CAS: 12065-10-0; Germanium Selenide

该化合物是一种由和组成的二元半导体化合物,在正方形结构中结晶,并显示出有希望的光电子特性,包括金枪鱼带宽(~1.1-1.6 eV),使之适合光伏和热电应用. GeSe 展示了高吸收系数,高效充电载体流动性和在环境条件下的极佳稳定性.它的厌异晶体结构有助于独特的电子和热运输特性,增强了其在薄膜太阳能电池和相位变化内存装置中的潜力. 此外, GeSe 与铅替代物相比,毒性较低,与有环境意识的物质开发相一致. 其合成可以通过蒸气运输或基于溶液的方法实现,提供多功能制造.

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    专利信息


    专利号:US-6874335-B2
    优先权日:2002-04-12
    标题 :Large scale synthesis of germanium selenide glass and germanium selenide glass compounds
    发明人:UHLENBROCK STEFAN
    权利人:MICRON TECHNOLOGY INC
    摘要:Systems and methods for large scale synthesis of germanium selenide glass and germanium selenide glass compounds are provided. Up to about 750 grams of a germanium selenide glass or a glass compound can be synthesized at a time in about eight hours or less. Stoichiometrically proportional amounts of germanium and selenium are placed in an ampoule. A variable may also be placed in the ampoule. The ampoule is heated to above the softening temperature of the glass or glass compound being synthesized. The ampoule is then rocked for a period of time while the temperature is held constant. The temperature of the ampoule is then brought down to above the softening temperature of the glass or glass compound being synthesized and then quenched.

    专利号:CN-1659106-A
    优先权日:2002-04-12
    标 题:Large scale synthesis of germanium selenide glass and germanium selenide glass compounds

    专利号:EP-1497233-A1
    优先权日:2002-04-12
    标题:Method and apparatus for synthesis of germanium selenide glasses

    专利号:EP-1497233-B1
    优先权日:2002-04-12
    标 题 :Method and apparatus for synthesis of germanium selenide glasses

    专利号:WO-03087000-A2
    优先权日:2002-04-12
    标 题 :Large scale synthesis of germanium selenide glass and germanium selenide glass compounds

    专利号:US-8741386-B2
    优先权日:2012-09-28
    标 题:Atomic layer deposition of quaternary chalcogenides
    发明人:THIMSEN ELIJAH J; RIHA SHANNON C; MARTINSON ALEX B F; ELAM JEFFREY W; PELLIN MICHAEL J
    权利人:THIMSEN ELIJAH J; RIHA SHANNON C; MARTINSON ALEX B F; ELAM JEFFREY W; PELLIN MICHAEL J; UCHICAGO ARGONNE LLC
    摘要:Methods and systems are provided for synthesis and deposition of chalcogenides (including Cu 2 ZnSnS 4 ). Binary compounds, such as metal sulfides, can be deposited by alternating exposures of the substrate to a metal cation precursor and a chalcogen anion precursor with purge steps between.

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    合成参考文献


    摘要:L620: Wikipedia. Selenium. Last Updated 7 June 2009.
    摘要:L134: ATSDR - Agency for Toxic Substances and Disease Registry (2001). Minimal Risk Levels (MRLs) for Hazardous Substances. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    摘要:L135: International Agency for Research on Cancer (2014). IARC Monographs on the Evaluation of Carcinogenic Risks to Humans.
    摘要:L619: ATSDR - Agency for Toxic Substances and Disease Registry (2003). Toxicological profile for selenium. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA). http://www.atsdr.cdc.gov/toxprofiles/tp92.html
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