专利号:US-6599972-B2 优先权日:1996-12-24 标 题 :Latex compositions containing ethylenically unsaturated esters of fatty compounds and applications thereof 发明人:THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; FRUCHEY OLAN STANLEY 权利人:UNIV SOUTHERN MISSISSIPPI 摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated derivatives of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of fatty alcohols. A process for the synthesis of the latex composition is also disclosed, which involves (a) polymerization of the ethylenically unsaturated derivatives of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from -5 to 10° C. and cure to above ambient glass transition (Tg) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
专利号:US-6897255-B1 优先权日:1996-12-24 标题:Latex compositions containing ethylenically unsaturated esters of long-chain alkenols and applications thereof 发明人:THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; FRUCHEY OLAN STANLEY 权利人:UNIV SOUTHERN MISSISSIPPI 摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable long-chain alkenol ester monomers are disclosed and claimed. Preferred embodiments include latex formed from acrylate or methacrylate esters of long-chain alkenols. A process for the synthesis of the latex composition is also disclosed, which involves (a) esterification of a long-chain alkenol with an ethylenically unsaturated carboxylic acid; (b) polymerization of the ethylenically unsaturated ester in an aqueous phase with at least one other copolymerizable monomer; and (b) blending of so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
专利号:US-6203720-B1 优先权日:1996-12-24 标题 :Low MFT and high Tg , internally plasticizing, and low voc latex compositions 发明人:THAMES SHELBY FRELAND; PANJNANI KAMLESH GOPICHAND; HARIHARAN RAJAN; WANG ZHIYU 权利人:UNIV SOUTHERN MISSISSIPPI 摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
专利号:US-6624223-B1 优先权日:1996-12-24 标题 :Internally plasticized and low VOC latex compositions and applications thereof 发明人:THAMES SHELBY FRELAND; WANG ZHIYU; BRISTER ELIZABETH H; HARIHARAN RAJAN; KING COREY L; PANJNANI KAMLESH GOPICHAND 权利人:UNIV SOUTHERN MISSISSIPPI 摘要:Novel latex or emulsion compositions containing internally plasticizing and crosslinkable monomers derived from traditional semi-drying or non-drying oils are disclosed and claimed. The monomers are ethylenically unsaturated esters of long-chain olefinic compounds. Preferred embodiments include latex formed from acrylate or methacrylate esters of hydroxy fatty acid esters derived from castor oil or lesquerella oil. A process for the synthesis of the latex composition is also disclosed, which involves (a) an esterification reaction of ethylenically unsaturated carboxylic acid or its derivatives with a substituted hydroxy long-chain olefinic compound; (b) subsequent polymerization of the so formed ethylenically unsaturated ester of a long-chain olefinic compound in an aqueous phase with at least one other copolymerizable monomer; and (c) blending so formed polymer with at least one drier and a surfactant to form the novel latex or emulsion compositions. These compositions form films at low minimum film forming temperatures (MFT) ranging from −5 to 10° C. and cure to above ambient glass transition (T g ) polymers without the use of traditional organic cosolvents which contribute to environmental pollution via volatile organic compounds (VOCs) emissions. These compositions are therefore useful in waterborne coatings, contact and pressure sensitive adhesives, and inks.
专利号:US-9605376-B2 优先权日:2011-06-28 标题 :Treating materials with combined energy sources 发明人:MISTRY PRAVIN 权利人:MISTRY PRAVIN; MTIX LTD 摘要:Material treatment is effected in a treatment region by at least two energy sources, such as (i) an atmospheric pressure (AP) plasma and (ii) an ultraviolet (UV) laser directed into the plasma and optionally onto the material being treated. During processing, the material being treated may remain substantially at room temperature. Precursor materials may be dispensed before, and finishing material may be dispensed after treatment. Precursors may be combined in the plasma, allowing for in situ synthesis and dry treatment of the material. Electrodes (e 1 , e 2 ) for generating the plasma may comprise two spaced-apart rollers which, when rotating, advance the material through a treatment region. Nip rollers adjacent the electrode rollers define a semi-airtight cavity, and may have a metallic outer layer. Loose fibers and fragile membranes may be supported on a carrier membrane, which may be doped. Individual fibers may be processed. Electrostatic deposition may be performed. Topographical changes may be effected. Various laser configurations and parameters are disclosed.
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