专利号:US-5693855-A 优先权日:1995-02-14 标 题 :Process for the synthesis of fluorinated sulfonic acids 发明人:ZAVILLA JOHN; HOMMELTOFT SVEN IVAR 权利人:HALDOR TOPSOE AS 摘要:Process for the preparation of a fluorinated sulphonic acid compound by hydrolysis of a corresponding fluorinated sulphonyl fluoride in the presence of a tertiary amine, comprising steps of n (a) recovering a mixture of a salt of the fluorinated sulphonic acid with the tertiary amine and an ammonium fluoride salt of the tertiary amine; n (b) distilling off the tertiary ammonium fluoride salt and leaving a distillation remanence containing the salt of the fluorinated sulphonic acid with the tertiary amine; and n (c) recovering the fluorinated sulphonic acid compound from the distillation remanence.
专利号:CN-117756633-A 优先权日:2023-12-19 标 题:Application of catalyst in synthesis of dimethyl dicarbonate, synthesis method and production system
专利号:CN-119588417-A 优先权日:2023-12-19 标 题:Application of catalyst in synthesis of dimethyl dicarbonate, synthesis method and production system
专利号:US-10125226-B2 优先权日:2013-06-05 标 题 :Scale-up process of bifunctionalized triblock copolymers with secondary and tertiary amines, with application in dewatering and desalting of heavy crude oils 发明人:FLORES SANDOVAL CESAR ANDRES; FLORES OROPEZA EUGENIO ALEJANDRO; LOPEZ ORTEGA ALFONSO; HERNANDEZ CORTEZ JOSE GONZALO; ESTRADA BUENDIA ARISTEO; CASTRO SOTELO LAURA VERONICA; REYES MARTINEZ REYNA; ALVAREZ RAMIREZ FERNANDO; ESTRADA MARTINEZ ARQUIMEDES; VAZQUEZ MORENO FLAVIO SALVADOR 权利人:MEXICANO INST PETROL 摘要:A chemical synthesis process is provided for the functionalization of monodispersed triblock copolymer (POEw-POPy-POEw) with secondary or tertiary amines at a semi-industrial level in glass reactors having a capacity between 1 L and 100 L. The process includes two stages where the first stage uses an alkylsulfonyl or arylsulfonyl chloride to obtain better leaving groups, and the second stage is the nucleophilic substitution with secondary or tertiary amines, to obtain the bifunctionalized triblock copolymers. The main advantage for this process is to reduce the quantity of unitary process done in each stage, the optimization of reaction times, and the stoichiometric relationships.
专利号:US-9752084-B2 优先权日:2013-02-26 标题 :Block copolymers, synthesis and application as dehydrating and desalting of heavy crudes 发明人:FLORES OROPEZA EUGENIO ALEJANDRO; FLORES SANDOVAL CESAR ANDRES; REYES MARTINEZ REYNA; HERNANDEZ CORTEZ JOSE GONZALO; LOPEZ ORTEGA ALFONSO; CASTRO SOTELO LAURA VERONICA; ALVAREZ RAMIREZ FERNANDO; ESTRADA MARTINEZ ARQUIMEDES; VAZQUEZ MORENO FLAVIO SALVADOR 权利人:MEXICANO INST PETROL 摘要:The present invention is related to formulations consisting by block copolymers α,ω-di-aryl or alkyl sulfonates of poly(ethylene oxide) w -poly(propylene oxide)-poly(ethylene oxide) w of bis-ammonium and block copolymers α,ω-di-amine of poly(ethylene oxide) w -poly(propylene oxide)-poly(ethylene oxide) w , that are effective in the dewatering and desalting crude whose specific gravities are within the range of 14 to 23° API.
专利号:US-5585510-A 优先权日:1994-06-24 标 题:Ligated polyoxometalates and methods for their synthesis 发明人:MAZANY ANTHONY M 权利人:GOODRICH CO B F 摘要:Polyoxometalates are provided which are highly soluble in organic solvents, including monomer mixtures utilized in reaction injection molding. High solubility is obtained by organic moieties incorporated in the cation and anion of compounds having the formula [R1mER2m']nMxOyLz. These compounds provide improved solubility while maintaining catalyst activity within reaction injection molding formulations. A method is also provided for preparing these polyoxometalates within an aqueous acidic medium, wherein ligands are incorporated in the complex simultaneously with the formation of the polyoxometalate complex.
[参考文献]: M Y Mirza, Et Al. Studies On The Extraction Of Platinum Metals With Tri-Iso-Octylamine From Hydrochloric And Hydrobromic Acid: Separation And Determination Of Gold, Palladium And Platinum. Talanta. 1980 Feb;27(2):101-6.
合成参考文献
摘要:American Industrial Hygiene Association Journal., 23(95), 1962 []