CAS: 830-81-9; Naphthalen-1-Yl Acetate

• 英文名称Naphthalen-1-Yl Acetate
• 中文名称乙酸-1-萘酯
• IUPAC名称naphthalen-1-yl acetate
• 其它别名1-Naphthalenol,acetate (9CI); 1-Naphthol, acetate (6CI,8CI); 1-Acetoxynaphthalene; 1-Naphthylacetate; Acetic acid 1-naphthyl ester; Naphthalen-1-yl acetate; a-Acetoxynaphthalene; a-Naphthol acetate; a-Naphthyl acetate
• CAS编号830-81-9
• MFCD编号:MFCD00003922
• EINECS号:212-599-8
• 分子式:C12H10O2
• 分子量:186.21
• 产品CID: 1820124
• 产品分类有机原料→分子砌块→芳环类化合物→萘类化合物

• 相似结构搜索
• InChIKey: VGKONPUVOVVNSU-UHFFFAOYSA-N
• InChI=1S/C12H10O2/c1-9(13)14-12-8-4-6-10-5-2-3-7-11(10)12/h2-8H,1H3…
• 计算化学: 氢键受体数2.0氢键供体数0.0可旋转键数1.0

相似化合物

物理性质

• 熔点43-46 °C
• 沸点118 °C at 1 mmHg
• 闪点110.4±8.2 °C
• 密度1.2±0.1 g/cm3
• PSA:26.3
• LogP:2.7651
• 折射率1.604
• 蒸汽压0.0±0.7 mmHg at 25°C
• 溶解性Dioxane: 0.1 G/ml, Clear, Colorless
• 敏感性易受潮
• 外观形态白色至淡黄色或微粉红色结晶粉末或块状物
• 储存条件-20°C
• 产品应用乙酸1-萘酯(830-81-9)的用途:是一种有机合成中间体.在酶组织化学中用以测定α-酯酶.用该品被α-酯酶水解,析出α-萘酚,在0.05M磷酸缓冲液中重重氮盐形成的色偶氮染料,在酶组织化学中用于测啶α-酶酶.

MSDS等安全信息

• GHS象形图
• GHS符号GHS05;
  注释: Corrosion
• 危险类别严重眼损伤 类别1
  皮肤腐蚀/刺激 类别2
• 警示词Danger(危险)
• 危险描述H318 |造成严重眼损伤.
  H315 |造成皮肤刺激.
• 防范说明P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P363-P405-P501
• 危险等级8
• UN编号3261.0
• 危险品标志T,Xi
• 包装等级Ⅲ
• 安全声明26-39-24/25-22-45-36/37-16
• 危险类别码41-39/23/24/25-23/24/25-10
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 90-15-3 = 830-81-9
  反应条件:1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)Pyridine Solvents: Dichloromethane; 1 H,Rt1.2 Reagents: Hydrochloric Acid Solvents: Water
  标题:Novel Naphthyl Based 1,2,4-Trioxanes: Synthesis And In-Vivo Efficacy In The Plasmodium Yoelii Nigeriensis In Swiss Mice
  作者:Karnatak,Manvika; Et Al
  参考文献:Bioorganic & Medicinal Chemistry Letters 日期:2021 卷标:51]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: (Oc-6-12)-[[4,4′,4′′,4′′′-(21H,23H-Porphine-5,10,15,20-Tetrayl-Kn21,Kn22,Kn23,Kn... (Supported On Chloromethylated Polystyrene) Solvents: Acetonitrile; 8 Min,Rt
  标题:Polystyrene-Bound Electron-Deficient Tin(Iv) Porphyrin: A New,Highly Efficient,Robust And Reusable Catalyst For Acetylation Of Alcohols And Phenols With Acetic Anhydride
  作者:Moghadam,Majid; Et Al
  参考文献:Comptes Rendus Chimie 日期:2011 卷标:14(12) 页码:1080-1087]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: 2,2′:6′,2′′-Terpyridine,Cobalt(Ii) Acetylacetonate Solvents: Dimethyl Sulfoxide; 5 Bar,Rt; 18 H,5 Bar,120 °C
  标题:Cobalt-Catalyzed Carbonylative Acetylation Of Phenols
  作者:An,Da-Lie; Et Al
  参考文献:Journal Of Catalysis 日期:2023 卷标:421 页码:194-197]
  
