CAS: 106-68-3; Octan-3-One

上下游产品

CAS号589-98-0 辛醇 | CAS号3391-86-4 1-辛烯-3-醇 | CAS号2809-67-8 2-辛炔 | CAS号111-67-1 2-辛烯 | CAS号26158-84-9 2-ethyl-2-penty... | CAS号50-00-0 甲醛 | CAS号17598-10-6 Morpholine, 4-(... | CAS号811-49-4 乙基锂 | CAS号111-65-9 正辛烷 | CAS号13389-42-9 反-2-辛烯 | CAS号1844-13-9 N-[(E)-3-nitros... | CAS号124-38-9 二氧化碳 | CAS号107-92-6 正丁酸 | CAS号109-52-4 正戊酸 | CAS号26158-84-9 2-ethyl-2-penty... | CAS号589-98-0 辛醇 | CAS号16487-68-6 2,3-°Ctadiene | CAS号142-62-1 正己酸 | CAS号585-25-1 2,3-辛二酮 | CAS号3457-39-4 °Ctane-3,4-dione

1-辛烯-3-醇置于[rucl2(η6-C6H5och2Ch2Oh)(P(Oi-Pr)3)],Potassium Tert-Butylate,水体系中,化学反应 0.08H,以99%的收率获得3-辛酮
参考文献:高度水溶性的芳烃-钌(II)配合物:在烯丙基催化异构化中的应用酒类 在水性介质中
标题:高度水溶性的芳烃-钌(II)配合物:在烯丙基催化异构化中的应用酒类 在水性介质中
摘要:芳烃-钌(II)的衍生物合成将[rucl 2(η 6-C 6 H ^ 5 och 2 Ch 2 Oh)(l)](l = P(ome)3(图2A),P(oet)3(图2B),P (o我pr)3(图2C),P(oph)3(2D),Pph 3(2E))已经从二聚物[{的rucl(制备μ-Cl)(η 6-C 6 H ^ 5 och 2 Ch 2个oh)} 2 ]和适当的p供体配体.羟基上的羟基乙氧基取代基芳烃 诱导 水所得复合物的溶解度(至多755 G L-1);特别是衍生物2A的溶解度高100倍水 比它的 对苯甲基同类将[rucl 2(η 6-P-Cymene){p(ome)3 }].化合物2A-e具有活性催化剂 用于烯丙基的异构化 酒类 进入相应的 酮类在水性介质中.衍生物2A-C获得了最佳性能,衍生物2A-C显示了迄今为止报道的芳族或二取代底物异构化的最高活性.水.
Doi:10.1039/b914789F

专利信息

专利号:US-6600040-B2
优先权日:2000-06-08
标 题:Process for the synthesis of (2R, 2-alpha-R, 3A)-2-[1-(3,5-bis(trifluoromethyl)phenyl)ethoxy]-3-(4-fluorophenyl)-1, 4-oxazine
发明人：BRANDS KAREL M JOS; TSAY FUH-RONG; CONRAD KAREN M; ZHAO MATTHEW M
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R, 3a)-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-3-(4-fluorophenyl)-1,4-oxazine. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.

专利号:US-6469164-B2
优先权日:2000-06-08
标题:Process for the synthesis of (2R, 2-alpha-R)-4-benzyl-2-[1-(3,5-bis (trifluoromethyl)phenyl)ethoxy]-1,4-oxazine-3-one
发明人：BRANDS KAREL M JOS; PAYACK JOSEPH F; PYE PHILIP J
权利人:MERCK & CO INC
摘要:The present invention is concerned with novel processes for the preparation of (2R, 2-alpha-R)-4-benzyl-2-[1-[3,5-bis(trifluoromethyl)phenyl]ethoxy-1,4-oxazin-3-one. This compound is useful as an intermediate in the synthesis of compounds which possess pharmacological activity.

专利号:US-9096519-B2
优先权日:2013-01-10
标 题 :Process for the synthesis of ketones from internal alkenes
发明人：MORANDI BILL; GRUBBS ROBERT H; WICKENS ZACHARY K; LERCH MICHAEL M
权利人:CALIFORNIA INST OF TECHN
摘要:The present invention is directed to methods for oxidizing internal olefins to ketones. In various embodiments, each method comprising contacting an organic substrate, having an initial internal olefin, with a mixture of (a) a biscationic palladium salt; and (b) an oxidizing agent; dissolved or dispersed in a solvent system to form a reaction mixture, said solvent system comprising at least one C 2-6 carbon nitrile and optionally at least one secondary alkyl amide, said method conducted under conditions sufficient to convert at least 50 mol % of the initial internal olefin to a ketone, said ketone positioned on a carbon of the initial internal olefin. The transformation occurs at room temperature and shows wide substrate scope. Applications to the oxidation of seed oil derivatives and a bioactive natural product are described.

专利号:US-2014296354-A1
优先权日:2013-04-01
标题 :Synthesis of peptoid-based small molecular gelators from multiple component reactions
发明人：WANG GUIJUN; MANGUNURU HARI P R
权利人:WANG GUIJUN; MANGUNURU HARI P R; OLD DOMINION UNIV RES FOUND
摘要:Described herein are the one-pot synthesis and characterization of a library of low molecular weight peptoid compounds that are able to form gels at room temperature. The compounds are synthesized from biologically-based starting materials, are biocompatible, and are resistant to degradation by proteases and peptidases. The compounds and gels synthesized therefrom can be used in such applications as tissue engineering, drug delivery, separation of biomolecules, and stimulus-responsive advanced materials

专利号:US-9822053-B2
优先权日:2016-01-28
标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
发明人：BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
权利人:EASTMAN CHEM CO
摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

专利号:US-4677190-A
优先权日:1986-05-09
标题 :Synthesis and ring-opening polymerization of bicyclic lactones containing a tetrahydropyran ring
发明人：HALL JR HENRY K; SUMITOMO HIROSHI; OKADA MASAHIKO
权利人:UNIVERSITY PATENTS INC
摘要:The synthesis of novel strained bicyclic lactones and their ring-opening polymerization to high molecular weight polyester polymers is disclosed.