CAS: 83-33-0; 2,3-Dihydro-1H-Inden-1-One

• 英文名称2,3-Dihydro-1H-Inden-1-One
• 中文名称1-茚酮
• IUPAC名称2,3-dihydro-1H-inden-1-one
• 其它别名2,3-Dihydro-1H-inden-1-one
• CAS编号83-33-0
• MFCD编号:MFCD00003785
• EINECS号:201-470-1
• 分子式:C9H8O
• 分子量:132.16
• 产品CID: 1822392
• 产品分类化学试剂 → 有机试剂 → 脂肪酮(含烯醇)

• 相似结构搜索
• InChIKey: QNXSIUBBGPHDDE-UHFFFAOYSA-N
• InChI=1S/C9H8O/c10-9-6-5-7-3-1-2-4-8(7)9/h1-4H,5-6H2…
• 计算化学: 氢键受体数1.0氢键供体数0.0可旋转键数0.0

物理性质

• 熔点38-40  °C(文献)
• 沸点244.0±0.0 °C at 760 mmHg
• 闪点111.7±0.0 °C
• 密度1.1±0.1 g/cm3
• PSA:17.07
• LogP:2.1
• 折射率1.585
• 蒸汽压0.0±0.4 mmHg at 25°C
• 溶解性水中的溶解度为6.5克/升
• 敏感性1. 存在于烟气中。
• 外观形态淡黄色液体
• 储存条件密封保存阴凉避光保存。久贮色变深。
• 产品应用用于有机合成.
• 性质描述该品为白色片状结晶.密度1.1,熔点38-42°C,沸点243-245°C,闪点111°C,水溶性6.5g/L(20C)

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别急性毒性 类别4(经口)
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
• 警示词Warning(警告)
• 危险描述H302 |吞咽有害.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P261-P305+P351+P338-
• UN编号NONH for all modes of transport
• 危险品标志Xn:Harmful
• 安全声明S22-S24/25
• 危险类别码R22
• WGK Germany3

欧盟法规

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合成工艺路线路线简述

• 103-25-3 = 83-33-0
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid; 0 °C; 48 H,25 °C1.2 Solvents: Chloroform; Rt
  标题:Superacid-Catalyzed Intramolecular Cyclization Reaction Of Arylcyanopropionate: Geminal Substitution Effect On Superelectrophilicity
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  103-25-3 = 83-33-0
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid; Cooled; 96 H,25 °C1.2 Reagents: Water Solvents: Dichloromethane; Cooled
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  2550-26-7 = 83-33-0
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid; 0 °C; 0 °C -> 25 °C; 48 H,25 °C
  标题:Cyclization Of Arylacetoacetates To Indene And Dihydronaphthalene Derivatives In Strong Acids. Evidence For Involvement Of Further Protonation Of O,O-Diprotonated β-Ketoester,Leading To Enhancement Of Cyclization
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  4840-91-9 = 83-33-0
  反应条件:1.1 Reagents: Pyridine,Tetrabutylammonium Chloride Solvents: Dimethylformamide; 80 °C
  标题:Palladium(Ii) Chloride
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  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2004 卷标:1 页码:1-18]
  
  501-52-0 = 83-33-0
  反应条件:1.1 Catalysts: Trifluoromethanesulfonic Acid Solvents: Dichloromethane; 0 °C -> Rt; 180 Min,80 °C
  标题:Non-Conventional Methodologies In The Synthesis Of 1-Indanones
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  501-52-0 = 83-33-0 [标题:Reaction Conditions
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  501-52-0 = 83-33-0
  反应条件:1.1 90 °C; 30 Min,90 °C1.2 Reagents: Water; Cooled
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  6351-10-6 = 83-33-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Calcium Manganese Oxide (Ca0.16Mno2),Hydrate (1:?) Solvents: Acetonitrile; 2 H,Rt
  标题:Nanolayered Manganese-Calcium Oxide As An Efficient And Environmentally Friendly Catalyst For Alcohol Oxidation
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  参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2014 卷标:394 页码:303-308]
  
  776-79-4 = 83-33-0
  反应条件:1.1 Solvents: Water
  标题:Mechanism Of Ketone Formation From Carboxylic Acids
  作者:Neunhoeffer,Otto; Et Al
  参考文献:Berichte Der Deutschen Chemischen Gesellschaft [abteilung] B: Abhandlungen 日期:1939 卷标:72 页码:919-29]
  
