CAS: 70851-49-9; Dimethylsila-14-Crown-5

该化合物是属于皇冠醚家族的合成有机化合物,其特点是由于其独特的分子结构,能够有选择地捆绑石块.其特征是环形的环形环形连接,专门设计用于容纳金属离子,"二甲基硅"前缀表明在皇冠结构中存在硅原子.该化合物通常具有类似于皇冠的形状,这加强了其与各种晶体(如碱和碱性土金属)形成复杂体的能力.二甲基组的存在有助于其有机溶剂中的溶解性,并能够影响其结合特性.二甲状锡拉-14-crowown-5经常用于诸如离子选择性电极,提取过程和作为协调化学的一种离子体.其选择性封装的能力使其在分析化学和材料科学中具有价值.此外,该化合物的稳定性和再活性可能受其与金属离物相互作用的性质的影响,使其在研究和工业应用中成为多用途的工具.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    📜三缩四乙二醇,双(二甲基氨基)二甲基硅烷 以85%的收率获得产物
    参考文献:Hoang Thi Phung; Pham Ba Chi; Kober F.,Z. Anorg. Und Allg. Chem.,1981,427,No 1,75-82
    标题:Hoang Thi Phung; Pham Ba Chi; Kober F.,Z. Anorg. Und Allg. Chem.,1981,427,No 1,75-82

    海关参考信息

    专利信息


    专利号:US-5393511-A
    优先权日:1988-10-10
    标题 :Synthesis of zeolites of faujasite structure
    发明人:DELPRATO FRANCOIS; GUTH JEAN-LOUIS; ANGLEROT DIDIER; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:A process is provided for the preparation of zeolites belonging to the faujasite structural class and exhibiting a Si:Al ratio higher than 1 in which a reaction mixture is first produced, which has a pH higher than 10 and contains water, a source of tetravalent silicon, a source of trivalent aluminum, a source of hydroxide ions in the form of a strong inorganic or organic base and a structuring agent ST so as to produce an aluminosilicate gel having the desired composition to permit its crystallization into a compound of the faujasite structural class. The gel obtained is kept at a temperature, pressure and for a sufficient period to effect the crystallization of the gel into a precursor of the zeolite consisting of the zeolite trapping the structuring agent ST in its cavities and the precursor is then subjected to a calcination to destroy the structuring agent and to produce the zeolite. The structuring agent ST consists of at least one compound belonging to the group formed by the carbon-containing macrorings and macropolyrings which contain in the rings heteroatoms chosen from oxygen, nitrogen, silicon and sulphur, and which contain 10 to 24 atoms per ring. Precursors of the zeolites are also provided.

    专利号:US-5098686-A
    优先权日:1988-10-10
    标题 :Synthesis of zeolites of faujasite structure
    发明人:DELPRATO FRANCOIS; GUTH JEAN-LOUIS; ANGLEROT DIDIER; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:PCT No. PCT/FR89/00522 Sec. 371 Date Jun. 8, 1990 Sec. 102(e) Date Jun. 8, 1990 PCT Filed Oct. 10, 1989 PCT Pub. No. WO90/03944 PCT Pub. Date Apr. 19, 1990.A process is provided for the preparation of zeolites belonging to the faujasite structural class and exhibiting a Si:Al ratio higher than 1 in which a reaction mixture is first produced which has a pH higher than 10 and contains water, a source of tetravalent silicon, a source of trivalent aluminum, a source of hydroxide ions in the form of a strong inorganic or orgnaic base and a structuring agent ST so as to produce an aluminosilicate gel having the desired composition to permit its crystallization into a compound of the faujasite structural class. The gel obtained is kept at a temperature, pressure and for a sufficient period to effect the crystallization of the gel into a precursor of the zeolite consisting of the zeolite trapping the structuring agent ST in its cavities and the precursor is then subjected to a calcination to destroy the structuring agent and to produce the zeolite. The structuring agent ST consists of at least one compound belonging to the group formed by the carbon-containing macrorings and macropolyrings which contain in the rings, heteroatoms chosen from oxygen, nitrogen, silicon and sulphur, and which contain 10 to 24 atoms per ring. Precursors of the zeolites are also provided.

    专利号:WO-9003944-A1
    优先权日:1988-10-10
    标 题 :Synthesis of zeolites having a faujasite structure

    专利号:EP-0364352-A1
    优先权日:1988-10-10
    标 题:Method for the synthesis of zeolites belonging to the structural family of faujasite, products obtained and their use in adsorption and catalysis

    专利号:EP-0364352-B1
    优先权日:1988-10-10
    标 题:Method for the synthesis of zeolites belonging to the structural family of faujasite, products obtained and their use in adsorption and catalysis

    专利号:US-5304601-A
    优先权日:1990-04-09
    标题 :Catalysts based on a faujasite and its application
    发明人:DES COURIERES THIERRY; GUTH JEAN-LOUIS; PATARIN JOEL; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:PCT No. PCT/FR91/00287 Sec. 371 Date Jan. 17, 1992 Sec. 102(e) Date Jan. 17, 1992 PCT Filed Apr. 8, 1991 PCT Pub. No. WO91/15293 PCT Pub. Date Oct. 17, 1991.A catalyst is provided which contains 1 to 99 wt. % of an inorganic binder and 99 to 1% of a zeolite consisting of a faujasite having an Si:Al synthesis ratio at least equal to 3 and 30 and the compensation cations of this zeolite consist partly or wholly of cations of one or more elements chosen from H, B, Al, Ga, In, rare earth metals and transition metals. The catalyst can also contain up to 15%, referred to the total weight of the binder and zeolite, of a catalytically active metal of the noble, non-noble transition or other type which is not already present in the compensation cations of the zeolite. The catalyst can be used in acid catalysis reactions carried out on hydrocarbon feedstock, in particular in fluidized bed catalytic cracking.

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