CAS: 14871-41-1; Carbonylchloro Bis(Triphenylphosphine)Iridium(I)

该化合物是一个定义明确的(I)复合体,具有碳基离心,氯化物和两种三苯基-磷(Pph3)组,该复合体在同质催化中具有稳定性和效用,特别是在氢化和碳化反应中具有稳定性和实用性,在吸收碳基和对PPH3的施用中,其精密的中心稳定,促进氧化添加和再消化过程,使其在合成有机化学中具有价值,其晶体形式和空气敏感性需要在惰性条件下处理,该复合体通常被用作反应性更强的种的前体,在催化循环中提供受控的再活动,其精密结构有助于过渡性金属催化的机械研究.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    海关参考信息

    专利信息


    专利号:US-3644446-A
    优先权日:1969-07-01
    标 题 :Preparation of rhodium and iridium hydride carbonyl complexes
    发明人：BOOTH FRANK B; FENTON DONALD M; OLIVIER KENNETH L
    权利人:UNION OIL CO
    摘要:HYDRIDE CARBONYL COMPLEXES OF RHODIUM AND IRIDIUM WITH BIPHYLIC LIGANDS ARE PREPARED BY TREATMENT OF RHODIUM OR IRIDIUM, COMPLEXES OR SALTS THEREOF WITH AN ALKALI METAL HYDROXIDE, ALKOXIDE OR ARYLOXIDE AND A BIPHYLLIC LIGAND AND A MIDL REDUCING AGENT. IN A TYPICAL SYNTHESIS A RHODIUM CARBONYL SALT IS CONTACTED WITH AN ALKALI METAL ALKOXIDE IN THE PRESENCE OF THE LIGAND AND THE HYDRIDE IS FORMED BY SUBSEQUENT OR SIMULTANEOUS CONTACTING WITH A REDUCING AGENT SUCH AS HYDROGEN, CARBON MONOXIDE OR AN OXIDIZABLE ALCOHOL. THE COMPOUNDS HAVE UTILITY AS HYDROFORMYLATION CATALYSTS.

    其他信息查阅

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    实用工具

    ⚠️全国化工行业净网倡议书
    📋制造商识别码
    📖 海关编码查询
    📝MSDS生成器

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Sülü M, Küçükbay H, Durmaz R, Günal S. Antifungal activity of rhodium, iridium, and ruthenium tripodal phosphine complexes. New Microbiol. 2000 Jan;23(1):73–8.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知