CAS: 701921-71-3; Trihexyltetradecylphosphonium Dicyanamide

相似化合物

15294-63-0 81741-28-8 57702-65-5

📜三己基(四癸基)氯化膦,Sodium Dicyanamide 以 氯仿,水 作为反应溶剂,化学反应 24.0H,反应生成 三己十四烷化膦氨腈
参考文献:四烷基phosph基离子液体
标题:四烷基phosph基离子液体
摘要:离子液体是在室温或室温附近为液体的盐.它们的宽液体范围,非常好的热稳定性和极低的蒸气压使它们在众多应用中具有吸引力.产生离子液体的一般方法是使用一种大的,非反应性的,低对称性的阳离子,以及一个阴离子,该阴离子在很大程度上控制物理和化学性质.离子液体中最常用的阳离子是n-烷基吡啶鎓和n,N'-二烷基咪唑鎓.用于产生离子液体的另一种非常有效的阳离子是四烷基phosph,[pr 1 R 2 R 3 R 4] +.烷基,R N,通常都很大,而且不尽相同.几种phospho阳离子的卤化物盐可用作制备离子液体的复分解反应的起始原料.大phospho阳离子可与相对大的阴离子结合,以制得配方质量大于1000 G Mol-1的粘稠但自由流动的液体.其他一些更重的盐是蜡和玻璃.测量并报道了阴离子具有广泛质量范围的-离子液体的合成以及物理,化学和光学性质.
DOI:10.1016/j.Jorganchem.2004.09.060

专利信息

专利号:US-9267213-B1
优先权日:2005-03-25
标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
发明人：MAURER KARL; COOPER JOHN J
权利人:CUSTOMARRAY INC
摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

专利号:US-10407676-B2
优先权日:2014-12-09
标题 :High efficiency, small volume nucleic acid synthesis
发明人：POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN
权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS
摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).

专利号:MX-2007011815-A
优先权日:2005-03-25
标题 :ELECTROCHEMICAL UNLOCK SOLUTION FOR ELECTROCHEMICAL SYNTHESIS OF OLIGOMEROS IN AN ARRANGEMENT OF ELECTRODES.

专利号:RU-2007139631-A
优先权日:2005-03-25
标题 :SOLUTION FOR ELECTROCHEMICAL DEPARTMENT IN ELECTROCHEMICAL SYNTHESIS OF OLIGOMERS ON THE ELECTRODE MATRIX