CAS: 1191-62-4; 1,8-Octanedithiol

该化合物是一种有机化合物,其特征是位于八烷链终端位置的两个硫醇(SH)功能组,该结构给化合物带来独特的特性,包括其在氧化后形成脱硫结层的可能性,这可能影响其反应性和稳定性.Octane-1,8-dithiol通常是一种无色的,有独特味的黄色粉色液体,它溶于有机溶剂,但由于其缺水碳烷链,在水中溶解性有限.该化合物在各个领域都有意义,包括有机合成和材料科学,可以作为更复杂的分子的建筑块或作为协调化学的木质.此外,该化合物的硫醇组可以参与各种化学反应,使其在开发功能材料和研究涉及硫柳的生化工艺过程中成为宝贵的化合物.在处理该化合物时,应当采取安全防范措施,因为硫磷可能是有毒的,并且具有很强的.

结构式图片

相似化合物

3489-28-9 1191-67-9 1191-43-1

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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CAS号629-41-4 1,8-辛二醇 | CAS号629-03-8 1,6-二溴己烷 | CAS号4549-32-0 1,8-二溴辛烷 | CAS号351003-17-3 1,8-辛二硫醇二乙酸酯 | CAS号6573-66-6 dithiecane

合成工艺路线路线简述

    1,8-二溴辛烷置于sodium Hydroxide体系中,用 乙醇,水 用作溶剂,化学反应 55.0H,反应生成1,8-辛二硫醇
    参考文献:具有各种-S(ch 2)n S-连接子长度(n = 2-8)的[fefe]-氢化酶h-簇模拟物:系统研究
    标题:具有各种-S(ch 2)n S-连接子长度(n = 2-8)的[fefe]-氢化酶h-簇模拟物:系统研究
    摘要:二硫代lato配体的性质对[fefe]-加氢酶的合成h-簇模拟物的物理和电化学性质的影响仍然是令人关注的问题.在本报告中,我们描述了各种链烷二硫醇的环化反应,得到环状二硫键,四硫键和六硫键化合物.后面的化合物用作配体,用于合成一系列具有通式[fe 2(co)6 {μ-S(ch 2)n S}] [ N = 4-8),[fe 2(co)6 {μ-S(ch 2)n S}] 2(n = 6-8)和[fe 2(co)6 {(μ-S(ch 2)n S)2 }](n = 6-8).通过1 H和13 C { 1 H} NMR和ir光谱技术,质谱分析,元素分析以及x射线分析对所得复合物进行表征.本研究的目的是通过循环伏安法研究n从2到7的系统增加对模型氧化还原电势和在乙酸(acoh)存在下的催化能力的影响.
    Doi:10.1021/acs.Inorgchem.7B01398

    专利信息


    专利号:US-9920160-B2
    优先权日:2014-09-03
    标题 :Method for synthesis of polymer containing multiple epoxy groups
    发明人:GAO CHAO; ZHENG YAOCHEN; PENG LI; CAI SHENGYING; WENG ZHULIN
    权利人:UNIV ZHEJIANG
    摘要:A method for a synthesis of a polymer containing multiple epoxy groups includes steps of: under protection of nitrogen or argon, with a photosensitive free radical initiator under an ultraviolet light irradiation, initiating a mixture of a dithiol compound and alkynyl glycidyl ether or other alkynyl-containing compounds to proceed a thiol-yne polymerization, so as to obtain the polymer. The number of the epoxy groups is able to be adjusted through changing a type of a dithiol monomer, a mixing ratio of the dithiol monomer, and a mixing ratio between the alkynyl glycidyl ether and other alkynyl compounds. The present invention has advantages of: fast reaction, convenient process, easy post-processing, a large number of the epoxy groups, and adjustable and controllable content. The obtained polymer has a wide potential application in fields of coating, adhesive, ink, encapsulating material, resin for composite material, additive, high performance material, function material, and so on.

    专利号:US-2009111737-A1
    优先权日:1999-05-24
    标题:Novel antibacterial agents
    发明人:CHRISTENSEN BURTON G; MORAN EDMUND J; GRIFFIN JOHN H; JUDICE J KEVIN; MU YONGQI; PACE JOHN L; MAMMEN MATHAI; AGGEN JAMES
    权利人:CHRISTENSEN BURTON G; MORAN EDMUND J; GRIFFIN JOHN H; JUDICE J KEVIN; MU YONGQI; PACE JOHN L; MAMMEN MATHAI; AGGEN JAMES
    摘要:This invention relates to novel multibinding compounds (agents) that are antibacterial agents. The multibinding compounds of the invention comprise from 2-10 ligands covalently connected by a linker or linkers, wherein each of said ligands in their monovalent (i.e., unlinked) state have the ability to bind to a an enzyme involved in cell wall biosynthesis and metabolism, a precursor used in the synthesis of the bacterial cell wall and/or the bacterial cell surface thereby interfere with the synthesis and/or metabolism of the cell wall. In particular the multibinding compounds of the invention comprise from 2-10 ligands covalently connected by a linker or linkers, wherein each of said ligands hasn a ligand domain capable of binding to penicillin binding proteins, a transpeptidase enzyme, a substrate of a transpeptidase enzyme, a beta-lactamase enzyme, pencillinase enzyme, cephalosporinase enzyme, a transglycoslase enzyme, or a transglycosylase enzyme substrate; Preferably, the ligands are selected from the beta lactam or glycopeptide class of antibacterial agents.

    专利号:US-9388345-B2
    优先权日:2012-07-03
    标题:Hydrocarbon synthesis methods, apparatus, and systems
    发明人:MCNEFF CLAYTON V; MCNEFF LARRY C; NOWLAN DANIEL THOMAS; YAN BINGWEN; GREUEL PETER G
    权利人:SARTEC CORP
    摘要:Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.

    专利号:US-9896776-B2
    优先权日:2011-09-21
    标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids
    发明人:STEVENSON KEITH J; MURUGESAN SANKARAN; KEARNS PATRICK; AKKINENI ARUNKUMAR
    权利人:UNIV TEXAS
    摘要:Room temperature electrochemical methods to deposit thin films of chalcogenide glasses.

    专利号:WO-2018049302-A1
    优先权日:2016-09-12
    标 题:One-pot, high-performance recycling method for polymer waste using renewable polymer synthesis
    发明人:HEARON KEITH
    权利人:POLY6 TECH
    摘要:Curable formulations, cured formulations, and mixtures and composites thereof are described herein, as well as methods of making and using the formulations, mixtures, and composites.

    专利号:US-10144840-B2
    优先权日:2013-03-13
    标题 :One-pot, high-performance recycling of polymer waste using renewable polymer synthesis
    发明人:HEARON KEITH
    权利人:POLY6 TECH
    摘要:Curable formulations, cured formulations, and mixtures and composites thereof are described herein, as well as methods of making and using the formulations, mixtures, and composites.
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    主要参考文献

    参考标题:Remarkably Fast Direct Synthesis Of Thiols From Alcohols Under Mild Conditions
    作者:B. P. Bandgar,V. S. Sadavarte,L. S. Uppalla |发布日期:2000.11
    摘要:One Pot Rapid Synthesis Of Thiols From Alcohols Via Trifluoroacetates Using Polymer Supported Hydrosulfide In Acetonitrile Under Mild Conditions Has Been Described.

    合成参考文献


    摘要:Shinmyozu, T.; Shibahara, M., Science of Synthesis, (2010) 45, 1272.
    摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/S_schafer851.pdf
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