专利号:US-5144069-A 优先权日:1990-12-13 标题 :Process for the preparation of fluoroaliphatic aminocarboxylate surfactants 发明人:STERN RICHARD M; GUENTHNER RICHARD A; ALM ROGER R; WILKINSON THOMAS K 权利人:MINNESOTA MINING & MFG 摘要:A process for the synthesis of the fluorochemical compound having formula n n R.sub.f SO.sub.2 N(CHR.sup.2 --CHR.sup.2 COO.sup.-) R.sup.1 N.sup.+ n n (R) 2 H n wherein R f is a fluoraliphatic radical containing at least 3 carbon atoms. The synthesis involves reaction of compounds of formula R f SO 2 N(H)R 1 N(R) 2 and CHR 2 â•?CH 2 COOH in solution at elevated temperatures. The process can be used to synthesize the fluoroaliphatic amphoteric amino carboxylate surfactant having the formula: n n C.sub.6 F.sub.13 SO.sub.2 N(C.sub.2 H.sub.4 COO.sup.-) C.sub.3 H.sub.6 n n N + (CH 3 ) 2 H n which compound is useful in aqueous film-forming foamable concentrates for extinguishing flammable liquid fires.
专利号:WO-2010015211-A1 优先权日:2008-08-07 标 题:Synthesis of oxazoline compounds 发明人:CHAN ALBERT SUN-CHI; DING KAI; YU WING-YIU 权利人:UNIV HONG KONG POLYTECHNIC; CHAN ALBERT SUN-CHI; DING KAI; YU WING-YIU 摘要:The present invention provides an improved process for preparing an oxazoline compound of the formula: (I) wherein R 1 and R 2 are independently hydrogen, sulfide, sulfoxide, sulfonyl, optionally substituted lower alkyl, optionally substituted aralkyl, optionally substituted aryl or optionally substituted polycyclic arylyl; or R 1 and R 2 combined together with the carbon atoms to which they are attached form an optionally substituted fused 6-member aromatic ring provided that R 1 and R 2 are attached to carbon atoms adjacent to each other; and R 3 is hydrogen, sulfide, sulfoxide, sulfonyl, optionally substituted lower alkyl, optionally substituted aralkyl, optionally substituted aryl or optionally substituted polycyclic arylyl; or an enantiomer therof; or an enantiomeric mixture therof; comprising the step of contacting an acylamino alcohol compound to a suitable amount of fluoroalkanesulfonyl fluoride compound and organic basic reagent. By using a fluoroalkanesulfonyl fluoride compound with an organic basic reagent, the present invention efficiently converts acylamino alcohol compounds into highly chemoselective oxazoline compounds with a remarkable variety of substrates, mild conditions and relatively short reaction time.
专利号:US-5399756-A 优先权日:1993-07-29 标题:Process for the production of liquid amine adducts of fluorine-containing amides 发明人:SCHNEIDER WOLFGANG; STACHULLA KARLHEINZ; POHMER KLAUS; WEBER RAINER; SCHLAK OTTFRIED; MORETTO HANS-HEINRICH 权利人:BAYER AG 摘要:The invention relates to an improved process for the production of liquid amine adducts of fluorine-containing amides, in which the compounds are synthesized in the absence of solvents in two process steps without the synthesis of intermediate products.
专利号:CN-115650884-A 优先权日:2022-10-10 标题 :A kind of ionic ammonium salt short-chain fluorocarbon surfactant and its synthesis method
参考标题:Synthesis Of Symmetric And Dissymetric Bisperfluoroalkanesulfonylimides And Evaluation Of Their Inhibition On Bovine Carbonic Anhydrase 作者:Zohra Benfodda,Franck Guillen,Hubert Blancou |发布日期:2008.7 摘要:Describes A Synthesis Of Symmetric And Dissymmetric Bis[(Perfluoroalkane)-Sulfonyl]Imides By The Reaction Of The Sodium Salt Of Perfluoroalkanesulfonamide Rfso2Nh−na+ (Rf = C4F9, C6F13, C8F17) With Hexamethyldisilazane And Perfluoroalkanesulfonylfluoride Rfso2F (Rf = C4F9, C6F13, C8F17). They Are Obtained, In Two Steps, In Moderate Overall Yield. Moreover, This Paper Provides A Study Of Their Inhibition On
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摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775 摘要:S74 | REFTPS | Transformation Products and Reactions from Literature | DOI:10.5281/zenodo.4318838