合成目标产物 Ovex 主要起始原料 Sodium 4-Chlorobenzene Sulfinate And 4-Chlorophenol
14752-66-0 = 80-33-1 反应条件:1.1 Reagents: Potassium Carbonate,Iodine Solvents: Methanol; 5 H,Rt1.2 Reagents: Sodium Thiosulfate Solvents: Water 标题:Iodine-Induced Synthesis Of Sulfonate Esters From Sodium Sulfinates And Phenols Under Mild Conditions 作者:Gao,Jian; Et Al 参考文献:Rsc Advances 日期:2015 卷标:5(35) 页码:27439-27442]
98-60-2 = 80-33-1 反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 0 °C 标题:Electron Donor-Acceptor Complex Enabled Decarboxylative Sulfonylation Of Cinnamic Acids Under Visible-Light Irradiation 作者:Ge,Qian-Qian; Et Al 参考文献:Journal Of Organic Chemistry 日期:2019 卷标:84(13) 页码:8691-8701]
98-60-2 = 80-33-1 反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 0 °C 标题:Visible Light-Induced Highly Regioselective And Stereoselective Oxysulfonylation Of Alkynes For The Synthesis Of (E)-β-Phenoxy Vinylsulfones 作者:Xie,Wenjiao; Et Al 参考文献:Organic Letters 日期:2022 卷标:24(32) 页码:6099-6104
📜Phenyl 4-Chlorobenzenesulfonate置于碘,氯体系中,化学反应生成 杀螨酯 参考文献:Wol'Fson Et Al.,Zhurnal Obshchei Khimii,1956,Vol. 26,P. 2579 标题:Wol'Fson Et Al.,Zhurnal Obshchei Khimii,1956,Vol. 26,P. 2579
专利号:WO-8400363-A1 优先权日:1982-07-12 标题 :Synthesis of periplanone-b 发明人:STILL W CLARK 权利人:HERCULITE PRODUCTS INC 摘要:A synthesis of periplanone-B, a female sex pheromone of the American cockroach, P. americana. Novel compounds which are useful as intermediates in the synthesis of periplanone-B are described including the precursor alcohol, periplanol-B.
专利号:WO-9507882-A1 优先权日:1993-09-14 标 题:Synthesis of amido acids from carboxylic acid esters and amino acid salts 发明人:HEINZMAN STEPHEN WAYNE; DUPONT JEFFREY SCOTT 权利人:PROCTER & GAMBLE 摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfonates for use as bleach activators, starting from carboxylic acid esters and amino acid salts.
专利号:US-5534642-A 优先权日:1993-09-14 标题 :Synthesis of amido acids from carboxylic acids and lactams 发明人:HEINZMAN STEPHEN W; DUPONT JEFFREY S; TETTENHORST WILLIAM C 权利人:PROCTER & GAMBLE 摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfates for use as bleach activators, starting from carboxylic acids and lactams.
专利号:US-4686285-A 优先权日:1984-02-10 标题:Basic azo and non-azo compounds having one or two disubstituted 1,3,5-triazine rings each of which is linked through a bridging radical to the 1-position of a pyrazole ring 发明人:PEDRAZZI REINHARD 权利人:SANDOZ LTD 摘要:(i) Metal-free compounds of the formula ##STR1## (ii) tautomers thereof, (iii) 1:1 and 1:2 metal complexes of (i) and (ii), n (iv) salts of (i), (ii), and (iii), and n (v) mixtures of (i), (ii), (iii), and (iv), n wherein the symbols are as defined in the Specification, are useful as dyes for, for example, polymers and copolymers of acrylonitrile, polyesters modified to contain acid groups, polyamides such as wool, leather, cotton, bast fibers such as hemp, flax, sisal jute, coir and straw, regenerated cellulose, glass fibers and paper (those wherein R o is other than hydrogen) or as intermediates for the synthesis of dyes.
专利号:US-4002684-A 优先权日:1974-07-05 标题:Manufacture of γ,δ-unsaturated ketones 发明人:VON FRAUNBERG KARL 权利人:BASF AG 摘要:gamma , delta -Unsaturated non-cyclic aliphatic ketones are prepared by reacting specific alpha , beta -unsaturated ketones with vinylmagnesium halide in the presence of inorganic copper compounds at temperatures below 0 DEG C. The reaction products are valuable intermediates in the synthesis of a number of perfumes. For example, the compound 3,3-dimethyl-1-hexen-5-one which may be prepared from mesityl oxide and vinylmagnesium chloride is an intermediate for lavandulyl compounds such as lavandulol and lavandulyl acetate.
专利号:US-10906880-B2 优先权日:2016-01-26 标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application 发明人:FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI 权利人:UNIV NANKAI 摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.
1: Federici LM, Roth SD, Krier C, Fitz SD, Skaar T, Shekhar A, Carpenter JS, Johnson PL. Anxiogenic CO2 stimulus elicits exacerbated hot flash-like responses in a rat menopause model and hot flashes in postmenopausal women. Menopause. 2016 Nov;23(11):1257-1266. 2: Acar N, Balkarli H, Soyuncu Y, Ozbey O, Celik-Ozenci C, Korkusuz P, Ustunel I. The determination of apoptosis rates on articular cartilages of ovariectomized rats with and without alendronate treatment. Histol Histopathol. 2016 Jun;31(6):635-45. doi: 10.14670/HH-11-701. Epub 2015 Dec 3. doi: 10.1016/j.taap.2015.06.010. Epub 2015 Jun 12. 4: Passmore DR, Rao TC, Peleman AR, Anantharam A. Imaging plasma membrane deformations with pTIRFM. J Vis Exp. 2014 Apr 2;(86). doi: 10.3791/51334.
合成参考文献
摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(37), 1982 摘要:Guide to the Chemicals Used in Crop Protection., 6(381), 1973 摘要:Meylan WM et al; Environ Sci Technol 28: 459-65 (1992) 摘要:White-Stevens, R. (ed.). Pesticides in the Environment: Volume 1, Part 1, Part 2. New York: Marcel Dekker, Inc., 1971., p. 116 摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)