CAS: 1124-19-2; Phenyltin Trichloride

该化合物是有机锡化合物,其特征是锡原子中存在一个联苯组,该化合物与三个氯原子进一步协调,该化合物一般看起来无色可与青黄液体有关,以其高活性闻名,特别是在水分可导致水解的湿度情况下.三氯苯基主要用作各种有机锡化合物合成的前体和农业应用中的生物杀灭剂.它具有毒理特性,对水生生物有害,接触时可能危害人类健康.由于其环境持久性和生物累积潜力,其使用受到监管审查.适当处理和处置措施对于减轻与该化合物相关的风险至关重要.总的来说,三氯苯基在工业应用中起着重要的化学作用,但对环境和健康的影响需要谨慎管理.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号595-90-4 四苯基锡 | CAS号10294-34-5 三氯化硼 | CAS号1125-27-5 乙基苯基二氯硅烷 | CAS号7646-78-8 四氯化锡 | CAS号149-74-6 甲基苯基二氯硅烷 | CAS号87518-43-2 triphenyl(8-tri... | CAS号5588-71-6 triphenyl(5-tri... | CAS号86623-72-5 triphenyl(3-tri... | CAS号5274-40-8 triphenyl(4-tri... | CAS号42393-74-8 N-phenyl-N-(2-(... | CAS号1082283-43-9 5-Chloro-3-phen... | CAS号143363-50-2 tri°Ctyl(phenyl... | CAS号92-69-3 4-苯基苯酚 | CAS号92-88-6 4,4'-二羟基联苯 | CAS号92-67-1 4-氨基联苯 | CAS号947-84-2 2-苯基苯甲酸 | CAS号90-41-5 2-氨基联苯 | CAS号1806-29-7 2,2'-二羟基联苯 | CAS号90-43-7 2-苯基苯酚 | CAS号21572-26-9 Phenyltrivinyls...

合成工艺路线路线简述

    📜三苯基碘锡置于na,Ch3I体系中,用 氨 用作溶剂,化学反应生成苯基三氯化锡
    参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.15.1,Page 353-359
    标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.2,1.1.2.15.1,Page 353-359

    海关参考信息

    专利信息


    专利号:US-10294336-B2
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use
    发明人：KOENIG CHRISTIAN; EMGE ANDREAS; OTERO MARTINEZ IRAN
    权利人:BASF SE
    摘要:The present invention relates to the synthesis of polymer polyols in unsaturated polyols as liquid phase, polymer polyols and their use.

    专利号:US-12077552-B2
    优先权日:2021-09-14
    标 题:Synthesis of fluoroalkyl tin precursors
    发明人：KUIPER DAVID
    权利人:ENTEGRIS INC
    摘要:The invention provides certain fluorinated alkyl tin compounds which are believed to be useful in the vapor deposition of tin-containing films onto the surface of microelectronic device substrates. Also provided are processes for the preparation of the precursor compounds and processes for the use of such compounds in the deposition of tin-containing films onto microelectronic device substrates.

    专利号:US-2018009956-A1
    优先权日:2014-11-27
    标题 :Synthesis of polymer polyols in unsaturated polyols, polymer polyols and their use

    专利号:TW-202321268-A
    优先权日:2021-09-14
    标 题:Synthesis of fluoroalkyl tin precursors

    专利号:US-2023098280-A1
    优先权日:2021-09-14
    标 题:Synthesis of fluoroalkyl tin precursors

    专利号:US-8329923-B2
    优先权日:2010-06-17
    标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
    发明人：VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
    权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
    摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

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    合成参考文献


    摘要:Gandeepan, P.; Cheng, C.-H., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 87.
    摘要:Zhang, M.; Su, W., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 94.
    摘要:Schafer, E. W., Jr., W. A. Bowles Jr., and J. Hurlbut. 1983. The acute oral toxicity and repellency and hazard potential of 998 chemicals to one or more species of wild and domestic birds. Archives of Environmental Contamination and Toxicology 12:355-382.
    参考文献:10.1007/s002040050603
    摘要:Ema M, Miyawaki E, Kawashima K. Suppression of uterine decidualization as a cause of implantation failure induced by triphenyltin chloride in rats. Arch Toxicol. 1999 Apr;73(3):175–9. doi: 10.1007/s002040050603.
    参考文献:10.1007/s10661-006-9278-6
    摘要:Ščančar J, Zuliani T, Turk T, Milačič R. Organotin Compounds and Selected Metals in the Marine Environment of Northern Adriatic Sea. Environmental Monitoring and Assessment. 2006 Aug 18;127(1-3):271–82. doi: 10.1007/s10661-006-9278-6.
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