苯硼酸频哪醇酯置于四(三苯基膦)钯,Potassium Carbonate,对甲苯磺酸,Potassium Iodide,Sodium Nitrite体系中,用 四氢呋喃,水,乙腈 用作溶剂,化学反应 4.0H,反应生成3-碘联苯
参考文献:Synthesis Of Substituted [8]Cycloparaphenylenes By [2 + 2 + 2] Cycloaddition
标题:Synthesis Of Substituted [8]Cycloparaphenylenes By [2 + 2 + 2] Cycloaddition
摘要:A New Modular Approach To The Smallest Substituted Cycloparaphenylenes (Cpps) Is Presented. This Versatile Method Permits Access To Substituted Cpps,Choosing The Substituent At A Late Stage Of The Synthesis. Variously Substituted [8]Cpps Have Been Synthesized,And Their Properties Analyzed. The Structural Characteristics Of Substituted Cpps Are Close To Those Of Unsubstituted Cpps. However,Their Optoelectronic Behavior Differs Remarkably Due To The Larger Torsion Angle Between The Phenyl Units.
Doi:10.1021/ol500194S