CAS: 99-75-2; Methyl 4-Methylbenzoate

上下游产品

CAS号681-84-5 原硅酸四甲酯 | CAS号104-87-0 对甲基苯甲醛 | CAS号98-59-9 对甲苯磺酰氯(PTSC) | CAS号67-56-1 甲醇 | CAS号2789-88-0 1, 2-二-对甲苯炔 | CAS号201230-82-2 carbon monoxide | CAS号106-38-7 对溴甲苯 | CAS号624-31-7 对碘甲苯 | CAS号3287-02-3 1-甲基-4-(苯乙炔基)苯 | CAS号99-94-5 对甲基苯甲酸 | CAS号103094-70-8 methyl 4-(4-oxo... | CAS号34040-64-7 4-氯甲基苯甲酸甲酯 | CAS号56525-63-4 3-氯-4-甲基苯甲酸甲酯 | CAS号31130-15-1 5-(4-甲基苯基)-1,3,... | CAS号52787-14-1 4-甲酸甲酯苯乙酸甲酯 | CAS号3247-00-5 三-对甲苯基甲醇 | CAS号589-18-4 4-甲基苄醇 | CAS号22717-57-3 5-甲基水杨酸甲酯 | CAS号4670-56-8 4-甲基水杨酸甲酯 | CAS号14062-78-3 N,N-二甲基-4-甲基苯甲酰胺

Methyl Methoxy(P-Tolyl)Methylenecarbamate置于对甲苯磺酸一水合物,三乙胺体系中,用 甲醇,水 作为反应溶剂,化学反应 10.17H,以90%的收率获得产物对甲基苯甲酸甲酯
参考文献:通过有机硼与n-[甲氧基(甲硫基)亚甲基]氨基甲酸甲酯的钯催化的单碳延伸反应偶联制备酰亚胺
标题:通过有机硼与n-[甲氧基(甲硫基)亚甲基]氨基甲酸甲酯的钯催化的单碳延伸反应偶联制备酰亚胺
摘要:描述了通过钯催化的偶联反应作为一碳延伸反应制备酰亚胺.在噻吩-2-羧酸铜(i)存在下,芳基-,烷基-和烯基硼与n-[甲氧基(甲硫基甲基)亚甲基]氨基甲酸酯的钯催化偶联反应提供亚氨基醚,该亚氨基醚被转化为酸水解得到相应的酰亚胺,产率很高.亚氨基醚也可用于制备相应的酯而不使用一氧化碳.
DOI:10.1021/ol303062A

专利信息

专利号:US-4219489-A
优先权日:1978-09-05
标题:Synthesis of steroids
发明人：BUNES LEONARD A; JOHNSON WILLIAM S
权利人:STANFORD LELAND JUNIOR UNIV TR
摘要:Method and compounds are provided for use in the synthesis of steroids wherein a polyolefin is provided having an initiating group having a chalcogen atom in juxtaposition to a double bond, so as to be capable of bond formation to close to form a ring and having a terminating group involving pi unsaturation (a double or triple bond) conjugated to an aromatic ring. Upon acid catalysis, sigma bonds are formed through the interaction of a carbocation formed at the carbon atom bonded to the chalcogen atom and the double bond intermediate the initiating group and the terminating group, which close to form rings of a steroid nucleus, the carbocation interacting with the pi unsaturation conjugated with the aromatic group and being captured by a nucleophile present in the acidic reaction medium. The resulting steroid product may then be modified in known ways to produce known steroids.

专利号:US-5166110-A
优先权日:1989-12-22
标 题 :Process for the synthesis of ziegler-type catalytic solids or solid constituents of the same
发明人：BRUN CLAUDE
权利人:ATOCHEM ELF SA
摘要:A process is provided for the synthesis of a solid Ziegler catalyst or of a transition metal solid constituent thereof, which entails preparing the solid catalyst or constituent thereof as a suspension in an inert liquid medium by contacting precursors or ingredients of the catalyst or of the constituent in the inert liquid medium in one or more steps, and drying the suspension, and collecting the catalyst or constituent thereof; and wherein the process is conducted in a single multi-function reactor having a longitudinal axis and which can pivot around an axis which intersects perpendicularly with this axis.

