物理性质
- 熔点76-78 °C(溶剂: acetone (67-64-1); chloroform (67-66-3))
- 沸点260-270°C
- 闪点164 °C
- 密度70-400kg/m3
- PH:5-7.5 (100g/l, H2O, 20°C)(slurry)
- PSA:0.0
- LogP:0.0
- 折射率n20/D 1.504
- 蒸汽压1.08E-20 mmHg at 25 °C
- 溶解性Practically Insoluble In Water, In Acetone, In Anhydrous Ethanol, In Toluene, In Dilute Acids And In A 50 G/l Solution Of Sodium Hydroxide
- 外观形态白色或几乎白色粉末
- 储存条件室温
- 产品应用纤维素高分子中的羟基发生酯化或醚化反应,可衍生出许多有用的产品.实际应用的纤维素酯类有:纤维素硝酸酯,纤维素乙酸酯,纤维素乙酸丁酸酯和纤维素黄酸酯.纤维素醚类有:甲基纤维素,羧甲基纤维素,乙基纤维素,羟乙基纤维素,氰乙基纤维素,羟丙基纤维素和羟丙基甲基纤维素等.此外,还有酯醚混合衍生物
- 性质描述纤维素是由D-吡喃型葡萄糖基彼此以1,4-β-苷键连接而成的一种均一的高分子.纤维素分子除了两个端基外,每个葡萄糖基都有三个羟基.平均聚合度约10000左右.由于纤维素羟基的极性,水可进入非晶区,发生结晶区间的有限溶胀.某些酸,碱和盐的水溶液在一定条件下可渗入结晶区,产生无限溶胀,使纤维素溶解.最常用的纤维度溶剂是铜铵Cu(NH3)4(OH)2溶液和铜乙二胺[NH2CH2CH2NH2]Cu(OH)2溶液.
欧盟法规
C&L通报REACH预注册上下游产品
D-Glucose Cellobiose 4)-α-D-glucopyranosyl fluorideβ-D-glucopyranosyl-(1-4)-α-D-glucopyranosyl fluoridefuran acetaldehyde acetone 2-methylfuran合成工艺路线路线简述
- 9004-34-6 = 9004-34-6 + 57-11-4
反应条件:1.1 Catalysts: Triethylamine Solvents: Dichloromethane; 0 °C; 22 H,Rt
标题:Direct Conversion Of Sugarcane Bagasse Into An Injection-Moldable Cellulose-Based Thermoplastic Via Homogeneous Esterification With Mixed Acyl Groups
作者:Suzuki,Shiori; Et Al
参考文献:Acs Sustainable Chemistry & Engineering (2021 日期:Acs Sustainable Chemistry & Engineering (2021),9(17),5933-5941 卷标:9(17) 页码:5933-5941]
9004-34-6 = 9004-34-6 + 57-11-4
反应条件:1.1 Reagents: Triethylamine Solvents: 1,4-Dioxane; Rt; 15 H,Reflux
标题:Homogeneous Acylation Of Cellulose Diacetate: Towards Bioplastics With Tuneable Thermal And Water Transport Properties
作者:Boulven,Manon; Et Al
参考文献:Carbohydrate Polymers (2019 日期:Carbohydrate Polymers (2019),206,674-684 卷标:206 页码:674-684]
638-08-4 + 9004-34-6 = 9004-34-6 + 57-11-4
反应条件:1.1 Reagents: Lithium Chloride Solvents: Dimethylacetamide; Overnight,Rt; 1 H,100 °C1.2 Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dimethylacetamide; 100 °C; 6 H,100 °C
标题:Long/short Chain Mixed Cellulose Esters: Effects Of Long Acyl Chain Structures On Mechanical And Thermal Properties
作者:Tanaka,Shukichi; Et Al
参考文献:Acs Sustainable Chemistry & Engineering (2017 日期:Acs Sustainable Chemistry & Engineering (2017),5(2),1485-1493 卷标:5(2) 页码:1485-1493]
57-11-4 = 9004-34-6 + 57-11-4
反应条件:1.1 1 H,100 °C2.1 Reagents: Lithium Chloride Solvents: Dimethylacetamide; Overnight,Rt; 1 H,100 °C2.2 Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dimethylacetamide; 100 °C; 6 H,100 °C
标题:Long/short Chain Mixed Cellulose Esters: Effects Of Long Acyl Chain Structures On Mechanical And Thermal Properties
作者:Tanaka,Shukichi; Et Al
参考文献:Acs Sustainable Chemistry & Engineering (2017 日期:Acs Sustainable Chemistry & Engineering (2017),5(2),1485-1493 卷标:5(2) 页码:1485-1493]
9004-34-6 + 57-11-4 = 9004-34-6 + 57-11-4
反应条件:1.1 Solvents: 1-Butyl-3-Methylimidazolium Chloride; 2 H,Rt
标题:Preparation Of Cellulose Stearate And Cellulose Acetate Stearate In 1-Butyl-3-Methylimidazolium Chloride
作者:Tarasova,Elvira; Et Al
参考文献:Key Engineering Materials (2013 日期:Key Engineering Materials (2013),559,105-110,7 Pp. 卷标:105-110 页码:7 Pp.]
