CAS: 137641-05-5; Picolinafen

该化合物是属于pyridinecarboxamide类的选择性除草剂,主要用于谷物作物中大叶草的抗冒前控制,其作用方式包括抑制长链脂肪酸(VLCFA)的延长,干扰易感染植物细胞膜形成.Picolinafen对诸如Galium aparine和Veronica spp等主要杂草物种表现出很高的功效,同时展示了小麦和大麦的作物安全性.该化合物的特点是其应用率低,通常为50-100克活性/公顷,而且土壤持久性最小,环境状况良好.其选择性和可靠的残留活动使得它成为综合杂草管理系统中有价值的组成部分,特别是易抗药性物种.

结构式图片

欧盟法规

[[ECHA物质C&L通报REACH预注册

上下游产品

CAS号98-17-9 3-三氟甲基苯酚 | CAS号371-40-4 4-氟苯胺 | CAS号201230-82-2 carbon monoxide | CAS号855-38-9 三(4-甲氧苯基)膦 | CAS号137640-94-9 N-(4-氟苯基)-6-氯-2...

合成工艺路线路线简述

    📜6-氯吡啶-2-羧酸置于三光气,Potassium Carbonate,三乙胺,Copper(L) Chloride体系中,用 二氯甲烷,乙酸乙酯,N,N-二甲基甲酰胺 用作溶剂,化学反应 13.0H,反应生成氟吡酰草胺
    参考文献:一种2-取代苯氧基-6-吡啶甲酰氯的制备方法及氟吡酰草胺的制备方法
    标题:一种2-取代苯氧基-6-吡啶甲酰氯的制备方法及氟吡酰草胺的制备方法
    摘要:本发明提供了一种2‑取代苯氧基‑6‑吡啶甲酰氯的制备方法及氟吡酰草胺的制备方法,采用双(三氯甲基)碳酸酯(固体光气)作为氯化试剂进行2‑(3‑三氟甲基苯氧基)‑6‑吡啶甲酸的酰氯化反应.本发明方法合成条件温和,安全,操作过程易于控制,后处理简便,废水量少,对环境友好,避免使用二氯亚砜等腐蚀性反应物,减少了如二氧化硫和氯化氢等污染性气体的排放和废水的排放,降低了对设备的要求,简化了操作,利于改进氟吡酰草胺除草剂的制备方法,具有广泛的应用前景.

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Lee JY, Park S, Lim W, Song G. Picolinafen exerts developmental toxicity via the suppression of oxidative stress and angiogenesis in zebrafish embryos. Pestic Biochem Physiol. 2021 Jan;171:104734. doi: 10.1016/j.pestbp.2020.104734. Epub 2020 Oct 16.
    201:12-23. doi: 10.1016/j.theriogenology.2023.02.015. Epub 2023 Feb 16. 75(1):195-203. doi: 10.1002/ps.5087. Epub 2018 Jul 30.
    155:51-57. doi: 10.1016/j.pestbp.2019.01.005. Epub 2019 Jan 17. 61(51):e202212873. doi: 10.1002/anie.202212873. Epub 2022 Nov 17.

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    摘要:S72 | NTUPHTW | Pharmaceutically Active Substances from National Taiwan University | DOI:10.5281/zenodo.3955664
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知