CAS: 5418-86-0; Tris(Methylthio)Methane

该化合物是一种含有硫的有机化合物,其特点是三(甲基硫)甲烷结构,该化合物作为有机合成的多用途中间体,特别是在准备硫化分子方面,其作用显著,其高含量和稳定的分子框架使其在诸如离子设计,协调化学和材料科学等应用中有用.该化合物显示与电极具有良好的热稳定性和回活动性,能够有选择地改变合成途径.其独特的化学特性还有助于农用化学和制药研究,因为基于硫的植物往往至关重要.处理需要有机硫化合物的标准防范措施.

结构式图片

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6267-24-9

欧盟法规

ECHA物质C&L通报

上下游产品

tetrachloromethane ethanol sodium thiomethoxide bis(methylthio)(methylsulfinyl)methane1,1,2-Tris-methylmercapto-3-(4-methoxy-phenyl)-propanon-(3) -propanon-(3)1,1,2-Tris-methylmercapto-3-4-nitro-phenyl-propanon-(3) -propanon-(3)1,1,2-Tris-methylmercapto-3-2-chlor-phenyl-propanon-(3) chlordimethylmercaptomethan

合成工艺路线路线简述

    📜(Toluene-4-Sulfonyl)-Dithiocarbonohydrazonic Acid Dimethyl Ester置于sodium Hydride,4-(1-苯基乙烯基)吗啉体系中,化学反应生成 三(甲基硫代)甲烷
    参考文献:Schoellkopf,U.; Wiskott,E.,Justus Liebigs Annalen Der Chemie,1966,Vol. 694,P. 44-55
    标题:Schoellkopf,U.; Wiskott,E.,Justus Liebigs Annalen Der Chemie,1966,Vol. 694,P. 44-55

    海关参考信息

    专利信息


    专利号:US-4309346-A
    优先权日:1980-03-27
    标 题:Process for the preparation of 1-carbapenems and intermediates via trithioorthoacetates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMANN THOMAS N
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the total synthesis of 1-carbapenem antibiotics (I) from L-aspartic acid via intermediates II and III: I II III wherein R is hydrogen, a pharmaceutically acceptable ester moiety or salt cation, or a readily removable blocking group; R6 and R7 are, inter alia, independently selected from the group consisting of hydrogen, alkyl, alkenyl, aryl and aralkyl; R1' is hydrogen or a protecting group; and Ra, Rb and Rc are independently selected from alkyl, aryl and aralkyl.

    专利号:US-4378315-A
    优先权日:1980-05-29
    标题:Process for the preparation of thienamycin and intermediates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMANN THOMAS N
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the total synthesis of thienamycin from L-aspartic acid via intermediate III: ##STR1## R=H, blocking group or salt cation.

    专利号:US-4290947-A
    优先权日:1979-04-27
    标 题:Process for the preparation of thienamycin and intermediates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMAN THOMAS N
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the total synthesis of thienamycin from L-aspartic acid via intermediate III: ##STR1## R=H, blocking group or salt cation.

    专利号:US-4739048-A
    优先权日:1980-05-29
    标 题:Process for the preparation of thienamycin and intermediates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMANN THOMAS N
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the total synthesis of thienamycin from L-aspartic acid via intermediate III: ##STR1##

    专利号:US-4736025-A
    优先权日:1981-05-11
    标题 :Process for the preparation of thienamycin and intermediates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMANN THOMAS N
    权利人:MERCK & CO INC
    摘要:Disclosed is a process for the total synthesis of thienamycin from L-aspartic acid via intermediate III: ##STR1## R=H, blocking group or salt cation.

    专利号:US-4610820-A
    优先权日:1979-07-23
    标 题:Process for the preparation of thienamycin and intermediates
    发明人:CHRISTENSEN BURTON G; RATCLIFFE RONALD W; SALZMANN THOMAS N
    权利人:MERCK & CO INC
    摘要:In a process for the total synthesis of thienamycin from L-aspartic acid via intermediate III: ##STR1## R=H, blocking group or salt cation there is disclosed a process for preparing III via ##STR2## wherein R is a protecting group.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Witt, D., Science of Synthesis Knowledge Updates, (2011) 3, 300.
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