  28272-96-0 = 83-33-0
  反应条件:1.1 Catalysts: Rhodium(1+),Bis[(1,2,5,6-η)-1,5-Cyclooctadiene]-,Tetrafluoroborate(1-) (1:1),Binap Solvents: Dichloromethane; 5 Min,Rt1.2 Reagents: Hydrogen; 0.5 H,Rt1.3 Reagents: 1-Dodecyne Solvents: Dichloromethane; 16 H,Rt
  标题:Rh-Catalyzed [4 + 2] Carbocyclization Of Vinylarylaldehydes With Alkenes And Alkynes Leading To Substituted Tetralones And 1-Naphthols
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  参考文献:Organic Letters 日期:2007 卷标:9(11) 页码:2059-2062]
  
  496-11-7 = 83-33-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Dichlorobis[μ-[2-(Diphenylphosphino-Kp)-6-Methylpyridine-Kn]]Dicopper Solvents: Acetonitrile; 12 H,Rt
  标题:Photocatalytic C(Sp3)-H Bond Functionalization By Cu(I) Halide Cluster-Mediated O2 Activation
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  参考文献:Dalton Transactions 日期:2023 卷标:52(46) 页码:17109-17113]
  
  496-11-7 = 83-33-0
  反应条件:1.1 Reagents: M-Chloroperbenzoic Acid Catalysts: (Oc-6-42)-(1,1′-Hydroxyylenebis[ethane])Phenyl[5,10,15,20-Tetrakis(2,6-Dichlorop... Solvents: Dichloromethane; 0.5 H,Rt
  标题:Arylruthenium(Iii) Porphyrin-Catalyzed C-H Oxidation And Epoxidation At Room Temperature And [ruv(Por)(O)(Ph)] Intermediate By Spectroscopic Analysis And Density Functional Theory Calculations
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  = 83-33-0
  反应条件:1.1 Reagents: Chromium Trioxide Catalysts: Montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(Oh)2O10.Xh2O); 3 Min,Rt
  标题:Rapid Oxidation Of Alcohols And Trimethylsilyl And Tetrahydropyranyl Ethers With Cro3 In The Presence Of Sulfonic Acid Functionalized Ordered Nanoporous Na+-Montmorillonite
  作者:Shirini,Farhad; Et Al
  参考文献:Iranian Journal Of Catalysis 日期:2014 卷标:4(1) 页码:1-7]
  
  = 83-33-0
  反应条件:1.1 Reagents: Potassium Persulfate Catalysts: Molybdenum Oxide (Moo3) Solvents: Acetonitrile,Water; Rt; 0.34 H,Reflux
  标题:K2S2O8/moo3,An Oxidation Reagent For Benzylic Alcohols And Trimethylsilyl And Tetrahydropyranyl Ethers
  作者:Shirini,F.; Et Al
  参考文献:Journal Of Chemical Research 日期:2008 卷标:(7) 页码:409-411]
  
  352533-60-9 = 83-33-0
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium Diacetate Solvents: Dimethylacetamide; 30 Min,140 °C
  标题:Palladium Catalyzed Annulation Of Morita-Baylis-Hillman Adducts: Synthesis Of Indene And Indanone Derivatives
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  参考文献:Chemistryselect 日期:2020 卷标:5(5) 页码:1648-1654]
  
  5758-12-3 = 83-33-0
  反应条件:1.1 Catalysts: Montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(Oh)2O10.Xh2O); 2 Min
  标题:Montmorillonite K-10 As Highly Efficient And Mild Catalyst For Deprotection Of Ketone Dimethylhydrazones Using Microwaves In A Solventless System
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  参考文献:Zeitschrift Fuer Naturforschung 日期:2002 卷标:57(8) 页码:961-962]
  
  13225-61-1 = 83-33-0
  反应条件:1.1 Catalysts: Carbon Monoxide,Platinum Tetrachloride Solvents: Tetrahydrofuran,Water
  标题:Hydration Of Alkynes By A Ptcl4-Co Catalyst
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  参考文献:Journal Of Organic Chemistry 日期:1997 卷标:62(3) 页码:669-672]
  
  73424-46-1 = 83-33-0
  反应条件:1.1 Reagents: Water Catalysts: Amberlyst 15 Solvents: Acetone,Water
  标题:Amberlyst 15,A Superior,Mild,And Selective Catalyst For Carbonyl Regeneration From Nitrogeneous Derivatives
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  参考文献:Journal Of The Chemical Society 日期:1988 卷标:(9) 页码:2563-5]
  
