CAS: 2039-96-5; Sodium 3-(Trimethylsilyl)Propane-1-Sulfonate

该化合物是一种磺酸化合物,由三甲基硅酸盐组组成,通常用作核磁共振光谱学中的化学转移参考,其主要优点包括水和极地有机溶剂的溶解性极佳,确保水体和非水体系统中的一致性能.该化合物具有高度的化学稳定性,适合精确的NMR校准和内部参照.其清晰定义的共振信号为0 ppm,用于三甲基硅质子的光谱解释.此外,它也是有机合成中有用的中间体,特别是在需要全氟辛烷磺酸功能的反应中.该产品在分析和合成应用中具有可靠性,因此受到重视.

结构式图片

上下游产品

tris(trimethylsilylpropyl)aluminium

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    专利信息


    专利号:US-3852307-A
    优先权日:1972-04-25
    标 题 :Synthesis of zearalanone and related compounds
    发明人:URRY W; MULLENBACH G
    权利人:COMMERCIAL SOLVENTS CORP
    摘要:WHEREIN X is an integer having a value from 0 to 6 inclusive and Y is an integer having a value from 3 to 8 inclusive. It also provides for new methods of making compounds useful in the synthesis of zearalanone and related compounds. The compounds 6-acetoxyhexanoic acid; 2-(5-hexenoyl)cyclohexanone; 7-keto-11-dodecenoic acid; 2-hydroxyethyl 7-keto11-dodecenoate ethylene ketal; N,N-dimethyl 7-keto-11dodecenamide ethylene ketal; 7-keto-11-dodecenal ethylene ketal; 9-keto-2,13-tetradecadienic acid ethylene ketal; 2-hydroxyethyl 9-keto-2,13-tetradecadienoate ethylene ketal; the sodium salt of ethyl 6-(6-keto-10-undecenyl)- Beta -dihydroresorcylate ethylene ketal; ethyl 3-bromo-6-(6-keto-10-undecenyl)- Beta dihydroresorcylate ethylene ketal; ethyl 6-(6-keto-10-undecenyl)Beta -resorcylate ehtylene ketal; ethyl 6-(6-keto-10-undecenyl)Beta -resorcylate ethylene ketal dibenzyl ether; ethyl 6-(6keto-10-hydroxyundecyl)- Beta -resorcylate ethylene ketal dibenzyl ether; and 6-(10-hydroxy-6-keto-undecyl)- Beta resorcylic acid dibenzyl ether are disclosed. Methods for preparing these compounds are also disclosed. This invention provides a new synthesis for zearalanone and for related compounds having more or fewer carbon atoms in the nonaromatic ring than does zearalanone, which related compounds and zearalanone are represented by the formula

    专利号:US-2012178710-A1
    优先权日:2009-07-01
    标题 :Synthesis of cyclic diguanosine monophosphate and thiophosphate analogs thereof
    发明人:JONES ROGER A; GAFFNEY BARBARA L
    权利人:JONES ROGER A; GAFFNEY BARBARA L; UNIV RUTGERS
    摘要:The invention provides methods for the synthesis of cyclic dinucleotides and thiophosphate analogs thereof as well as a new family of analogs of cyclic diguanosine monophosphate that includes a series of seven phosphorothioate derivatives that includes diastereomers of mono-, di-, and trithiophosphates.

    专利号:US-4937367-A
    优先权日:1987-07-15
    标 题:Process for the preparation of intermediates for the synthesis of fosfomycin
    发明人:CASTALDI GRAZIANO; GIORDANO CLAUDIO
    权利人:ZAMBON SPA
    摘要:A process is described for the preparation of intermediates useful in the synthesis of Fosfomycin. n More particularly, an enantioselective process is described for the preparation of derivatives of (1S,2S)-1,2-dihydroxypropyl-phosphonic acid of formula ##STR1## wherein R 2 and R 3 have the meanings reported in the specification.

    专利号:US-5292903-A
    优先权日:1991-08-22
    标 题:One step method for the preparation of difurfuryl diamines
    发明人:CONNER ANTHONY H; HOLFINGER MICHAEL S; HILL JR CHARLES G; MCKILLIP WILLIAM J; REIMANN ROLF H
    权利人:US DEPARTMENT OF AGRICULTURE A
    摘要:A synthetic procedure for the synthesis of diamino difurfuryl compounds via a one-step, low-temperature reaction that does not require additional steps for the protection of the amino functionalities in the reactant or the deprotection of the amino functionalities in an intermediate product to give the final product is disclosed. The importance of acid concentration, reaction temperature, and reaction time to the one step method are disclosed.

    专利号:US-2014316101-A1
    优先权日:2011-12-09
    标 题:One-pot synthesis of sibnc preceramic polymer
    发明人:WILFERT JAKOB; JANSEN MARTIN
    权利人:MAX PLANCK GES ZUR FÖRDERUNG DER WISSENSCHAFTEN E V
    摘要:The present invention relates to a one-pot synthesis for an SiBNC preceramic polymer.

    专利号:US-2017204442-A1
    优先权日:2014-05-29
    标题 :Enzymatic synthesis of soluble glucan fiber
    发明人:DICOSIMO ROBERT; CHENG QIONG; ELIOT ANDREW C; OUWEHAND ARTHUR; PAYNE MARK S; YOU ZHENG
    权利人:DU PONT
    摘要:An enzymatically produced soluble α-glucan fiber composition is provided suitable for use as a digestion resistant fiber in food and feed applications. The soluble α-glucan fiber composition can be blended with one or more additional food ingredients to produce fiber-containing compositions. Methods for the production and use of compositions comprising the soluble α-glucan fiber are also provided.
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    合成参考文献


    参考文献:10.1007/bf00731448
    摘要:Curto EV, Sakai TT, Jablonsky MJ, Rio-Anneheim S, Jacquinet JC, Krishna NR. Complete 1H NMR assignments of synthetic glycopeptides from the carbohydrate-protein linkage region of serglycins. Glycoconj J. 1996 Aug;13(4):599–607. doi: 10.1007/bf00731448.
    参考文献:10.1023/a:1011206701288
    摘要:van den Burg HA, de Wit PJGM, Vervoort J. Efficient 13C/15N double labeling of the avirulence protein AVR4 in a methanol-utilizing strain (Mut+) of Pichia pastoris. Journal of Biomolecular NMR. 2001 Jul;20(3):251–61. doi: 10.1023/a:1011206701288.
    参考文献:10.1023/a:1011208109853
    摘要:Pervushin K. The use of TROSY for detection and suppression of conformational exchange NMR line broadening in biological macromolecules. J Biomol NMR. 2001 Jul;20(3):275–85. doi: 10.1023/a:1011208109853.
    参考文献:10.1023/a:1015061222433
    摘要:Pashkov VS, Mareeva TIu, Balashova TA, Vychalkovskiĭ AA, Samokhvalova LV, Baĭdakova LK, Rodionov IL, Nesmeianov VA. [Bacteriorhodopsin retains the conformation of Val69-Gly72 fragment during functioning]. Bioorg Khim. 2002 Mar;28(2):109–17. doi: 10.1023/a:1015061222433.
    参考文献:10.2116/analsci.22.645
    摘要:Park JJ, Kim KW, Park TJ, Park EW, Kim Y. Solid-state NMR spectroscopy of silicon-treated rice with enhanced host resistance against blast. Anal Sci. 2006 Apr;22(4):645–8. doi: 10.2116/analsci.22.645.
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