CAS: 74-31-7; N1,N4-Diphenylbenzene-1,4-Diamine

该化合物是一种芳香二胺化合物,其特征是两个联苯组附于一个中苯-1,4-二胺核心的氮原子上,这种结构具有稳定性和高电子特性,在有机合成,聚合化学和材料科学等应用中有用,其硬性芳香框架有助于高热稳定性,而矿组则能够在凝聚和交叉反应中进行再活动.该化合物由于能够增强机械和电子特性,常常被用作包括聚胺和导导聚聚合物在内的先进材料的构件.

结构式图片

欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号108-90-7 氯苯 | CAS号101-54-2 对氨基二苯胺 | CAS号106-50-3 对苯二胺 | CAS号108-86-1 溴苯 | CAS号126150-65-0 benzene-1,4-dio... | CAS号109-79-5 正丁硫醇 | CAS号6246-98-6 N,N'-Diphenyl-1... | CAS号123-31-9 对苯二酚 | CAS号14118-16-2 N,N,N',N'-四苯基-1... | CAS号19606-98-5 N,N,N'-三苯基-1,4-苯二胺 | CAS号4369-14-6 3-三甲氧基硅烷丙烯酸丙脂 | CAS号19099-70-8 4-N-[4-(4-anili... | CAS号2716-09-8 1,4-Benzenediam... | CAS号824-69-1 2,5-二氯对苯二酚 | CAS号6246-98-6 N,N'-Diphenyl-1... | CAS号101-87-1 N-环己基-N'-苯基对苯二胺 | CAS号17754-68-6 1-N,4-N-dimethy... | CAS号88-99-3 邻苯二甲酸

合成工艺路线路线简述

    对氨基二苯胺置于钯体系中,用 5,5-Dimethyl-1,3-Cyclohexadiene,环己酮,硝基苯 作为反应溶剂,以40%的收率获得产物n,N'-二苯基-1,4-苯二胺
    参考文献:Process For Making Diarylamines
    标题:Process For Making Diarylamines
    摘要:在铂族金属催化剂和酸性促进剂的存在下,从脂环酮,一种主要芳香胺和氢受体制备二芳胺的改进工艺.

    海关参考信息

    专利信息


    专利号:US-12338202-B2
    优先权日:2021-09-10
    标 题 :One pot synthesis of urea (meth)acrylates
    发明人:BESTGEN SEBASTIAN; BEYER SILVIA
    权利人:EVONIK OPERATIONS GMBH
    摘要:A one-pot synthesis of polymerizable and acyclic urea (meth)acrylates, preferably mono(meth)acrylates, can be performed via in-situ synthesis of urea alcohols or amines followed by direct reaction with a (meth)acrylate reactive diluent. The urea alcohol/amine is obtained from isocyanates and alcohols, amines, or hydroxyamines. Subsequently, the reaction with the (meth)acrylate reactive diluent takes place and the urea (meth)acrylate is directly obtained either in solution with the reactive diluent, or as a pure material after removal of the reactive diluent.

    专利号:US-6329543-B1
    优先权日:1999-05-06
    标题:Process for synthesis of isobornyl (Meth) acrylate
    发明人:KNEBEL JOACHIM; SAAL DORIS
    权利人:ROEHM GMBH
    摘要:The present invention relates to processes for synthesis of isobornyl (meth)acrylate by reacting camphene with (meth)acrylic acid in the presence of sulfuric acid and at least one compound having inhibiting action. Aqueous sulfuric acid with an acid concentration in the range of 65 to 85 wt % is used. Isobornyl (meth)acrylate can advantageously be distilled from a mixture containing sulfuric acid in the presence of 2,6-di-tert-butyl-alpha-(dialkylamino)-p-cresol.

