CAS: 23407-76-3; (1S,4Ar,7Ar)-Methyl 4A-Hydroxy-7-(Hydroxymethyl)-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-1,4A,5,7A-Tetrahydrocyclopenta[c]Pyran-4-Carboxylate
该化合物是一个复杂的有机化合物,其独特的双环结构包含环球动物,与一个环状环状圆环结合,并带有一个环形环形圆环;该化合物具有多种功能组,包括一个甲氧基,氢氧基组,以及与乙型-D-四聚苯甘糖的球状联系,这种联系有助于其溶解性和再活性.1S,4aR,7aR)配置所显示的立体化学学表明其替代体的具体空间安排,这种安排能够对其生物活动和相互作用产生重大影响.这些化合物由于其潜在的治疗特性,往往对医药化学和天然产品合成感兴趣.水氧和氢氧化组的存在可能会增强氢的联结能力,影响该化合物在不同化学环境中的溶解性与再活.总体而言,这种物质体现了自然发现的有机分子的复杂性和多样性.
- 英文名称(1S,4Ar,7Ar)-Methyl 4A-Hydroxy-7-(Hydroxymethyl)-1-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-1,4A,5,7A-Tetrahydrocyclopenta[c]Pyran-4-Carboxylate
- 中文名称黄夹苦甙
- IUPAC名称methyl (1S,4aR,7aR)-4a-hydroxy-7-(hydroxymethyl)-1-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-4-carboxylate
- 其它别名(1S)-1α-(β-D-Glucopyranosyloxy)-1,4A,5,7Aα-Tetrahydro-4Aα-Hydroxy-7-(Hydroxymethyl)Cyclopenta[c]Pyran-4-Carboxylic Acid Methyl Ester; Theviridoside; Cyclopenta[c]Pyran-4-Carboxylic Acid, 1-(β-D-Glucopyranosyloxy)-1,4A,5,7A-Tetrahydro-4A-Hydroxy-7-(Hydroxymethyl)-, Methyl Ester, (1S,4Ar,7Ar)-; Yellow Bitter Glycoside; Cyclopenta[c]Pyran-4-Carboxylicacid, 1-(B-D-Glucopyranosyloxy)-1,4A,5,7A-Tetrahydro-4A-Hydroxy-7-(Hydroxymethyl)-,Methyl Ester, (1S,4Ar,7Ar)-; Theveridoside
- CAS编号23407-76-3
- MFCD编号:MFCD20260837
- 分子式:C17H24O11分子量:404.37
- 产品CID: 1175776
- 产品分类天然产物 → 环烯醚萜衍生物
物理性质
MSDS等安全信息
上下游产品
Silver; (1S,4aR,7aR)-4a-hydroxy-7-hydroxymethyl-1-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-1,4a,5,7a-tetrahydro-cyclopenta[c]pyran-4-carboxylate methyl iodide diazomethane theveside合成工艺路线路线简述
📜6'-O-Cyclopropanoyltheviridoside 以 甲醇,水,二乙胺 用作溶剂,化学反应 17.0H,反应生成黄夹苦甙
参考文献:Iridoid Glycosides From The Stems Of Pithecoctenium Crucigerum (Bignoniaceae)
标题:Iridoid Glycosides From The Stems Of Pithecoctenium Crucigerum (Bignoniaceae)
摘要:Sixteen Crude Extracts From Six Panamanian Plants Of The Family Bignoniaceae Were Submitted To Rapid Tlc Tests Against Dpph And Acetylcholinesterase. Pithecoctenium Crucigerum (L.) A.H. Gentry,Which Showed Interesting Activity Against Dpph,Has Been Studied. The Chemical Investigation Of The Methanol Extract From The Stems Afforded The Iridoid Glycoside Theviridoside And Three Derivatives (6 '-O-Cyclopropanoyltheviridoside,10-O-Hydroxybenzoyltheviridoside And 10-O-Vanilloyltheviridoside),Along With Five Known Phenyl-Ethanoid Glycosides (Verbascoside,Isoverbascoside,Forsythoside B,Jionoside D And Leucosceptoside B. These Last Compounds Were All Active Against Dpph.The Structures Were Determined By Means Of Spectrometric And Chemical Methods,Including 1 And 2D NMR Experiments And Ms Analysis. (C) 2007 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Phytochem.2007.02.002
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905143000-叔丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1016/0305-1978(86)90106-7
摘要:Rimpler H, Sauerbier H. Iridoid glucosides as taxonomic markers in the genera Lantana, Lippia, Aloysia and Phyla. Biochemical Systematics and Ecology. 1986 May;14(3):307–10. doi: 10.1016/0305-1978(86)90106-7.
参考文献:10.1248/cpb.44.1797
摘要:ABE F, YAMAUCHI T. 10-Carboxyloganin, Normonoterpenoid Gluosides and Dinormonoterpenoid Glucosides from the Leaves of Cerbera manghas (Studies on Cerbera. 10). Chem. Pharm. Bull. 1996;44(10):1797–800. doi: 10.1248/cpb.44.1797.
参考文献:10.1124/mol.119.115964
摘要:Lee TD, Lee OW, Brimacombe KR, Chen L, Guha R, Lusvarghi S, Tebase BG, Klumpp-Thomas C, Robey RW, Ambudkar SV, Shen M, Gottesman MM, Hall MD. A High-Throughput Screen of a Library of Therapeutics Identifies Cytotoxic Substrates of P-glycoprotein. Molecular Pharmacology. 2019 Nov;96(5):629–40. doi: 10.1124/mol.119.115964.
📝 需求与反馈
尽可能描述清楚需求与问题信息
