1-苄基-3-甲基咪唑氯盐置于氟硼酸钠体系中,用 水 作为反应溶剂,化学反应 0.25H,以72%的收率获得产物1-苄基-3-甲基咪唑四氟硼酸盐 参考文献:Influence Of Different Branched Alkyl Side Chains On The Properties Of Imidazolium-Based Ionic Liquids 标题:Influence Of Different Branched Alkyl Side Chains On The Properties Of Imidazolium-Based Ionic Liquids 摘要:在微波辐射下采用两种不同的合成方法合成了几种新的分支离子液体.将不同的已知离子液体(包括线性和分支型)加入到这一组新的离子液体中,以研究分支对热物理性质的影响,从而揭示第一结构与性质之间的关系.利用热重分析法研究了分解行为,差示扫描量热法用于研究分支对热行为的影响,例如熔点,玻璃转变温度,冰点和冷结晶温度.此外,还分析了所选离子液体的水吸收情况. DOI:10.1039/b807119E
专利号:US-9267213-B1 优先权日:2005-03-25 标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array 发明人:MAURER KARL; COOPER JOHN J 权利人:CUSTOMARRAY INC 摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.
专利号:US-9919997-B2 优先权日:2013-12-30 标题 :One-pot water-free ionic liquids synthesis using trialkyl orthoesters 发明人:PARK JIN KYOON; KIM DO JOONG; OH KYUNG HWAN 权利人:PUSAN NATIONAL UNIV INDUSTRY UNIV COOPERATION FOUNDATION OF PUSAN 摘要:The present disclosure provides a method for producing an ionic liquid, the method comprising: reacting a nitrogen-containing heterocyclic compound or an amine-based compound with an ammonium salt along with trialkyl orthoformate to acquire an alkylated nitrogen-containing heterocyclic compound or an alkylated nitrogen-containing amine-based compound, wherein the alkylated nitrogen-containing heterocyclic compound or the alkylated nitrogen-containing amine-based compound as a cation of the ionic liquid is ionically bonded to an anion included in the ammonium salt to form the ionic liquid.
专利号:US-10407676-B2 优先权日:2014-12-09 标题 :High efficiency, small volume nucleic acid synthesis 发明人:POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN 权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS 摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).
专利号:CN-1706817-A 优先权日:2005-05-20 标 题 :Synthesis process of methyl ethyl ketone azine
参考文献:10.1007/s00792-016-0832-z 摘要:Kurata A, Senoo H, Ikeda Y, Kaida H, Matsuhara C, Kishimoto N. Properties of an ionic liquid-tolerant Bacillus amyloliquefaciens CMW1 and its extracellular protease. Extremophiles. 2016 Jul;20(4):415–24. doi: 10.1007/s00792-016-0832-z.