专利号:WO-2013144924-A1
优先权日:2012-03-29
标 题:An improved process for the synthesis of strobilurin fungicides viz trifloxystrobin and kresoxim-methyl
发明人：KAMARAJ PASUMPON; SATAM VIJAY SHRIKANT; AJJANNA MAHALINGAPPA SRIDHARA; NANDI TAPASKUMAR; BOBADE ANNA; SHINDE RAVINDRA; NAIK PARAG; MOHITE DHANAJI; KADAM SUBHASH; HINDUPUR RAMA MOHAN; PATI HARI NARAYAN; MANE AVINASH; VADIRAJ SUPHALA GOPINATH; VENKATESH PRABHU MOODBIDRI
权利人:RALLIS INDIA LTD
摘要:The present invention relates to an improved process for the synthesis of E -isomer of compound of formula (5). It further relates to the conversion of formula (5), wherein R is H, to Intermediate (I) and subsequently to substantially pure Trifloxystrobin, compound of formula (I) in good yield.

专利号:EP-1641729-B1
优先权日:2003-07-09
标题:Use of functionalized onium salts as a soluble support for organic synthesis
发明人：VAULTIER MICHEL; GMOUH SAID; HASSINE FATIMA
权利人:CENTRE NAT RECH SCIENT; UNIV RENNES
摘要:The invention relates to the use of a onium salt functionalized by at least one organic function, as a soluble support, in the presence of at least one organic solvent, for organic synthesis of a molecule, in a homogenous phase, by at least one transformation of said organic function. The onium salt enables the synthesized molecule to be released. The onium salt is present in liquid or solid form at room temperature and corresponds to formula A₁⁺, X₁^-, wherein A₁⁺ represents a cation and X₁^- represents an anion.

专利号:US-6048991-A
优先权日:1990-11-16
标题:Preparation of epoxides
发明人：HAERMELING DIETER
权利人:BASF AG
摘要:Alpha-hydroxy-epoxides of alpha-alkoxy-epoxides of the formula IV ##STR1## in which the substituents have the following meanings: R 7 , R 8 , R 9 , R 10 , R 11 are independently hydrogen, C 1 -C 20 -alkyl, C 3 -C 12 -cycloalkyl, C 4 -C 20 -cycloalkylalkyl, C 1 -C 20 -hydroxy-alkyl, a heterocyclic ring, or an aryl or C 7 -C 20 -arylalkyl group optionally substituted by C 1 -C 8 -alkyl, C 1 -C 8 -alkoxy, halogen, C 1 -C 4 -haloalkyl, C 1 -C 4 -halo-alkoxy, phenyl, phenoxy, halophenyl, halophenoxy, carboxy, C 2 -C 8 -alkoxycarbonyl, or cyano, or R 7 and R 8 or R 7 and R 9 or R 7 and R 10 or R 9 and R 10 or R 10 and R 11 together form a (CH 2 ) n group in which n is an integer from 1 to 10 and which may be optionally substituted by C 1 -C 8 -alkyl, C 1 -C 8 -alkoxy, and/or halogen, and n R 12 is hydrogen, C 1 -C 8 -alkyl, or benzyl, n provided that R 10 is not hydrogen, methyl, ethyl, propyl, or cyclohexyl when R 7 , R 8 , R 9 , or R 11 is hydrogen, that R 7 is not methyl when R 8 is methyl or phenyl and R 9 , R 10 , or R 11 is hydrogen, that R 7 is not methyl when R 8 , R 9 , R 10 , or R 11 is hydrogen and R 12 is ethyl, that R 7 is not phenyl or hexyl when R 8 , R 9 , R 10 , or R 11 is hydrogen, that R 9 is not methyl when R 7 , R 8 , R 10 , or R 11 is hydrogen, that R 10 and R 11 are not methyl when R 7 , R 8 , or R 9 is hydrogen, and that R 7 and R 10 do not together form an unsubstituted cycloalkyl when R 8 , R 9 , or R 11 is hydrogen. The epoxides of the above formula serve as intermediates for the synthesis of, inter alia, perfumes, plant protectants and polymers.

专利号:US-2024067621-A1
优先权日:2021-02-23
标 题:Polyfluorinated cannabinoid and cannabinoid-like compounds and methods of synthesis and use thereof
发明人：WEAVER JIMMIE D; DAY JON; GROTJAHN SASCHA; SENAWEERA SAMEERA; KOENIG BURKHARD
权利人:WEAVER JIMMIE D; DAY JON; GROTJAHN SASCHA; SENAWEERA SAMEERA; KOENIG BURKHARD; THE BOARD OF REGENTS FOR THE OKLAHOMA AGRICULTURAL AND MECH COLLEGES
摘要:Polyfluorinated compounds are disclosed, including polyfluorinated cannabinoid and cannabinoid-like compounds. Also disclosed are methods of producing the polyfluorinated compounds.