  103-25-3 = 83-33-0
  反应条件:1.1 Reagents: 1-Carboxy-4-Hydroxy-α-Oxo-2,5-Cyclohexadiene-1-Propanoic Acid
  标题:Cyclization Of Aryl-Aliphatic Esters With Phosphorus Pentoxide In Phosphoric Acid
  作者:Gilmore,Richard C. Jr.
  参考文献:Journal Of The American Chemical Society 日期:1951 卷标:73 页码:5879-80]
  
  3349-60-8 = 83-33-0
  反应条件:1.1 Reagents: Diethyl Chlorophosphite Solvents: Chloroform1.2 Solvents: Water
  标题:Diethyl Chlorophosphite: A Versatile Reagent
  作者:Jie,Zhou; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2002 卷标:67(3) 页码:711-719]
  
  3349-60-8 = 83-33-0
  反应条件:1.1 Catalysts: Iron Oxide (Fe3O4),Sulfuric Acid; 5 Min,60 - 70 °C; 40 Min,60 - 70 °C
  标题:Nano Fe3O4/h2So4 As Effective Catalytic System For Deprotection Oxime
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  3349-60-8 = 83-33-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Manganese Oxide (Mno2); 6 H,Rt
  标题:Wool Supported Manganese Dioxide Nano-Scale Dispersion: A Biopolymer Based Catalyst For The Aerobic Oxidation Of Organic Compounds
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  4840-91-9 = 83-33-0
  反应条件:1.1 Reagents: Pyridine Catalysts: Tetrabutylammonium Chloride,Palladium Diacetate Solvents: Dimethylformamide1.2 8 H,100 °C1.3 Reagents: Ammonium Chloride Solvents: Water1.4 Solvents: Diethyl Ether
  标题:Palladium-Catalyzed Carbonylative Cyclization Of Unsaturated Aryl Iodides And Dienyl Triflates,Iodides,And Bromides To Indanones And 2-Cyclopentenones
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  参考文献:Journal Of The American Chemical Society 日期:2003 卷标:125(16) 页码:4804-4807]
  
  4840-91-9 = 83-33-0 [标题:Reaction Conditions
  标题:Product Class 6: Annulated Benzenes (1H-Cyclopropabenzenes,1,2-Dihydrocyclobutabenzenes,Indanes,And Indenes)
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  6351-10-6 = 83-33-0
  反应条件:1.1 Reagents: Hydrogen Peroxide Catalysts: N-(2-Pyridinylmethyl)Glycine (Complexes With Tungsten Trioxide And Fe3O4-Supported) Solvents: Acetonitrile,Water; 6 H,50 °C
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  6351-10-6 = 83-33-0
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Gold,Poly(Vinylpyrrolidone) Solvents: Water; 30 Min,27 °C
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  204519-27-7 = 83-33-0
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  标题:Preparation Of 1-Indanone From Cis-N-Indanylamides Via N-Indenylamides
  参考文献:Japan]
  
  28272-96-0 = 83-33-0
  反应条件:1.1 Catalysts: Di-μ-Chlorobis[(1,2,5,6-η)-1,5-Cyclooctadiene]Dirhodium,6-[(Diphenylphosphino)Methyl]-3-Methyl-2-Pyridinamine Solvents: Toluene; 24 H,150 °C
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  28272-96-0 = 83-33-0
  反应条件:1.1 Reagents: Hydrogen Catalysts: Rhodium(1+),[(1,2,5,6-η)-Bicyclo[2.2.1]Hepta-2,5-Diene][1,1′-(1,2-Ethanediyl)Bi... Solvents: Dichloromethane; 5 Min,Rt1.2 Solvents: Dichloromethane; 18 H,Rt
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  参考文献:Journal Of The American Chemical Society 日期:2005 卷标:127(46) 页码:16042-16043]
  
  496-11-7 = 83-33-0
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  = 83-33-0
  反应条件:1.1 Reagents: Iodic Acid Catalysts: Water,Sodium Bisulfate Monohydrate Solvents: Acetonitrile; 6.3 H,Reflux
  标题:Nahso4.H2O-Promoted Oxidative Deprotection Of Trimethylsilyl,Tetrahydropyranyl,And Methoxymethyl Ethers With Hio3
  作者:Shirini,Farhad; Et Al
  参考文献:Arkivoc (Gainesville 日期:2008 卷标:(15) 页码:71-78]
  
  = 83-33-0
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid Solvents: Chloroform; 4 H,25 °C
  标题:Friedel-Crafts Acylation With Amides
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  参考文献:Journal Of Organic Chemistry 日期:2012 卷标:77(13) 页码:5788-5793]
  
