CAS: 401788-98-5; 3-Butyl-1-Methyl-1H-Imidazol-3-Ium Methyl Sulfate

该化合物是一种具有低粘度,高热稳定性和极佳溶液特性的离子液体.作为一种流体性离子液体,它与水和极有机溶剂存在严重不相符性,因此适合施用催化,电化学和绿色化学.其甲基硫酸亚胺离子的毒性相对较低,因为与卤化物离子的其他离子液体相比,它具有相对较低的毒性.该化合物在广泛的温度下表现出稳定性,并经常被用作合成工艺中的反应媒介或溶剂.其微小的蒸汽压力与它作为挥发性有机溶剂的一种无害环境的替代品而相匹配.

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262297-13-2 478935-29-4 342789-81-5

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上下游产品

sulfuric acid monomethyl ester; ammonium salt 1-butyl-3-methylimidazolium chloride 1-Butylimidazole dimethyl sulfate 1-butyl-3-methylimidazolium hydrogen sulfate 1-butyl-3-methylimidazolium Tetrafluoroborate

合成工艺路线路线简述

    📜N-丁基咪唑,硫酸二甲酯 以 甲苯 作为反应溶剂,以75%的收率获得产物1-丁基-3-甲基咪唑甲磺酸
    参考文献:1-丁基-3-甲基咪唑硫酸甲酯的物理性质随温度的变化
    标题:1-丁基-3-甲基咪唑硫酸甲酯的物理性质随温度的变化
    摘要:进行了1-丁基-3-甲基咪唑甲基硫酸甲酯的密度,声速,折射率,动态粘度和表面张力的测量,作为温度的函数.给出了离子液体的合成.离子液体的低粘度表明其在萃取过程中用作共沸混合物的分离溶剂.由密度计算出离子液体的热膨胀系数,并讨论了结果.通过与最近发表的值进行比较,分析了阳离子的烷基链长度对密度的影响.
    DOI:10.1021/je060313V

    海关参考信息

    专利信息


    专利号:US-2010191010-A1
    优先权日:2007-07-02
    标题 :Process for the synthesis of carbamates using co2
    发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
    权利人:HUNTSMAN INT LLC
    摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

    专利号:US-9267213-B1
    优先权日:2005-03-25
    标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
    发明人:MAURER KARL; COOPER JOHN J
    权利人:CUSTOMARRAY INC
    摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

    专利号:US-9126848-B2
    优先权日:2009-12-29
    标题:Synthesis of nanoparticles by means of ionic liquids
    发明人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL
    权利人:DE OLIVEIRA PETER WILLIAM; LIN HECHUN; VEITH MICHAEL; LEIBNIZ INSITUT FUER NEUE MATERIALIEN GEMEINNUETZIGE GMBH
    摘要:A method for producing nanoscale particles by means of ionic liquids produces highly crystalline particles. The ionic liquids can be easily regenerated.

    专利号:US-12392085-B2
    优先权日:2020-04-28
    标题 :Use of in-situ ionic liquid (IL) and deep eutectic solvent (DES) synthesis using chemically synthesized or biomass-derived ions in the pretreatment of biomass
    发明人:MAGURUDENIYA HARSHA D; ACHINIVU EZINNE; SIMMONS BLAKE A; GLADDEN JOHN M
    权利人:UNIV CALIFORNIA; NATIONAL TECH AND ENGINEERING SOLUTIONS OF SANDIA LLC; NAT TECH & ENG SOLUTIONS SANDIA LLC
    摘要:The present invention provides for a method to deconstruct a biomass comprising: (a) introducing one or more individual components of an ionic liquid (IL) or deep eutectic solvent (DES) to a biomass, wherein the one or more individual components, and optionally any components already present in the biomass, form an IL or DES, or mixture thereof, which solubilizes the biomass to form a solubilized biomass mixture, wherein at least one individual component is introduced to the biomass separately from any other individual component; (b) optionally introducing an enzyme and/or a microbe to the solubilized biomass mixture such that the enzyme and/or microbe produces a sugar from the solubilized biomass mixture; and, (c) optionally separating the sugar from the solubilized biomass mixture.

    专利号:US-2014001420-A1
    优先权日:2011-09-30
    标题 :Method of preparing metal nanoparticles
    发明人:DRZAL LAWRENCE T; DO IN-HWAN
    权利人:DRZAL LAWRENCE T; DO IN-HWAN
    摘要:A method for the synthesis of new metal based metal nanoparticles by the combination of conducting polymers and room temperature ionic liquids to produce nanoparticle electro-catalysts with very high catalytic activity and controllable size and high surface area to volume ratios.

    专利号:US-9765044-B2
    优先权日:2013-03-15
    标 题 :Synthesis of novel ionic liquids from lignin-derived compounds
    发明人:SOCHA AARON; SINGH SEEMA; SIMMONS BLAKE A; BERGERON MAXIME
    权利人:UNIV CALIFORNIA; SANDIA CORP
    摘要:Methods and compositions are provided for synthesizing ionic liquids from lignin derived compounds comprising: contacting a starting material comprising lignin with a depolymerization agent to depolymerize the lignin and form a mixture of aldehyde containing compounds; contacting the mixture of aldehyde containing compounds with an amine under conditions suitable to convert the mixture of aldehyde containing compounds to a mixture of amine containing compounds; and contacting the mixture of amine containing compounds with an acid under conditions suitable to form an ammonium salt, thereby preparing the ionic liquid.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Vassilikogiannakis, G.; Montagnon, T., Science of Synthesis, (2009) 38, 187.
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