📜2-甲基萘置于盐酸,聚合甲醛,溶剂黄146体系中,化学反应生成 1-氯甲基-2-甲基萘 参考文献:Darzens; Levy,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1936,Vol. 202,P. 73 标题:Darzens; Levy,Comptes Rendus Hebdomadaires Des Seances De L'Academie Des Sciences,1936,Vol. 202,P. 73
专利号:US-8193392-B2 优先权日:2005-07-29 标 题:Method for enantioselective synthesis of phosphorus-stereogenic phosphines 发明人:SCRIBAN CORINA; GLUECK DAVID S 权利人:SCRIBAN CORINA; GLUECK DAVID S; DARTMOUTH COLLEGE 摘要:The present invention relates to a process for preparing an enantioenriched phosphorus-stereogenic, tertiary phosphine. Secondary phosphines are contacted with an alkyl halide and base in the presence of a chiral metal catalyst thereby producing the enantioenriched phosphorus-stereogenic, tertiary phosphine for subsequent use in homogeneous catalysis reactions.
专利号:US-2008193357-A1 优先权日:2005-07-29 标 题:Method for Enantioselective Synthesis of Phosphorus-Stereogenic Phosphines
专利号:US-4528195-A 优先权日:1978-02-01 标题:Imidazole derivatives and salts thereof, their synthesis and intermediates and pharmaceutical formulations 发明人:THOROGOOD PETER B 权利人:THOROGOOD PETER B 摘要:Pharmaceutical formulations comprising an imidazole (or pharmaceutically acceptable salt thereof) of formula: ##STR1## wherein (i) A is an aliphatic hydrocarbon residue of from 1 to 4 carbon atoms and R is a naphthyl, tetrahydronaphthyl, heterocyclyl, arylthio, arylalkylthio, aryloxy, arylalkyloxy, arylhydroxymethylene, arylcarbonyl, arylalkylcarbonyl, alkyloxy, alkylthio or a substituted cycloalkyl or cycloalkenyl group or n (ii) A is an --SO 2 -- group and R is aryl or heterocyclyl or n (iii) A is a chemical bond and R is a heterocyclyl or n Some of these imidazoles and salts are novel. n Methods of preparing the imidazoles are disclosed. The imidazoles and their salts are useful in the treatment or prophylaxis of thrombo-embolic conditions, shock and angina pectoris.
专利号:US-3989746-A 优先权日:1972-05-11 标 题 :Substituted naphthyl anthranilic acids 发明人:NOHARA FUJIO; FUJINAWA TOMOAKI 权利人:IKEDA MOHANDO CO 摘要:This invention relates to novel N-(substituted-naphthyl-1)anthranilic acids and their salts, and also to a process for the synthesis of these compounds. These compounds and their pharmaceutically acceptable salts are novel and therapeutically useful as anti-inflammatory agents and analgesics, and they may be orally or non-orally applied, or administered by other methods.
专利号:CN-103626621-A 优先权日:2013-12-11 标 题:A new method for the synthesis of 1,2-dihydrocyclobuteno[α]naphthalene
专利号:WO-2007016264-A2 优先权日:2005-07-29 标题:Method for enantioselective synthesis of phosphorus-stereogenic phosphines
参考文献:10.1016/j.saa.2011.09.001 摘要:Nagabalasubramanian PB, Karabacak M, Periandy S. Molecular structure, polarizability, hyperpolarizability analysis and spectroscopic characterization of 1-(chloromethyl)-2-methylnaphthalene with experimental (FT-IR and FT-Raman) techniques and quantum chemical calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2012 Jan;85(1):43–52. doi: 10.1016/j.saa.2011.09.001.