CAS: 13629-22-6; (9H-Fluoren-9-Ylidene)Hydrazine

相似化合物

2157-52-0 153-78-6 4440-33-9

上下游产品

CAS号486-25-9 9-芴酮 | CAS号6630-65-5 9-氯芴 | CAS号5758-11-2 9H-Fluoren-9-on... | CAS号832-80-4 9H-Fluorene, 9-diazo | CAS号2071-44-5 N-(fluoren-9-yl... | CAS号751-35-9 Phosphorane, (f... | CAS号64-17-5 乙醇 | CAS号7803-57-8 水合肼 | CAS号861373-39-9 fluoren-9-ylide... | CAS号861373-41-3 (diethyl-phenyl... | CAS号86-73-7 芴 | CAS号7664-41-7 氨 | CAS号983-79-9 Benzophenone, azine | CAS号746-47-4 9,9-联亚茀 | CAS号885-39-2 9-(dibromomethy... | CAS号486-25-9 9-芴酮 | CAS号6630-65-5 9-氯芴 | CAS号835-17-6 9H-Fluorene, 9-... | CAS号2071-44-5 N-(fluoren-9-yl... | CAS号25023-01-2 9,9-二氯芴

📜9-芴酮置于hydrazine Hydrate,溶剂黄146体系中,用 甲醇 用作溶剂,化学反应 6.0H,反应生成9-芴酮腙
参考文献:钌,铑和铱的芴酮席夫碱衍生物配合物表现出有效的抗菌活性和dna结合亲和力
标题:钌,铑和铱的芴酮席夫碱衍生物配合物表现出有效的抗菌活性和dna结合亲和力
摘要:与9-芴酮衍生物配体l1,L2和l3反应的金属前体[(亚芳基)mcl 2 ] 2(亚芳基= 对-Cymene,Cp *; M = Ru,Rh和ir)导致单核双齿阳离子n的形成∩n键合配合物.这些复合物的诸如抗菌活性的研究(对革兰阳性和革兰氏阴性细菌)的生物的研究揭示了与络合物显著抗菌活性4,7和9具有最高的活性效力(体外).在进行dna结合研究时,结果显示复合物4和5 在添加sm-Dna时,它们的光谱特征发生了显着变化,因此表明这些复合物以显着的亲和力与dna结合.
Doi:10.1016/j.Jorganchem.2020.121246

专利信息

专利号:WO-2013067646-A1
优先权日:2011-11-12
标题:Process for the synthesis of beta-aminocarbonyls
发明人：BEAUCHEMIN ANDRE MARTIN; CLAVETTE CHRISTIAN; GAN WEI; MARKIEWICZ THOMAS; TODERIAN AMY BEVERLY
权利人:UNIV OTTAWA
摘要:The present application provides processes and intermediates useful in the production of β- aminocarbonyl- or β-aminothiocarbonyl-containing compounds. Provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazone. Also provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazine. The present application further provides intermediate aminoisocyanate and iminoisocyanate compounds, and methods for synthesizing the starting hydrazone and hydrazine compounds.