CAS: 32598-13-3; 3,3',4,4'-Tetrachloro-1,1'-Biphenyl
该化合物是一种氯化联苯衍生物,其特点是以四个氯原子替换在副位置,具有高度的热稳定性和低挥发性,适合需要耐热和阻燃性的应用,其非极性性有助于其在有机溶剂中的溶解性,在各种工业工艺中具有优势.
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;;;; - InChIKey: UQMGJOKDKOLIDP-UHFFFAOYSA-N
- InChI=1S/C12H6Cl4/c13-9-3-1-7(5-11(9)15)8-2-4-10(14)12(16)6-8/h1-6H
- 计算化学: 氢键受体数*氢键供体数*可旋转键数1.0
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
vinyl trifluoromethanesulfonate 3,4-dichlophenylboronic acid 2,3,7,8-Tetrachlorodibenzofuran 3,4,6,7-tetrachlorodibenzofuran 2,3,6,7-tetrachlorodibenzofuran 2,3,7,8-tetrachlorodibenzothiophene合成工艺路线路线简述
- 合成目标产物 3,3',4,4'-Tetrachlorobiphenyl 主要起始原料 3,4-Dichloroiodobenzene And 3,4-Dichlorophenylboronic Acid
- (文献来源)合成步骤主要原料 3,4-Dichloroiodobenzene 和 3,4-Dichlorophenylboronic Acid
📜邻二氯苯置于1,10-菲罗啉,(1,5-Cyclooctadiene)(Methoxy)Iridium(I) Dimer,Copper Diacetate,4,4'-二叔丁基-2,2'-二吡啶体系中,用 四氢呋喃,N,N-二甲基甲酰胺 用作溶剂,化学反应 36.0H,反应生成3,3,4,4-四氯联苯
参考文献:经由ch硼化的芳烃立体控制ch / Ch均偶联.
标题:经由ch硼化的芳烃立体控制ch / Ch均偶联.
摘要:描述了一种温和的一锅法方案,该方案通过顺序的ir催化的ch硼酸酯化和cu催化的芳烃均偶联合成对称的联芳基.所形成的联芳基的区域化学空间上受ch硼酸酯化步骤的控制.该方法还成功地扩展到了杂芳烃.通过这种方法获得的某些产品无法通过ullmann或suzuki耦合协议获得.最后,我们显示了一锅序列描述了ch硼化/ Cu催化的均偶联/ Pd催化的suzuki偶联以获得π扩展的芳烃骨架.
Doi:10.1039/c9Ob00995G
海关参考信息
- 2903911000-邻二氯苯
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- 详情请参考：📖 海关编码查询和海关进出口税则
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品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
[参考文献]: Ben F Brammell, Et Al. Differential Sensitivity Of Cyp1A To 3,3',4',4-Tetrachlorobiphenyl And Benzo(A)Pyrene In Two Lepomis Species. Comp Biochem Physiol C Toxicol Pharmacol. 2010 Jun;152(1):42-50.[参考文献]: Ben F Brammell, Et Al. Lack Of Cyp1A Responsiveness In Species Inhabiting Chronically Contaminated Habitats: Two Varieties Of Resistance. Comp Biochem Physiol C Toxicol Pharmacol. 2013 Mar;157(2):212-9.
[参考文献]: Kristine L Richardson, Et Al. Biotransformation Of 2,2',5,5'-Tetrachlorobiphenyl (Pcb 52) And 3,3',4,4'-Tetrachlorobiphenyl (Pcb 77) By Liver Microsomes From Four Species Of Sea Turtles. Chem Res Toxicol. 2011 May 16;24(5):718-25.
[参考文献]: Natalie A Chapados, Et Al. Increased Proliferative Effect Of Organochlorine Compounds On Human Preadipocytes. Mol Cell Biochem. 2012 Jun;365(1-2):275-8.
[参考文献]: Périne Doyen, Et Al. Identification And Mrna Expression Of Pi-Class Glutathione S-Transferase And Selenium-Dependent Glutathione Peroxidase In The Gudgeon Gobio Gobio Exposed To Pcb 77. Comp Biochem Physiol C Toxicol Pharmacol. 2012 Mar;155(2):300-6.
合成参考文献
参考文献:10.1016/j.jhazmat.2010.01.097
摘要:Zanaroli G, Balloi A, Negroni A, Daffonchio D, Young LY, Fava F. Characterization of the microbial community from the marine sediment of the Venice lagoon capable of reductive dechlorination of coplanar polychlorinated biphenyls (PCBs). J Hazard Mater. 2010 Jun 15;178(1-3):417–26. doi: 10.1016/j.jhazmat.2010.01.097.
参考文献:10.1530/rep.1.00761
摘要:Pocar P, Nestler D, Risch M, Fischer B. Apoptosis in bovine cumulus-oocyte complexes after exposure to polychlorinated biphenyl mixtures during in vitro maturation. Reproduction. 2005 Dec;130(6):857–68. doi: 10.1530/rep.1.00761.
参考文献:10.1093/toxsci/kfr189
摘要:He G, Tsutsumi T, Zhao B, Baston DS, Zhao J, Heath-Pagliuso S, Denison MS. Third-generation Ah receptor-responsive luciferase reporter plasmids: amplification of dioxin-responsive elements dramatically increases CALUX bioassay sensitivity and responsiveness. Toxicol Sci. 2011 Oct;123(2):511–22.
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