专利号:US-2024097109-A1 优先权日:2021-02-11 标 题:Bottom-Up, Scalable Synthesis Of Oxide-Based Sub-Nano And Nanofilaments And Nanofilament-Based Two-Dimensional Flakes And Mesoporous Powders 发明人:BARSOUM MICHEL W; BADR HUSSEIN OSAMA 权利人:UNIV DREXEL 摘要:Provided are methods to convert—through a bottom-up approach—binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into lepidocrocitic nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can comprise nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances.
专利号:WO-2022174264-A1 优先权日:2021-02-11 标题:Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders 发明人:BADR HUSSEIN O; BARSOUM MICHEL W 权利人:UNIV DREXEL 摘要:Provided are methods to convert - through a bottom-up approach – binary and ternary titanium carbides, nitrides, borides, phosphides, aluminides, and silicides into nanofilaments that in some cases self-assemble into 2D flakes by immersing them in a quaternary ammonium solution at moderate temperatures. The resulting flakes can be C-containing anatase-based layers that are in turn comprised of nanofilaments in cross-section, some of which nanofilaments can be few microns long in some instances. Electrodes made from these materials performed well in energy systems. The materials also reduce the viability of some cancer cells. Also provided are mesoporous materials, devices, and related methods.
专利号:EP-4291240-A1 优先权日:2021-02-11 标题 :Bottom-up, scalable synthesis of oxide-based sub-nano and nanofilaments and nanofilament-based two-dimensional flakes and mesoporous powders
专利号:WO-2016091694-A1 优先权日:2014-12-12 标题 :Process for producing a supported, partially reductively activated fischer-tropsch synthesis catalyst, and process for producing hydrocarbons using the same 发明人:CLARK THOMAS EDWARD; CLARKE ROBERT WILLIAM; COUVES JOHN; FERGUSON EWEN; GAEMERS SANDER; KRAWIEC PIOTR; SHARMA BHUSHAN; WELLS MATTHEW JAMES; NAY BARRY 权利人:BP PLC; JOHNSON MATTHEY DAVY TECHNOLOGIES LTD; CLARK THOMAS EDWARD; CLARKE ROBERT WILLIAM; COUVES JOHN; FERGUSON EWEN; GAEMERS SANDER; KRAWIEC PIOTR; SHARMA BHUSHAN; WELLS MATTHEW JAMES; NAY BARRY 摘要:A process for the production of a reductively activated cobalt-containing Fischer- Tropsch catalyst supported on a support material comprising zinc oxide, said process comprising a carbon monoxide reduction step comprising contacting a cobalt-containing Fischer-Tropsch catalyst with a gaseous stream comprising carbon monoxide and less than 10 vol.% hydrogen based on the volume of carbon monoxide; followed by a hydrogen reduction step comprising contacting the product of the carbon monoxide reduction step with a gaseous stream comprising hydrogen and less than 10 vol.% carbon monoxide based on the volume of hydrogen, such that the reductively activated cobalt-containing Fisher- Tropsch catalyst comprises from 20% to 95% metallic cobalt by weight of cobalt.
专利号:WO-2016091692-A1 优先权日:2014-12-12 标 题:Process for producing a supported reductively activated fischer-tropsch synthesis catalyst, and process for producing hydrocarbons using the same 发明人:CLARK THOMAS EDWARD; COUVES JOHN; FERGUSON EWEN; GAEMERS SANDER; WELLS MATTHEW JAMES; SHARMA BHUSHAN 权利人:BP PLC; JOHNSON MATTHEY DAVY TECHNOLOGIES LTD; CLARK THOMAS EDWARD; COUVES JOHN; FERGUSON EWEN; GAEMERS SANDER; WELLS MATTHEW JAMES; SHARMA BHUSHAN 摘要:The present invention provides a process for the production of a reductively activated cobalt-containing Fischer-Tropsch catalyst supported on a support material comprising zinc oxide, said process comprising i) a carbon monoxide reduction step comprising contacting a cobalt-containing Fischer-Tropsch catalyst with a gaseous stream comprising carbon monoxide and less than 10 vol.% hydrogen based on the volume of carbon monoxide; followed by ii) a hydrogen reduction step comprising contacting the product of the carbon monoxide reduction step i) with a gaseous stream comprising hydrogen and less than 10 vol.% carbon monoxide based on the volume of hydrogen at a temperature of from 200 °C to 280 °C.
专利号:WO-2016091696-A1 优先权日:2014-12-12 标 题:Process for producing a partially reductively activated fischer-tropsch synthesis catalyst, and process for producing hydrocarbons using the same 发明人:FERGUSON EWEN; OJEDA PINEDA MANUEL; PATERSON ALEXANDER; WELLS MATTHEW JAMES 权利人:BP PLC; FERGUSON EWEN; OJEDA PINEDA MANUEL; PATERSON ALEXANDER; WELLS MATTHEW JAMES 摘要:The present invention provides a process for the production of a reductively activated cobalt-containing Fischer-Tropsch catalyst supported on a support material comprising titanium dioxide, said process comprising i) a carbon monoxide reduction step comprising contacting a cobalt-containing Fischer-Tropsch catalyst with a gaseous stream comprising carbon monoxide and less than 10 vol.% hydrogen based on the volume of carbon monoxide; followed by ii) a hydrogen reduction step comprising contacting the product of the carbon monoxide reduction step i) with a gaseous stream comprising hydrogen and less than 10 vol.% carbon monoxide based on the volume of hydrogen, such that the reductively activated cobalt-containing Fisher-Tropsch catalyst comprises from 30% to 95% metallic cobalt by weight of cobalt.
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