CAS: 15760-18-6; 3-(4-Methylcyclohex-3-En-1-yl)Butan-1-Ol

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CAS号201230-82-2 carbon monoxide | CAS号138-86-3 柠檬烯;双戊烯 | CAS号6784-13-0 3-(4-Methyl-3-c... | CAS号39155-38-9 (4-methylcycloh... | CAS号4342-60-3 4-甲基-3-环己烯-1-羧酸 | CAS号162132-39-0 1,1-dibromo-2-(... | CAS号162132-41-4 methyl 3-(4-met...

📜4-甲基环己-3-烯-1-羧酸置于copper(L) Iodide,Lithium Aluminium Tetrahydride,甲基锂,三苯基膦,Pyridinium Chlorochromate,锌体系中,用 乙醚,二氯甲烷 用作溶剂,化学反应 211.0H,反应生成甲基环己烯基丁醇
参考文献:Termite Trail Attractants: New Syntheses Of Racemic (E)-α-,(Z)-α-Andβ-Bisabolenes
标题:Termite Trail Attractants: New Syntheses Of Racemic (E)-α-,(Z)-α-Andβ-Bisabolenes
摘要:Racemic (E)-Alpha-Bisabolene (E)(1) Was Synthetized Starting From 4-Methyl-3-Cyclohexenecarboxylic Acid (3) By A Reaction Sequence Involving The Pd(0)-Catalyzed Cross-Coupling Reaction Between The (E)-2-Methyl-1-Alkenyltrimethylstannane 8 And 3-Methyl-2-Buten-1-Yl Acetate (9). Three Different Procedures,In Which A Common Precursor Was Used As Key Intermediate,Were Tested For The Synthesis Of Racemic (Z)-Alpha-Bisabolene (Z)(1). The Best One,Which Involved The Reaction Between Bromide 18 And Lithium Dialkenylcuprate 19,Afforded A Mixture Of (Z)-And (E)-1 In A 93:7 Molar Ratio,Respectively. Finally,Racemic Beta-Bisabolene (2) Was Synthetized By A Simple Reaction Sequence Involving The Zr-Promoted Methylenation Of Ketone 22 Prepared From 3.
Doi:10.1080/00397919408010239