catalyzing oxidation reactions.

专利号:US-2010324266-A1
优先权日:2000-09-11
标题:Photocleavable Protecting Groups
发明人：BARONE ANTHONY D; MCGALL GLENN H
权利人:AFFYMETRIX INC
摘要:Novel compounds are provided, which are useful as linking groups in chemical synthesis, preferably in the solid phase synthesis of oligonucleotides and polypeptides. These compounds are generally photolabile and comprise protecting groups which can be removed by photolysis to unmask a reactive group. The protecting group has the general formula Y, wherein Y is a chemical structure as shown in FIG. 1 . Also provided is a method of forming, from component molecules, a plurality of compounds on a support, each compound occupying a separate predefined region of the support, using the protected compounds described above.

专利号:US-6011152-A
优先权日:1996-07-22
标 题 :Synthesis of macrocyclic tetraamido-N ligands

专利号:US-5994535-A
优先权日:1989-03-06
标题 :Water soluble texaphyrin metal complex preparation
发明人：SESSLER JONATHAN L; HEMMI GREGORY W; MODY TARAK D
权利人:UNIV TEXAS
摘要:The present invention is directed to methods for synthesizing water soluble hydroxy-substituted texaphyrins retaining lipophilicity. The synthesis comprises condensing a diformyltripyrrole with an ortho-phenylenediamine to give a nonaromatic texaphyrin having at least one hydroxy substituent, and oxidizing the condensation product to form an aromatic texaphyrin metal complex having at least one hydroxy substituent. These expanded porphyrin-like macrocycles may be used for magnetic resonance imaging and for photodynamic therapy in the treatment of atheroma and tumors.