  6202-48-8 = 830-81-9
  反应条件:1.1 Catalysts: Titania,Sulfate Solvents: Acetic Anhydride; 35 Min,Rt
  标题:Tio2/so42-,A Convenient And Efficient Catalyst For Desilylation-Acetylation Of Trimethylsilyl Ethers With Acetic Anhydride
  作者:Jin,Tong-Shou; Et Al
  参考文献:Journal Of Chemical Research 日期:2003 卷标:(2) 页码:98-100]
  
  607-58-9 = 830-81-9
  反应条件:1.1 Reagents: Lithium Bromide Solvents: Dichloromethane; 24 H,30 - 35 °C
  标题:Counterattack Mode Differential Acetylative Deprotection Of Phenylmethyl Ethers: Applications To Solid Phase Organic Reactions
  作者:Chakraborti,Asit K.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2009 卷标:74(3) 页码:1367-1370]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: Dabco; 10 Min,70 °C -> 140 °C
  标题:The First Vinyl Acetate Mediated Organocatalytic Transesterification Of Phenols: A Step Towards Sustainability
  作者:Kumar,Manoj; Et Al
  参考文献:New Journal Of Chemistry 日期:2015 卷标:39(11) 页码:8329-8336]
  
  3396-11-0 + 90-11-9 = 830-81-9
  反应条件:1.1 Catalysts: Palladium Trifluoroacetate,4-[bis(1,1-Dimethylethyl)Phosphino]-9-[3,5-Bis(Trifluoromethyl)Phenyl]Acridine Solvents: Dimethylacetamide; 36 H,35 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water
  标题:Shining Visible Light On Reductive Elimination: Acridine-Pd-Catalyzed Cross-Coupling Of Aryl Halides With Carboxylic Acids
  作者:Toriumi,Naoyuki; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2022 卷标:144(42) 页码:19592-19602]
  
  90-15-3 + 10387-40-3 = 830-81-9
  反应条件:1.1 Reagents: Carbon Dioxide Solvents: Diglyme; 8 H,35 °C
  标题:Co2-Promoted Direct Acylation Of Amines And Phenols By The Activation Of Inert Thioacid Salts
  作者:Wang,Huan; Et Al
  参考文献:Chemsuschem 日期:2022 卷标:15(10)]
  
  = 830-81-9
  反应条件:1.1 Reagents: Acetic Anhydride,Sodium Nitrate Solvents: Trifluoroacetic Acid; 14 H,Rt
  标题:Metal-Free,Direct Acetoxylation Of Arenes
  作者:Hong Nguyen,Thi Anh; Et Al
  参考文献:Organic Letters 日期:2021 卷标:23(21) 页码:8127-8131]
  
  = 830-81-9
  反应条件:1.1 Reagents: Sodium Acetate Solvents: Water
  标题:A One-Pot Electro Oxidative Nuclear And Side Chain Acetoxylation Of Aromatic Compounds At Platinum Electrode
  作者:Srivastav,Manish K.; Et Al
  参考文献:Oriental Journal Of Chemistry 日期:2010 卷标:26(1) 页码:61-68]
  
  103-54-8 = 830-81-9
  反应条件:1.1 Reagents: Acetic Anhydride,Triethylamine Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Benzene
  标题:Construction Of Polycyclic Compounds By Cyclocarbonylation. Part 5. Synthesis Of Benzofurans And Benzothiophenes By Palladium Catalyzed Cyclocarbonylation Of 3-Furylallyl And 3-Thienylallyl Acetates
  作者:Iwasaki,Masakazu; Et Al
  参考文献:Tetrahedron Letters 日期:1989 卷标:30(1) 页码:95-8]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: Poly(Vinylpyrrolidone),Zirconium Chloride (Zrcl4) Solvents: Chloroform,Hexane; 1.67 H,Reflux
  标题:Polyvinylpyrrolidone-Supported Zirconium Nanoparticles: Synthesis,Characterization,Efficiency As A New Polymer Nanocomposite Catalyst For One-Step Transesterification Reaction
  作者:Azadi,Sedigheh; Et Al
  参考文献:Monatshefte Fuer Chemie 日期:2023 卷标:154(2) 页码:239-248]
  