  810669-79-5 = 83-33-0
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Palladium Diacetate Solvents: Dimethylacetamide; 30 Min,140 °C
  标题:Palladium Catalyzed Annulation Of Morita-Baylis-Hillman Adducts: Synthesis Of Indene And Indanone Derivatives
  作者:Rajan Sruthi,Pambingal; Et Al
  参考文献:Chemistryselect 日期:2020 卷标:5(5) 页码:1648-1654]
  
  5758-12-3 = 83-33-0
  反应条件:1.1 Reagents: Oxygen Catalysts: Montmorillonite ((Al1.33-1.67Mg0.33-0.67)(Ca0-1Na0-1)0.33Si4(Oh)2O10.Xh2O); Rt; 12 H,Rt
  标题:A Facile Deprotection Of N,N-Dimethylhydrazones Using Montmorillonite Ksf As Catalyst
  作者:Hosseinzadeh,Rahmam; Et Al
  参考文献:Chemistry: An Indian Journal 日期:2003 卷标:1(1) 页码:53-56]
  
  5758-12-3 = 83-33-0
  反应条件:1.1 Catalysts: Alumina; 4.5 Min
  标题:Solvent-Free Solid-Supported Recovery Of Carbonyl Compounds From N,N-Dimethylhydrazones Under Microwave Irradiation
  作者:Sharifi,Ali; Et Al
  参考文献:Arkivoc (Gainesville 日期:2006 卷标:(15) 页码:17-21]
  
  625-36-5 = 83-33-0
  反应条件:1.1 Reagents: Aluminum Chloride,Sulfuric Acid
  标题:Modern Friedel-Crafts Chemistry. Xiii. Intra- And Intermolecular Cyclization Of Some Carbonyl Derivatives Under Friedel-Crafts Conditions
  作者:Khalaf,Ali A.; Et Al
  参考文献:Bulletin De La Societe Chimique De France 日期:1984 卷标:285 页码:285-91]
  
  880486-81-7 = 83-33-0
  反应条件:1.1 Reagents: Ammonium Dichromate Catalysts: Silica,Water,Aluminum Hydrogen Sulfate; 20 Min,Rt
  标题:Selective Oxidative Deprotection Of Trimethylsilyl Ethers In Solution And Under Solvent Free Conditions
  作者:Shirini,F.; Et Al
  参考文献:Bulletin Of The Korean Chemical Society 日期:2005 卷标:26(11) 页码:1833-1835]
  
  880486-81-7 = 83-33-0
  反应条件:1.1 Reagents: Iodic Acid Catalysts: Water,Sodium Bisulfate Monohydrate Solvents: Acetonitrile; 5.5 H,Reflux
  标题:Nahso4.H2O-Promoted Oxidative Deprotection Of Trimethylsilyl,Tetrahydropyranyl,And Methoxymethyl Ethers With Hio3
  作者:Shirini,Farhad; Et Al
  参考文献:Arkivoc (Gainesville 日期:2008 卷标:(15) 页码:71-78]
  
  95-13-6 = 83-33-0
  反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide Catalysts: Palladium(2+),Bis(Acetonitrile)(7-Methyl-6-Phenylimidazo[1,2-A][1,8]Naphthyridi... Solvents: Acetonitrile; 24 H,70 °C
  标题:Electronic Asymmetry Of An Annelated Pyridyl-Mesoionic Carbene Scaffold: Application In Pd(Ii)-Catalyzed Wacker-Type Oxidation Of Olefins
  作者:Saha,Sayantani; Et Al
  参考文献:Acs Catalysis 日期:2020 卷标:10(19) 页码:11385-11393]
  
  95-13-6 = 83-33-0
  反应条件:1.1 Reagents: Oxygen,Poly(Methylhydrosiloxane) Catalysts: Ferrous Chloride Solvents: Ethanol; 6 H,1 Atm,Rt -> 80 °C
  标题:Iron-Catalyzed Wacker-Type Oxidation
  作者:Liu,Binbin; Et Al
  参考文献:Synlett 日期:2018 卷标:29(4) 页码:383-387]
  
  73424-46-1 = 83-33-0
  反应条件:1.1 Catalysts: Envirocat Epzg Solvents: Acetone,Water
  标题:Envirocat Epzg As A New Heterogeneous Catalyst For The Regeneration Of Ketones From Their Tosylhydrazones
  作者:Ballini,Roberto; Et Al
  参考文献:Synlett 日期:1997 卷标:(7) 页码:795-796

海关参考信息

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  2912120000-乙醛
  2912210000-苯甲醛
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