CAS: 150-75-4; 4-(Methylamino)Phenol

相似化合物

55-55-0 51-72-9 54840-15-2

上下游产品

4-羟基苯甲酰胺 N-(4-Hydroxyphenyl)Formamide 1693-39-6
N-甲基-P-氨基苯甲醚 N-Methyl-N-(4-Methoxyphenyl)Amine 5961-59-1
对氨基苯酚 4-Amino-Phenol 123-30-8
1-(对羟基苯基)-2-硫脲 1-(4-Hydroxyphenyl)Thiourea 1520-27-0
N-(4-羟苯基)甘氨酸 N-(Hydroxyphenyl)Glycine 122-87-2
N,N-二甲基苯胺 N,N-Dimethyl-Aniline 86362-18-7

4-苄氧基-N-甲基苯胺置于pd(0)Encat,Ammonium Formate体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 0.17H,以45%的收率获得对甲氨基酚
参考文献:Fast Deprotection Of Phenoxy Benzyl Ethers In Transfer Hydrogenation Assisted By Microwave
标题:Fast Deprotection Of Phenoxy Benzyl Ethers In Transfer Hydrogenation Assisted By Microwave
摘要:Phenoxy Benzyl Ethers Are Easily And Quickly Deprotected In The Presence Of Ammonium Formate And Microencapsulated Pd(0)Encat With The Assistance Of Microwave Irradiation. This Procedure Can Be Applied In The Presence Of Other Functional Groups As Well. The Described Protocol Is Particularly Convenient For The Preparation In A Parallel And Automatic Fashion Of Libraries Of Compounds Possessing A Phenol Type Moiety. (C) 2006 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tetlet.2006.12.041

专利信息

专利号:US-3956184-A
优先权日:1974-04-24
标题:Method of preparing silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol
发明人：KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH
权利人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH
摘要:The method of preparing a silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol which consists in that a carrier is impregnated with an aqueous or an aqueous-alcohol solution containing complex ions of silver having the general formula [Ag(X) n ] + or [Ag(Y) 2 ] - , where X is ammonia, ethylenediamine, triethylenetetramine or triaminotriethylamine, Y is a thiocyanate, cyanide, acetate, or hydroxyl ion, and n is 1 or 2. The impregnated carrier is processed, at a temperature of from 10° - 100°C, with a reducing agent taken in the quantity sufficient to reduce the silver completely from said ion. The thus-prepared catalyst is dried at a temperature of from 80° to 400°C. It is recommended that the catalyst be washed with water before drying. The thus-prepared catalyst has a highly developed active surface with a small content of silver (the specific surface of the catalyst is 0.7 - 7 square meters per gram, with the metal silver content of the catalyst being from 5 - 10 per cent by weight). The catalyst is highly active and has good selectivity in the process of formaldehyde synthesis from methyl alcohol. The yield of formaldehyde with the proposed catalyst is from 75 - 80 per cent, calculating with reference to the passed methyl alcohol, with the selectivity of the process being from 89 - 95 per cent.

专利号:EP-1431274-B1
优先权日:2002-12-18
标题 :Synthesis of mono-N-substituted functionalized anilines
发明人：SELVA MAURIZIO; TUNDO PIETRO
权利人:CONSORZIO INTERUNIVERSITARIO N
摘要:The present invention relates to a process for direct and selective synthesis of mono-N-substituted functionalized anilines by using alkylating agents selected from the class of organic carbonates, preferably of the dialkyl, dibenzyl and diallyl types, in the presence of suitable catalysts that are chemically related to the class of aluminosilicates.

专利号:US-8153817-B2
优先权日:2006-09-12
标 题 :Synthesis of methyl nonactate derivatives
发明人：BERGMEIER STEPHEN C; PRIESTLEY NIGEL D
权利人:BERGMEIER STEPHEN C; PRIESTLEY NIGEL D; UNIV OHIO
摘要:Methyl nonactate is converted into a variety of different triazoloamide antibacterial agents by a reaction scheme involving (1) inversion of the secondary alcohol of the methyl nonactate to produce the corresponding azidoester, (2) converting the azido ester to the corresponding azidoamide, and (3) converting the azido group of the azidoamide to a triazole to produce the corresponding triazoloamide.

专利号:US-7550510-B2
优先权日:2001-07-06
标 题 :Solid phase synthesis of arylretinamides
发明人：CURLEY JR ROBERT W; MERSHON SERENA M; BARNETT DEREK W; CLAGETT-DAME MARGARET; CHAPMAN JASON S
权利人:WISCONSIN ALUMNI RES FOUND
摘要:A solid phase synthetic method for preparing arylretinamides is provided. The method comprises reacting hexachloroacetone with a solvent-suspended resin-bound triphenylphosphine to provide a suspension comprising an activated chlorinating reagent; reacting retinoic acid with the activated chlorinating reagent to provide retinoyl chloride; adding pyridine and a select arylamine to the resulting mixture; and stirring the resulting mixture for a time and at a temperature sufficient for the select arylamine to react with the retinoyl chloride and provide the arylretinamide. Also provided, are select arylretinamides that can be prepared by the present method, and methods of using such arylretinamides to induce apoptosis in cancer cells.

专利号:US-2004102650-A1
优先权日:2001-07-06
标 题:Solid phase synthesis of arylretinamides

专利号:US-2010056779-A1
优先权日:2006-09-12
标题:Synthesis of methyl nonactate derivatives