📜2-Acetoxy-1-Acetylsulfanyl-Propane置于盐酸体系中,用 甲醇 用作溶剂,化学反应生成1-巯基-2-丙醇 参考文献:Synthesis Of Possible Cancer Chemotherapeutic Compounds Based On Enzyme Approach. Iii. 1,2,3-Oxadithiolane 2-Oxide1 标题:Synthesis Of Possible Cancer Chemotherapeutic Compounds Based On Enzyme Approach. Iii. 1,2,3-Oxadithiolane 2-Oxide1 摘要: Doi:10.1021/jo01070A051
专利号:US-4910330-A 优先权日:1987-09-25 标题 :Synthesis of sulfonic acids and carboxylic acid ester derivatives thereof 发明人:MCGEE DENNIS E; HALLEN TED S 权利人:UNION OIL CO 摘要:Hydroxy sulfonic acids in general and isethionic acid (2-hydroxy ethyl sulfonic acid) in particular can be prepared at 99+% purity and good yields by the selective oxidation of a precursor hydroxy mercaptan with hydrogen peroxide. The resulting product is pure enough to be used directly in the synthesis of sulfo-acrylic esters which are finding considerable use as stabilizers in producing vinylidene chloride copolymers used for FDA approved packaging films.
专利号:US-4987250-A 优先权日:1987-09-25 标 题:Synthesis of hydroxy sulfonic acids 发明人:MCGEE DENNIS E; HALLEN TED S 权利人:UNION OIL CO 摘要:Hydroxy sulfonic acids in general and isethionic acid (2-hydroxy ethyl sulfonic acid) in particular can be prepared at 99+% purity and good yields by the selective oxidation of a precursor hydroxy mercaptan with hydrogen peroxide. The resulting product is pure enough to be used directly in the synthesis of sulfo-acrylic esters which are finding considerable use as stabilizers in producing vinylidene chloride copolymers used for FDA approved packaging films.
专利号:US-11180507-B2 优先权日:2016-07-08 标题:Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor 发明人:CUI XINYAN; CAO BIN 权利人:UNIV PITTSBURGH COMMONWEALTH SYS HIGHER EDUCATION; UNIV OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION 摘要:A method of forming a compound having the formula (I′): (I′) includes the reaction: (II′) in the presence of a base, wherein X is a halo atom selected from the group consisting of Cl, Br and I.
专利号:US-8673260-B2 优先权日:2012-01-04 标 题 :Development of earth-abundant mixed-metal sulfide nanoparticles for use in solar energy conversion 发明人:PLASS KATHERINE 权利人:FRANKLIN AND MARSHALL COLLEGE 摘要:This invention relates to a process for the phase-controlled synthesis of ternary and quaternary mixed-metal sulfide nanoparticles by reacting soft metal ions with hard metal ions in a high-boiling organic solvent in the presence of a complexing and activating ligands to control the reactivity of the metal ions. Ternary and quaternary mixed metal sulfides nanoparticles of copper, sulfur, and iron, aluminum, tin, and silicon are preferred. This invention also relates to the phase controlled preparation of polymorphs of bornite nanoparticles and the phase controlled preparation of stabilized α- and γ-chalconite nanoparticles.
专利号:US-5331096-A 优先权日:1992-04-01 标题 :2- and 3-sulfur derivatives of 1,5-iminosugars 发明人:KOSZYK FRANCIS J; MUELLER RICHARD A 权利人:SEARLE & CO 摘要:Novel derivatives of 1-deoxynojirimycin are disclosed which have thio or sulfinyl substituents at C-2 or C-3. These compounds are useful inhibitors of lentiviruses such as visna virus and human immunodeficiency virus. Methods of chemical synthesis of these derivatives and intermediates therefor are also disclosed.
专利号:US-9634161-B2 优先权日:2013-05-01 标题 :Nanoscale precursors for synthesis of Fe2(Si,Ge)(S,Se)4 crystalline particles and layers 发明人:RADU DANIELA RODICA; LAI CHENG-YU 权利人:RADU DANIELA RODICA; LAI CHENG-YU; DELAWARE STATE UNIV 摘要:Thin films comprising crystalline Fe 2 XY 4 , wherein X is Si or Ge and Y is S or Se, are obtained by coating an ink comprised of nanoparticle precursors of Fe 2 XY 4 and/or a non-particulate amorphous substance comprised of Fe, X and Y on a substrate surface and annealing the coating. The coated substrate thereby obtained has utility as a solar absorber material in thin film photovoltaic devices.
[参考文献]: Ting F Zhu, Et Al. Photochemically Driven Redox Chemistry Induces Protocell Membrane Pearling And Division. Proc Natl Acad Sci U S A. 2012 Jun 19;109(25):9828-32.
合成参考文献
摘要:Echavarren, A. M.; Porcel, S., Science of Synthesis, (2006) 28, 519. 摘要:Saito, M.; Nakayama, J., Science of Synthesis, (2008) 39, 638. 摘要:Comasseto, J. V.; Guarezemini, A. S., Science of Synthesis, (2008) 39, 414.