CAS: 513-92-8; 1,1,2,2-Tetraiodoethene

该化合物是一种卤化有机化合物,其独特结构包括四个附于乙烯脊柱的碘原子,该化合物一般没有色素,可粉色黄色液体,以高密度和低挥发性而著称.Tetraiodoene在水中是无法溶解的,但在有机溶剂中是可溶的,因此在各种化学应用中有用.其高含碘含量具有重要的再活性,特别是在替代反应中,并且可作为有机合成中碘的来源.此外,四碘乙烯具有有趣的特性,例如高电子密度,可影响其在化学反应中的行为.由于其卤化性质,它也可能对环境和健康造成危害,需要小心处理和处置.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

peracetic acid diiodoacetylene chloroform Perbenzoic aciddiiodoacetylene polytetrafluoroethylene Pentafluoroethyl iodide 1,6-bis(phenyl)-3,4-bis(phenylethynyl)hex-3-ene-1,5-diyne

合成工艺路线路线简述

    📜乙炔置于iodonitrogen,水体系中,化学反应生成 甲碘乙烯
    参考文献:Datta; Prosad,Journal Of The American Chemical Society,1917,Vol. 39,P. 452
    标题:Datta; Prosad,Journal Of The American Chemical Society,1917,Vol. 39,P. 452

    海关参考信息

    专利信息


    专利号:US-2016237595-A1
    优先权日:2014-08-18
    标 题 :High-Strength Refractory Fibrous Materials
    发明人:MAXWELL JAMES L; WEBB NICHOLAS; HOOPER RYAN; ALLEN JAMES
    权利人:DYNETICS
    摘要:The disclosed materials, methods, and apparatus, provide novel ultra-high temperature materials (UHTM) in fibrous forms/structures; such “fibrous materialsâ€? can take various forms, such as individual filaments, short-shaped fiber, tows, ropes, wools, textiles, lattices, nano/microstructures, mesostructured materials, and sponge-like materials. At least four important classes of UHTM materials are disclosed in this invention: (1) carbon, doped-carbon and carbon alloy materials, (2) materials within the boron-carbon-nitride-X system, (3) materials within the silicon-carbon-nitride-X system, and (4) highly-refractory materials within the tantalum-hafnium-carbon-nitride-X and tantalum-hafnium-carbon-boron-nitride-X system. All of these material classes offer compounds/mixtures that melt or sublime at temperatures above 1800° C.—and in some cases are among the highest melting point materials known (exceeding 3000° C.). In many embodiments, the synthesis/fabrication is from gaseous, solid, semi-solid, liquid, critical, and supercritical precursor mixtures using one or more low molar mass precursor(s), in combination with one or more high molar mass precursor(s). Methods for controlling the growth, composition, and structures of UHTM materials through control of the thermal diffusion region are disclosed.

    专利号:US-2022033999-A1
    优先权日:2014-08-18
    标题:High-Strength Refractory Fibrous Materials
    发明人:MAXWELL JAMES L; WEBB NICHOLAS; HOOPER RYAN; ALLEN JAMES
    权利人:DYNETICS
    摘要:The disclosed materials, methods, and apparatus, provide novel ultra-high temperature materials (UHTM) in fibrous forms/structures; such “fibrous materialsâ€? can take various forms, such as individual filaments, short-shaped fiber, tows, ropes, wools, textiles, lattices, nano/microstructures, mesostructured materials, and sponge-like materials. At least four important classes of UHTM materials are disclosed in this invention: (1) carbon, doped-carbon and carbon alloy materials, (2) materials within the boron-carbon-nitride-X system, (3) materials within the silicon-carbon-nitride-X system, and (4) highly-refractory materials within the tantalum-hafnium-carbon-nitride-X and tantalum-hafnium-carbon-boron-nitride-X system. All of these material classes offer compounds/mixtures that melt or sublime at temperatures above 1800° C.—and in some cases are among the highest melting point materials known (exceeding 3000° C.). In many embodiments, the synthesis/fabrication is from gaseous, solid, semi-solid, liquid, critical, and supercritical precursor mixtures using one or more low molar mass precursor(s), in combination with one or more high molar mass precursor(s). Methods for controlling the growth, composition, and structures of UHTM materials through control of the thermal diffusion regio are disclosed.

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    合成参考文献


    摘要:U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals., NX#04958
    摘要:Kostikov, R. R., Science of Synthesis, (2006) 24, 105.
    摘要:Banert, K., Science of Synthesis, (2006) 24, 753.
    摘要:Ono, N., Science of Synthesis, (2007) 33, 365.
    摘要:Burmester, C.; Haß, O.; Faust, R., Science of Synthesis, (2008) 43, 240.
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