  21040-45-9 = 830-81-9
  反应条件:1.1 Reagents: Triethylamine Catalysts: Dichlorobis(Triphenylphosphine)Palladium
  标题:Palladium(Ii) Chloride
  作者:Tsuji,Jiro; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2004 卷标:1 页码:1-18]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: 1-Butanaminium,N,N,N-Tributyl-,(Dichlorostannate)Octatetraconta-μ-Oxotetra-μ6-... Solvents: Acetonitrile; 6 Min,Rt
  标题:New Porphyrin-Polyoxometalate Hybrid Materials: Synthesis,Characterization And Investigation Of Catalytic Activity In Acetylation Reactions
  作者:Araghi,Mehdi; Et Al
  参考文献:Dalton Transactions 日期:2012 卷标:41(38) 页码:11745-11752]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: Titania; 25 Min,25 °C
  标题:Tio2,A Simple And An Efficient Catalyst For Esterification Of Phenols Under Solvent-Free Condition
  作者:Pasha,Mohamed Afzal; Et Al
  参考文献:Indian Journal Of Chemistry 日期:2008 卷标:(4) 页码:597-600]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Reagents: Pyridine Solvents: Dichloromethane; 0 °C -> Rt; 3 H,Rt
  标题:Nis/tbhp Induced Regioselective Selenation Of (Hetero)Arenes Via Direct C-H Functionalization
  作者:Ding,Chaochao; Et Al
  参考文献:Chemcatchem 日期:2018 卷标:10(23) 页码:5397-5401]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Catalysts: Cobalt Chloride (Cocl2); 15 S,Rt
  标题:Highly Efficient Cobalt (Ii) Catalyzed O-Acylation Of Alcohols And Phenols Under Solvent-Free Conditions
  作者:Mulla,Shafeek A. R.; Et Al
  参考文献:Open Journal Of Synthesis Theory And Applications 日期:2012 卷标:1(3) 页码:31-35]
  
  127-09-3 + 90-15-3 = 830-81-9
  反应条件:1.1 Reagents: (Diethylamino)Sulfur Trifluoride Catalysts: 4-(Dimethylamino)Pyridine Solvents: Acetonitrile; Rt; 6 H,Rt
  标题:Acylation Of Phenols To Phenolic Esters With Organic Salts
  作者:Zhang,Zhanrong; Et Al
  参考文献:Green Chemistry 日期:2022 卷标:24(24) 页码:9763-9771]
  
  3019-88-3 = 830-81-9
  反应条件:1.1 Solvents: Acetonitrile; Rt; 5 - 15 Min,Rt
  标题:Synthesis And Antibacterial Activity Of 1-Naphthyl Ethers And Esters
  作者:Pawar Nilesh,S.; Et Al
  参考文献:Research Journal Of Chemistry And Environment 日期:2013 卷标:17(2) 页码:25-29]
  
  6202-48-8 = 830-81-9
  反应条件:1.1 Catalysts: Bismuth Triflate Solvents: Acetonitrile
  标题:Efficient And Selective Conversion Of Trimethylsilyl And Tetrahydropyranyl Ethers To Their Corresponding Acetates And Benzoates Catalyzed By Bismuth(Iii) Salts
  作者:Mohammadpoor-Baltork,Iraj; Et Al
  参考文献:Monatshefte Fuer Chemie 日期:2002 卷标:133(2) 页码:189-193]
  
  6202-48-8 = 830-81-9
  反应条件:1.1 Catalysts: Sulfuric Acid (Silica-Bound) Solvents: Dichloromethane; 60 Min,Rt
  标题:An Efficient And Convenient Method For Desilylation-Acetylation Of Trimethylsilyl Ethers Catalyzed By Silica Sulfuric Acid
  作者:Jin,Tong-Shou; Et Al
  参考文献:Asian Journal Of Chemistry 日期:2008 卷标:20(7) 页码:5005-5010]
  
  17545-30-1 = 830-81-9
  反应条件:1.1 Solvents: Acetic Anhydride,1,4-Dioxane
  标题:Acetylation Of Polymer Supported Phenoxides By Acetic Anhydride In Nonaqueous Medium
  作者:Ram,B.; Et Al
  参考文献:Indian Journal Of Chemistry 日期:1988 卷标:(7)]
  