9004-34-6 = 9004-34-6 + 57-11-4
反应条件:1.1 Catalysts: Stannous Octoate Solvents: 1-Butyl-3-Methylimidazolium Chloride; 1.5 - 2 H,80 °C2.1 Solvents: 1-Butyl-3-Methylimidazolium Chloride; 2 H,Rt
标题:Preparation Of Cellulose Stearate And Cellulose Acetate Stearate In 1-Butyl-3-Methylimidazolium Chloride
作者:Tarasova,Elvira; Et Al
参考文献:Key Engineering Materials (2013 日期:Key Engineering Materials (2013),559,105-110,7 Pp. 卷标:105-110 页码:7 Pp.
海关参考信息
- 2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇
2905399001-1,3-丙二醇 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:US-2008032964-A1
优先权日:2006-04-10
标题:Process for the synthesis of azetidinone
发明人:KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
权利人:KANSAL VINOD K; AHMAD SUHAIL; MARIAPPAN SHANMUGAVEL; TYAGI BHUPENDRA; PERLMAN NURIT; LE PAIH JACQUES; ZANOTTI-GEROSA ANTONIO
摘要:Provided are intermediates useful for the synthesis of hydroxyl-alkyl substituted azetidinones, processes of their preparation, and processes for the synthesis of certain hydroxyl-alkyl substituted azetidinones. Also provided are processes for the synthesis of 1-(4-fluorophenyl)-3(R)-[3-(4-fluorophenyl)-3(S)-hydroxypropyl]-4(S)-(4-hydroxyphenyl)-2-azetidinone, or ezetimibe.
专利号:US-8541571-B2
优先权日:2008-03-03
标题:Homogeneous synthesis of cellulose ethers in ionic liquids
发明人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH
权利人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH; SE TYLOSE GMBH & CO KG
摘要:The invention is directed to a simple and new method for the homogeneous synthesis of cellulose ethers. Ionic liquids are not only used as solvent, but also as reaction media for the homogeneous etherification of cellulose. The dissolved cellulose is treated with the etherification agent in the absence of organic and/or inorganic bases and in the absence and/or in the presence of moderate amounts of water. The obtained cellulose ethers show new distributions of substitution on the polymer chain, resulting in new properties and applications.
专利号:US-5436143-A
优先权日:1992-12-23
标题:Method for enzymatic synthesis of oligonucleotides
发明人:HYMAN EDWARD D
摘要:Enzymatic synthesis of oligonucleotides may be performed in a single vessel without intermediate purification, by the steps of: n (a) combining a nucleotide primer sequence and a blocked nucleotide in the presence of a chain extending enzyme whereby a reaction mixture is formed containing the blocked nucleotide coupled to the nucleotide primer sequence at its 3' end; n (b) inactivating the chain extending enzyme; n (c) removing the blocking group from the primer-blocked nucleotide to form a primer-nucleotide product; and converting any unreacted blocked nucleotide to an unreactive form which is substantially less active as a substrate for the chain extending enzyme than the blocked nucleotide.
专利号:US-9982005-B2
优先权日:2013-04-04
标 题 :Macrolides and methods of their preparation and use
发明人:MYERS ANDREW G; SEIPLE IAN BASS; ZHANG ZIYANG
权利人:HARVARD COLLEGE
摘要:Provided herein are methods of preparing macrolides by the coupling of an eastern and western half, followed by macrocyclization, to provide macrolides, including both known and novel macrolides. Intermediates in the synthesis of macrolides including the eastern and western halves are also provided. Pharmaceutical compositions and methods of treating infectious diseases and inflammatory conditions using the inventive macrolides are also provided. A general diastereoselective aldol methodology used in the synthesis of the western half is further provided.
专利号:US-11466046-B2
优先权日:2014-10-08
标题 :14-membered ketolides and methods of their preparation and use
发明人:MYERS ANDREW G; SEIPLE IAN BASS; ZHANG ZIYANG
权利人:HARVARD COLLEGE
摘要:Provided herein are methods of preparing new 14-membered ketolides via coupling of an eastern and western half moiety, followed by macrocyclization, and optional functionalization. Intermediates in the synthesis of these ketolides including the eastern and western halves are also provided. Pharmaceutical compositions and methods of treating infectious diseases and inflammatory conditions using these ketolides are also provided.
专利号:US-2008015197-A1
优先权日:2006-06-26
标题 :Process for the preparatrion of zopiclone
发明人:MAINFELD ALEX; MENDELOVICI MARIOARA
权利人:MAINFELD ALEX; MENDELOVICI MARIOARA
摘要:Provided is a process for the preparation of zopiclone, an intermediate in the synthesis of eszopiclone.