    专利号:US-7799944-B2
    优先权日:2003-09-05
    标题 :Process for the preparation of (meth)acrylate di-ammonium salts and their use as monomers for the synthesis of polymers
    发明人:VANNESTE PIET; LOENDERS RAF; VANDEN EYNDE IVAN; EECKHAOUDT SABINE
    权利人:TAMINCO N V
    摘要:The invention relates to the preparation of (meth)acrylate di-ammonium salts responding to formula (I) n nwherein R 1 represents hydrogen or methyl, each R 2 , independently, represents an alkyl comprising from 1 to 4 carbon atoms, each R 3 , independently, represents an alkyl or an aralkyl and each X − , independently, represents an anion;n nhaving a high purity and their use as monomers for the synthesis of polymers useful as cationic flocculants.

    专利号:US-4910330-A
    优先权日:1987-09-25
    标题 :Synthesis of sulfonic acids and carboxylic acid ester derivatives thereof
    发明人:MCGEE DENNIS E; HALLEN TED S
    权利人:UNION OIL CO
    摘要:Hydroxy sulfonic acids in general and isethionic acid (2-hydroxy ethyl sulfonic acid) in particular can be prepared at 99+% purity and good yields by the selective oxidation of a precursor hydroxy mercaptan with hydrogen peroxide. The resulting product is pure enough to be used directly in the synthesis of sulfo-acrylic esters which are finding considerable use as stabilizers in producing vinylidene chloride copolymers used for FDA approved packaging films.

    专利号:US-4987250-A
    优先权日:1987-09-25
    标 题:Synthesis of hydroxy sulfonic acids
    发明人:MCGEE DENNIS E; HALLEN TED S
    权利人:UNION OIL CO
    摘要:Hydroxy sulfonic acids in general and isethionic acid (2-hydroxy ethyl sulfonic acid) in particular can be prepared at 99+% purity and good yields by the selective oxidation of a precursor hydroxy mercaptan with hydrogen peroxide. The resulting product is pure enough to be used directly in the synthesis of sulfo-acrylic esters which are finding considerable use as stabilizers in producing vinylidene chloride copolymers used for FDA approved packaging films.

    专利号:US-6987186-B2
    优先权日:2003-01-28
    标 题 :Synthesis of small particle size quinacridone of beta crystal phase
    发明人:COLE DAMIEN THURBER; JEGANATHAN SURULIAPPA GOWDER; HE YINGXIA
    权利人:CIBA SC HOLDING AG
    摘要:The present invention relates to a process for the synthesis of beta-quinacridone by oxidation in the presence of selected additives that promote the formation of the desired crystal phase and particle size.
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    主要参考文献


    1: Ahmad F, Leake DS. Antioxidants inhibit low density lipoprotein oxidation less at lysosomal pH: A possible explanation as to why the clinical trials of antioxidants might have failed. Chem Phys Lipids. 2018 Mar 5;213:13-24. doi: 10.1016/j.chemphyslip.2018.03.001. [Epub ahead of print] doi: 10.1021/acs.jpca.7b09851. Epub 2018 Jan 9. doi: 10.1074/jbc.M115.680371. Epub 2015 Dec 8.
    4: Al Maruf A, O'Brien P. Flutamide-induced cytotoxicity and oxidative stress in an in vitro rat hepatocyte system. Oxid Med Cell Longev. 2014;2014:398285. doi: 10.1155/2014/398285. Epub 2014 Oct 13.
    5: Al Maruf A, Wan L, O'Brien PJ. Evaluation of azathioprine-induced cytotoxicity in an in vitro rat hepatocyte system. Biomed Res Int. 2014;2014:379748. doi: 10.1155/2014/379748. Epub 2014 Jul 1.

    合成参考文献


    摘要:Hay, M. B.; Hicks, J. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 2, 121.
    摘要:Prehled Prumyslove Toxikologie; Organicke Latky, Marhold, J., Prague, Czechoslovakia, Avicenum, 1986, -(485), 1986
    摘要:Hawley, G.G. The Condensed Chemical Dictionary. 9th ed. New York: Van Nostrand Reinhold Co., 1977., p. 318
    摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
    摘要:Budavari, S. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Whitehouse Station, NJ: Merck and Co., Inc., 1996., p. 564
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