CAS: 5986-55-0; (1R,4S,4As,6R,8As)-4,8A,9,9-Tetramethyldecahydro-1,6-Methanonaphthalen-1-Ol

上下游产品

CAS号874747-37-2 (1S,4R,6R)-6-(2... | CAS号874747-39-4 (1S,4R,6R)-6-[2... | CAS号874747-38-3 (1S,2R,4S,8S)-4... | CAS号733001-15-5 (-)-(1S,2R,4S,8...

(-)-(1S,4R,6S)-6-异丙烯基-1,3,3-三甲基二环[2.2.2]辛烷-2-酮置于palladium On Activated Charcoal 4-二甲氨基吡啶,氢气,Sodium,碳酸氢钠,臭氧,N,N-二异丙基乙胺体系中,用 四氢呋喃,甲醇,二氯甲烷,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 55.0H,反应生成 百秋李醇
参考文献:对映体全合成(-)-广cho香醇
标题:对映体全合成(-)-广cho香醇
摘要:从容易获得的单萜(R)-香芹酮开始,完成了广patch香醇的对映体特异性全合成.串联的双迈克尔反应-烷基化序列和单电子介导的6-内基trig环化反应已被用作关键步骤.
DOI:10.1016/j.Tetasy.2005.11.012

专利信息

专利号:US-4146740-A
优先权日:1974-08-02
标题 :Intermediates useful in the production of norpatchoulenol
发明人：TEISSEIRE PAUL J
权利人:ROURE BERTRAND DUPONT SA
摘要:Intermediates useful for the synthesis of the valuable perfume material norpatchoulenol, said intermediates having the formula, for instance ##STR1## This intermediate, which is a novel compound, is useful as an intermediate for the production of ethers, esters and other intermediates, which are also novel compounds, such as, for instance, methyl, ethyl, isopropyl and benzyl ethers which can be represented by the formulae ##STR2## wherein R is hydrogen or lower carboxylic acyl. ##STR3## WHERE R is lower alkyl, such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, benzyl, etc., and ##STR4## where ##STR5## is a lower acyl radical such as acetyl, propionyl, butyryl, benzoyl, etc. Such intermediates are readily prepared by etherification and esterification reaction procedures and said intermediates are useful as intermediates for the preparation of other odorants. n The intermediate of the above formula I is, however, especially valuable for the production of the novel acid-alcohol compound corresponding to the formula ##STR6## which it has been discovered is highly effectively converted, by oxidative decarboxylation, to the valuable perfume material norpatchoulenol which latter has the formula ##STR7##

专利号:US-4055594-A
优先权日:1975-04-09
标 题 :Intermediates useful for the production of norpatchoulenol
发明人：TEISSEIRE PAUL JOSE
权利人:ROURE BERTRAND DUPONT SA
摘要:A novel process for the production of the valuable perfume material norpatchoulenol is disclosed which involves oxidatively decarboxylating an acid precursor according to the following reaction scheme: ##STR1## Intermediates for the synthesis, having the formula ##STR2## wherein R represents -COOH, CH 2 OH or --CHO are also disclosed.

专利号:CN-115948456-A
优先权日:2022-10-18
标题:A fusion gene and method capable of increasing the synthesis of patchouli alcohol

专利号:CN-107033037-B
优先权日:2017-04-27
标题 :An Asymmetric Synthesis of Optically Pure Terpenoid Alkaloid Analogs Catalyzed by Chiral Acids

专利号:CN-115948456-B
优先权日:2022-10-18
标题 :A fusion gene and method for increasing the synthesis of patchouli alcohol

专利号:CN-114921463-B
优先权日:2022-04-11
标题:Artificial non-coding RNA molecule CsiY for regulating and controlling synthesis yield of terpenoid and application thereof