  575-36-0 = 830-81-9
  反应条件:1.1 Reagents: Sodium Nitrite Solvents: Acetic Acid,Acetic Anhydride1.2 Reagents: Water
  标题:Conversion Of N-Aromatic Amides To O-Aromatic Esters
  作者:Glatzhofer,Daniel T.; Et Al
  参考文献:Organic Letters 日期:2002 卷标:4(14) 页码:2349-2352]
  
  90-14-2 = 830-81-9
  反应条件:1.1 Reagents: Cesium Carbonate Catalysts: Bis(Dibenzylideneacetone)Palladium,9-[3,5-Bis(Trifluoromethyl)Phenyl]-4-(Diphenylphosphino)Acridine Solvents: Dimethylacetamide; 24 H,35 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water
  标题:Shining Visible Light On Reductive Elimination: Acridine-Pd-Catalyzed Cross-Coupling Of Aryl Halides With Carboxylic Acids
  作者:Toriumi,Naoyuki; Et Al
  参考文献:Journal Of The American Chemical Society 日期:2022 卷标:144(42) 页码:19592-19602]
  
  90-15-3 + 62-23-7 = 830-81-9
  反应条件:1.1 Reagents: Trifluoroacetic Anhydride,Phosphoric Acid Solvents: Acetic Acid,Water; Rt; Rt; 5 Min,Rt
  标题:A Tfaa-H3Po4-Mediated Direct,Metal-Free And High-Speed Synthesis Of Aryl Carboxylate Esters From Phenols
  作者:Kankanala,Kavitha; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2009 卷标:130(5) 页码:505-508]
  
  90-15-3 + 10387-40-3 = 830-81-9
  反应条件:1.1 Reagents: Oxygen Catalysts: Cupric Acetate Solvents: Acetonitrile; 8 H,80 °C
  标题:Copper-Catalyzed Acetylation Of Electron-Rich Phenols And Anilines
  作者:Zhang,Jieyu; Et Al
  参考文献:Synlett 日期:2019 卷标:30(6) 页码:726-730]
  
  80116-05-8 = 830-81-9
  反应条件:1.1 Catalysts: Ferric Sulfate Hydrate Solvents: 1,2-Dichloroethane; Rt; Rt -> Reflux; 2 H,Reflux
  标题:Convenient Tetrahydropyranylation Of Alcohols And Phenols By Catalytic Ferric Sulfate Hydrate (Fe2(So4)3.Xh2O)
  作者:Li,Lingjun; Et Al
  参考文献:Canadian Journal Of Chemistry 日期:2005 卷标:83(8) 页码:1120-1123]
  
  21040-45-9 = 830-81-9
  反应条件:1.1 Catalysts: Triethylamine,Dichlorobis(Triphenylphosphine)Palladium Solvents: Benzene; 60 Atm,160 °C
  标题:Carbon Monoxide
  作者:Chatani,Naoto; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  21040-45-9 = 830-81-9
  反应条件:1.1 Reagents: Triethylamine Catalysts: Dichlorobis(Triphenylphosphine)Palladium
  标题:Palladium(Ii) Chloride
  作者:Tsuji,Jiro; Et Al
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]
  
  90-15-3 = 830-81-9
  反应条件:1.1 Reagents: Phosphorus Pentoxide
  标题:P2O5/sio2 As An Efficient Reagent For Esterification Of Phenols In Dry Media
  作者:Eshghi,Hossien; Et Al
  参考文献:Synthetic Communications 日期:2001 卷标:31(5) 页码:771-774]
  
  90-15-3 = 830-81-9 [标题:Reaction Conditions
  标题:Alkylaluminum Compounds. Xxx. Competitive Reaction Mechanisms Between 1,4-Quinone And Trialkylaluminum Compounds
  作者:Alberola,A.; Et Al
  参考文献:Anales De Quimica 日期:1982 卷标:78(2) 页码:175-9

海关参考信息

• 2902902000-精萘
  2912110000-甲醛
  2912120000-乙醛
  2915110000-甲酸
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管