📜Isopropyl 6-Oxoheptanoate置于氢氧化钾体系中,用 甲苯 用作溶剂,化学反应生成2-乙酰基环戊酮 参考文献:Blaha,L. Et Al.,Collection Of Czechoslovak Chemical Communications,1965,Vol. 30,P. 1214-1220 标题:Blaha,L. Et Al.,Collection Of Czechoslovak Chemical Communications,1965,Vol. 30,P. 1214-1220
专利号:RU-2177955-C2 优先权日:1996-02-16 标 题 :Vanadium compounds, method of their synthesis, method of synthesis of elastomeric copolymers
专利号:US-6545033-B1 优先权日:1999-10-06 标 题:Fused 1-(2,6-dichloro-4-trifluoromethylphenyl)-pyrazoles, the synthesis thereof and the use thereof as pesticides 发明人:DHANOA DALJIT S; MEEGALLA SANATH; SOLL RICHARD M; DOLLER DARIO; SHA DEYOU; LIU RUIPING; SILVER GARY; LEE YU-KAI 权利人:DIMENSIONAL PHARM INC 摘要:The present invention is directed to novel pyrazole derivatives and their use as pesticidal agents. The pyrazole derivatives have Formula I:or a salt thereof, whereR1 is amino, hydrogen, alkyl, hydroxy, halo, alkoxy, alkylamino, dialkylamino, alkylthio, alkylsulfinyl, alkylsulfonyl, trifluoroalkylsulfinyl, trifluoroalkylsulfonyl, hydroxy, amino, trifluoromethyl, acetylamino, -OSO2R2, -OS(O)R2, -OC(O)R2, -OC(O)NHR2, or -NHC(O)NHR2 where R2 is C1-4 alkyl or optionally substituted aryl;X, Y and Z are each independently (CH)n, (CR3R4)n, S, S(O), or SO2, wherein n is 1-2, R3 and R4 are defined herein;Q is N or C-R6, wherein R6 is fluoro, chloro, bromo, or iodo;R5 is halo, C1-C6 alkyl, C1-C4 alkenyl, C1-C4 alkoxy, C1-C4 alkylamino, C1-C4 dialkylamino, C1-C4 alkylthio, C1-C4 alkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4 trifluoroalkylsulfinyl, C1-C4 trifluoroalkylsulfonyl, hydroxy, amino, or trifluoromethyl; andwith the proviso that only one of X, Y and Z can be S, S(O) or SO2.
专利号:US-9260463-B2 优先权日:2011-11-30 标题 :Substituted pyrimidinato iridium complexes and substituted pyrazinato iridium complexes having an alicyclic diketone ligand 发明人:INOUE HIDEKO; SEO HIROMI; SEO SATOSHI 权利人:SEMICONDUCTOR ENERGY LAB 摘要:As a novel substance having a novel skeleton, a novel organometallic complex that can emit phosphorescence in the green to red wavelength region and has high emission efficiency and a high yield of synthesis is provided. One embodiment of the present invention is an organometallic complex in which a diketone having a five-membered or six-membered alicyclic structure composed of carbon and hydrogen is a ligand. n nIn the formula, L represents a bidentate aromatic ligand and has at least a bond between carbon of an aromatic ring in the aromatic ligand and Ir. X represents a five-membered or six-membered alicycle composed of carbon and hydrogen. Further, R 1 represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms.
摘要:Jang, H. B.; Oh, J. S.; Song, C. E., Science of Synthesis: Asymmetric Organocatalysis, (2012) 2, 137. 摘要:Fan, Y. C.; Kwon, O., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 769. 摘要:Chanda, A.; Fokin, V. V., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 734. 摘要:Nagasawa, K.; Sohtome, Y., Science of Synthesis: Asymmetric Organocatalysis, (2012) 2, 29. 摘要:Singh, R. P.; Deng, L., Science of Synthesis: Asymmetric Organocatalysis, (2012) 2, 72.